CAS: 595-90-4; Tetraphenyltin

该化合物其结构特征为结构结构,由锡原子结为四个苯基组组成,在室内温度下,该化合物一般是白到光黄色的固体,以其稳定性和与其他有机锡化合物相比的低活性而著称.Tetraphentistannane在锡原子周围展示了四面形几何,这助长了其独特的化学特性.它经常用于有机合成,并在各种化学反应中用作试剂,特别是在有机金属化学领域.此外,四联苯丹可以作为其他含锡化合物的前体,并研究其在材料科学和催化中的潜在应用.然而,与许多有机锡化合物一样,由于有机锡化合物的潜在毒性和环境问题,应当谨慎地处理它.在与该物质打交道时,应当遵循适当的安全措施和条例.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号7646-78-8 四氯化锡 | CAS号108-90-7 氯苯 | CAS号591-51-5 苯基锂 | CAS号108-86-1 溴苯 | CAS号2117-48-8 Stannane,etheny... | CAS号4167-90-2 lithium,triphenyltin | CAS号591-50-4 碘苯 | CAS号100-58-3 苯基溴化镁 | CAS号639-58-7 三苯基氯化锡 | CAS号4713-59-1 dibromo(dipheny... | CAS号1080-42-8 Germane,dibromo... | CAS号98-95-3 硝基苯 | CAS号92-52-4 联苯 | CAS号90-90-4 4-溴二苯甲酮 | CAS号92-93-3 4-硝基联苯 | CAS号368-98-9 difluorophenyl-... | CAS号379-52-2 三苯基氟化锡 | CAS号71-43-2 苯 | CAS号666-23-9 tetrafluorophen...

合成工艺路线路线简述

    📜溴化锡 反应生成 四苯基锡
    参考文献:Pfeiffer,P.; Schnurmann,K.,Berichte Der Deutschen Chemischen Gesellschaft,1904,Vol. 37,P. 319-323
    标题:Pfeiffer,P.; Schnurmann,K.,Berichte Der Deutschen Chemischen Gesellschaft,1904,Vol. 37,P. 319-323

    海关参考信息

    专利信息


    专利号:US-5186864-A
    优先权日:1989-10-13
    标题:Synthesis of dielectric liquids by improved friedel-crafts condensation
    发明人:COMMANDEUR RAYMOND; BERGER NOELLE; JAY PIERRE; KERVENNAL JACQUES
    权利人:ATOCHEM
    摘要:Dielectric liquids are prepared by (a) Friedel-Crafts condensing at least one aromatic halide with at least one aromatic compound in the presence of a catalytically effective amount of ferric chloride, and thereafter deliberately avoiding any downstream destruction/neutralization and/or washing of such ferric chloride catalyst, (b) optionally, removing unreacted reactants from the medium of reaction, and (c) recovering from such medium of reaction a purified dielectric liquid; the subject process is thus environmentally improved by avoiding the generation of aqueous solutions containing contaminating amounts of objectionable organic compounds.

    专利号:US-10384201-B2
    优先权日:2016-02-17
    标题:Direct synthesis method of nanostructured catalyst particles on various supports and catalyst structure produced by the same
    发明人:JEONG NAMJO; KIM CHAN-SOO; JWA EUN-JIN; CHOI JI YEON; NAM JOO-YOUN; PARK SOON-CHUL; JANG MOON-SEOK; SEO YONG SEOK; HWANG KYO SIK; KIM HAN KI; HAN JI HYUNG; KIM TAE YOUNG; YOON YOUNG GI
    权利人:KOREA INST ENERGY RES
    摘要:Disclosed is a direct synthesis method of nanostructured catalyst particles on surfaces of various supports. In the disclosed synthesis method of a catalyst structure having a plurality of nanostructured catalyst particles dispersed in a support by a one-step process using a high-temperature high-pressure closed reactor, the one-step process includes supplying the support and a catalyst source into the high-temperature high-pressure closed reactor; supplying an atmosphere forming gas of the reactor into the reactor; perfectly sealing the high-temperature high-pressure closed reactor and heating the reactor to produce the catalyst structure in the reactor under self-generated pressure and synthesis temperature conditions, the catalyst structure including the plurality of nanostructured catalyst particles dispersed in the support; removing internal gases of the reactor to allow the reactor to be in a high-temperature, atmospheric pressure state and supplying an inert gas into the reactor to remove unreacted materials and byproducts remaining in the reactor; and cooling the reactor to room temperature while supplying the inert gas to synthesize the catalyst structure.

    专利号:US-7432031-B2
    优先权日:2005-03-22
    标 题:Toner for electrostatic charge developing, production method thereof, developer for electrostatic charge developing using the same, and image forming method
    发明人:MIZUTANI NORIYUKI; MAEHATA HIDEO; HAMANO HIROKAZU; TANAKA HIROYUKI; KITAGAWA SOICHIRO; IGUCHI MOEGI
    权利人:FUJI XEROX CO LTD
    摘要:A toner for electrostatic charge developing prepared by a production method including aggregating one or more kind of particles in a raw material dispersion including the particles to form aggregated particles, and coalescing the aggregated particles by heating. At least one kind of the particles is resin particles including an amorphous polyester resin synthesized by copolymerizing one or more polyvalent carboxylic acids and two or more polyhydric alcohols; at least one of the polyvalent carboxylic acids is polyvalent carboxylic acid having a sulfonic acid group; two of the polyhydric alcohols are an ethylene oxide adduct of bisphenol A and a propylene oxide adduct of bisphenol A; and the following equation is satisfied:n n10/90≦ BPA ( EO )/ BPA ( PO )≦90/10.n n In the equation, BPA(EO) represents a total mole amount of the ethylene oxide adduct of bisphenol A used in synthesis of the amorphous polyester resin, and BPA(PO) represents a total mole amount of the propylene oxide adduct of bisphenol A used in synthesis of the amorphous polyester resin.

    专利号:US-9611281-B2
    优先权日:2013-12-05
    标题:BODIPY derivatives and methods of synthesis and use thereof
    发明人:YOU YOUNGJAE; AWUAH SAMUEL; WATLEY RYAN
    权利人:UNIV OKLAHOMA
    摘要:Derivatives of BODIPY (boron dipyrromethene difluoride) and their synthesis and use are disclosed.

    专利号:US-8329923-B2
    优先权日:2010-06-17
    标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same
    发明人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH
    权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT
    摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).

    专利号:US-10024983-B1
    优先权日:2015-12-01
    标 题 :Metal-loaded plastic scintillators for gamma-ray spectroscopy
    发明人:FENG PATRICK L; CORDARO JOSEPH GABRIEL; MENGESHA WONDWOSEN; MYLLENBECK NICOLAS RICHARD
    权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC
    摘要:Exemplary embodiments of several new metal-loaded plastic scintillators are reported herein, comprising sterically and electronically isolated organotin additive complexes. Distance-dependent quenching relationships have been used as design criteria for the selection and synthesis of these organometallic additives, resulting in increased light yields and improved gamma-ray energy resolution values relative to previously reported PS/PVT examples. Fast scintillation decay properties have also been characterized in the prepared scintillators, rivaling the kinetics of stilbene-doped bibenzyl and BC-422Q-1% while providing higher light yields than these reference materials.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Jhaveri SB, Carter KR. Disubstituted polyacetylene brushes grown via surface-directed tungsten-catalyzed polymerization. Langmuir. 2007 Jul 31;23(16):8288-90. Epub 2007 Jun 14.

    合成参考文献


    摘要:Masuda, T.; Shiotsuki, M.; Sanda, F., Science of Synthesis, (2010) 45, 1437.
    摘要:Masuda, T.; Shiotsuki, M.; Sanda, F., Science of Synthesis, (2010) 45, 1426.
    摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 248.
    摘要:Sato, N., Science of Synthesis Knowledge Updates, (2011) 4, 302.
    摘要:Shirakawa, E., Science of Synthesis, (2021) , 153.
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