
CAS Name: 1-Methoxypropane
Additional Names: Neo-thyl
Percent Composition: C 64.82%, H 13.60%, O 21.59%
Literature References: Prepd by passing a mixture of methyl and propyl alcohol through a hot layer of b-naphthalenesulfonic or benzenesulfonic acids: Krafft, Ber. 26, 2832 (1893); DE 69115; Frdl. III, 11. Laboratory prepn from sodium propylate and methyl iodide: Chancel, Ann. 151, 305 (1869); Michael, Wilson, Ber. 39, 2573 (1906); Bennett, Phillip, J. Chem. Soc. 1928, 1931.
CAS Name: Selenium nitride
Percent Composition: N 15.07%, Se 84.93%
Literature References: Prepd by passing dry ammonia over selenium tetrachloride: Wöhler, Bull. Soc. Chim. [1] 1, 25 (1859); by treating a dil soln of selenium oxychloride in benzene with dry ammonia and washing the precipitate with water and potassium cyanide: Lenher, Wolesensky, J. Am. Chem. Soc. 29, 215 (1907); by the action of dry ammonia on a dilute soln of selenium monochloride in carbon disulfide: van Valkenburg, Bailar, ibid. 47, 2134 (1925); by the action of dry ammonia on diethyl selenite or dimethyl selenite dissolved in benzene and washing with potassium cyanide: Strecker, Schwarzkopf, Z. Anorg. Chem. 221, 193 (1934); by reacting anhydr, liquid ammonia with selenium dioxide: Jander, Doetsch, Ber. 93, 561 (1960). Crystal structure: Baernighausen et al., Acta Crystallogr. 15, 615 (1962); 21, 571 (1966).
Additional Names: Chlorine tetroxyfluoride
Percent Composition: Cl 29.93%, F 16.04%, O 54.03%
Literature References: Prepd by passing fluorine over cold 72% aq perchloric acid in platinum apparatus: Rohrback, Cady, J. Am. Chem. Soc. 69, 677 (1947).
CAS Name: Tetrachlorodiborane(4)
Additional Names: boron chloride
Percent Composition: B 13.23%, Cl 86.77%
Literature References: Prepd by passing gaseous boron trichloride through flow discharge between mercury or copper electrodes: Urry et al., J. Am. Chem. Soc. 76, 5293 (1954); Wartik et al., Inorg. Synth. 10, 118 (1967); by passing boron trichloride vapor over boron monoxide at 200°: McCloskey et al., J. Am. Chem. Soc. 83, 4750 (1961). Infrared and Raman spectra: Linevsky et al., J. Am. Chem. Soc. 75, 3287 (1953). Review of boron halides: Massey, Adv. Inorg. Chem. Radiochem. 10, 1-152 (1967).
CAS Name: Carbamic chloride
Additional Names: chloroformamide
Percent Composition: C 15.11%, H 2.54%, Cl 44.60%, N 17.62%, O 20.13%
Literature References: Prepd by passing HCl gas over heated cyanuric acid: Gattermann, Rossolymo, Ber. 23, 1190 (1890); Gattermann, Ber. 32, 1117 (1899). From ammonia and phosgene at 400°: Rupe, Labhard, Ber. 33, 236 (1900), cf. Gattermann, Ann. 244, 30 (1888).
CAS Name: Ethanimidamide hydrochloride
Additional Names: ethanamidine hydrochloride; a-amino-a-iminoethane hydrochloride; ethenylamidine hydrochloride; acediamine hydrochloridePercent Compositi...
Literature References: Prepd by passing HCl into a soln of acetonitrile in abs alcohol, then passing NH3 into the reaction mixture: Pinner, Ber. 16, 1654 (1883); 17, 178 (1884); Dox, Org. Synth. coll. vol. I, 5 (New York, 2nd ed., 1941). See also Fargher, J. Chem. Soc. 117, 674 (1920). Review: Shriner, Neumann, Chem. Rev. 35, 351-425 (1944).
Additional Names: Tribromomonosilane; silicobromoform
Percent Composition: Br 89.18%, H 0.37%, Si 10.45%
Literature References: Prepd by passing hydrogen bromide over heated silicon or a silicide such as copper silicide: Schumb, Young, Inorg. Synth. 1, 38 (1939); Schenk in Handbook of Preparative Inorganic Chemistry vol. 1, G. Brauer, Ed. (Academic Press, New York, 2nd ed., 1963) pp 692-694.
Additional Names: Tin diselenide
Percent Composition: Se 57.09%, Sn 42.91%
Literature References: Prepd by passing the vapor of selenium over heated tin: Little, On Selenium and Some of the Metallic Selenides, Göttingen (Thesis, 1859); by treating a soln of stannic chloride with hydrogen selenide: Berzelius, cited in Mellor's vol. X, 785 (1930); by treating a soln of an alkali selenostannate or sulfoselenostannate with hydrochloric acid: Ditte, Compt. Rend. 95, 641 (1882).
CAS Name: N,N,N-Trimethyl-2-(phosphonooxy)ethanaminium chloride
Additional Names: choline chloride dihydrogen phosphate; (2-hydroxyethyl)trimethylammonium chloride phosphate; phosphorylcholine ...
Literature References: Prepd by phosphorylation of choline chloride with diphenylphosphoryl chloride: Baer, McArthur, J. Biol. Chem. 154, 451 (1944); Baer, J. Am. Chem. Soc. 69, 1253 (1947); Biochem. Prep. 2, 96 (1952); by heating choline or choline chloride with pyrophosphoric or polyphosphoric acid: Cherbuliez, Rabinowitz, Helv. Chim. Acta 42, 1154 (1959).
CAS Name: 1-Bromo-4-(bromomethyl)benzene
Additional Names: p,a-dibromotoluene
Percent Composition: C 33.64%, H 2.42%, Br 63.94%
Literature References: Prepd by photo-bromination of p-bromotoluene: Weizmann, Patai, J. Am. Chem. Soc. 68, 150 (1946). Alternate procedure: Goerner, Nametz, ibid. 73, 2940 (1951).
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