CAS: 670-54-2; Tetracyanoethylene

该化合物是一种高度活性有机化合物,其独特结构特征是四组环丙烷(Euron),其特点是具有与中乙烯单元相连的四种环丙烷(Euron CN),在室温温度下,这种化合物无色至黄色,以其强烈的电子接受特性而闻名,使它成为有机合成和材料科学的宝贵试剂;TCNE经常用于组成充电传输综合体,并用作包括导电聚合物在内的各种有机材料的合成构件;其高电子亲密性允许其参与红氧化反应,并可以作为强大的氧化剂;此外,TCNE在环境条件下相对稳定,但应当因其毒性和潜在的环境危害而谨慎处理;适当的安全措施,包括使用个人防护设备,在与该化合物合作时至关重要;

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

dibromomalononitrile malononitrile 1,1,2,2,-tetracyanoethane dimethylsulfonium dicyanomethylide(4-chloro-anilino)-ethenetricarbonitrile 2,6-dimethyl-4-tricyanovinylaniline 2-Cyano-3-(2,6-dimethyl-phenylamino)-but-2-enedinitrile 3-Tricyanovinylindol

合成工艺路线路线简述

  • 合成目标产物 Tetracyanoethylene 主要起始原料 Malononitrile
  • (文献来源)合成步骤主要原料 Malononitrile
📜1,1,2,2-乙烷四甲腈置于4-苯基-1,2,4-三唑啉-3,5-二酮体系中,用 乙腈 作为反应溶剂,化学反应生成 四氰基乙烯
参考文献:Aromatization Of 1,4-Cyclohexadiene With Tetracyanoethylene: An Ene Reaction
标题:Aromatization Of 1,4-Cyclohexadiene With Tetracyanoethylene: An Ene Reaction
摘要:
DOI:10.1021/ja00522A094

海关参考信息

专利信息


专利号:US-6251689-B1
优先权日:1998-05-14
标 题:Methods for the solid phase synthesis of combinatorial libraries of benzimidazoles benzoxazoles benzothiazoles and derivatives thereof
发明人:LABORDE EDGARDO; MATSUMOTO YUKIHARU
权利人:TELIK INC
摘要:The present invention provides an efficient and versatile method for the synthesis and screening of combinatorial libraries of benzimidazoles, benzoxazoles, benzothiazoles, and derivatives thereof. In order to expedite the synthesis of large arrays of compounds possessing these core structures, a general methodology for solid phase synthesis of these derivatives is provided. Arrays of benzimidazoles, benzoxazoles, benzothiazoles, and derivatives thereof useful as peptidomimetics and for the identification of agents having antifungal, antiviral, antimicrobial, anticoagulant, and antiulcer activity, or use in the treatment of inflammation, hypertension, cancer, and other conditions can be prepared by this method.

专利号:US-5824801-A
优先权日:1996-01-19
标 题:Process for sterospecific synthesis of keto-enol tautomeric mixture of p nitrobenzyl (1R, 6R, 7R)-7-phenoxyacetamido-3-oxo-3-cepham-4-(R/S)-carboxylate-1-oxide and p-nitrobenzyl (1R, 6R, 7R)-7-phenoxyacteamido-3-hydroxy-3-cephem-4-carboxylate-1-oxide
发明人:GUPTA NIRANJAN LAL; SANKARAN RAMANATHAN; CHATTEJEE SUGATA; KRISHNA TUMMA HARI
权利人:LUPIN LAB LTD
摘要:A process for the stereospecific synthesis of keto-enol tautomeric mixture of p-nitrobenzyl (1R,6R,7R)-7-phenoxyacetamido-3-oxo-3-cepham-4-(R/S)-carboxylate-1-oxide and p-nitrobenzyl (1R,6R,7R)-7-phenoxyacetamido-3-hydroxy-3-cephem-4-carboxylate-1-oxide is described. These compounds are valuable intermediates for the synthesis of cephalosporin antibiotics e.g. cefaclor.

专利号:US-7138554-B2
优先权日:2001-06-14
标题 :Synthesis of (dibromocyclobuta) aromatic compounds
发明人:STANGER AMNON
权利人:TECHNION RES & DEV FOUNDATION
摘要:A method for the synthesis of cyclobuta aromatic compounds by cyclizing two ortho dibromoalkyl substituents is described. Using a mediator, such as nickel metal, and continuous removal of product from contact with the mediator, high product yields are achieved. A method for bromination of ortho alkyl substituents of aromatic compounds is also described.

专利号:US-2018208775-A1
优先权日:2014-06-23
标 题:New aromatic macrocyclic metal complex dyes and the synthesis thereof with active nano metal powders
发明人:OLGUN UGURSOY; YILDIZ SALIH ZEKI
权利人:OLGUN UGURSOY; YILDIZ SALIH ZEKI
摘要:The present invention relates to a new type of inorganic coordination compound dyes having advanced technology optical, electronic and medical characteristics and relates to production of these dyes by means of new synthesis methods. The present invention relates to dyes which are metal (M: Li, Na, K, Mg, Ca, Sr, Ba, Ti, Zr, V, Cr, Mo, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Si, Ge, Sn, Pb, Sb, Bi, Se, Te) complexes of aromatic macrocyclic compounds of the type Phtalocyanine (Pc), Naphtalocyanine (Nc), Porphyrazine (Pz), Porphyrin (Pr), sub-Phtalocyanine (subPc), sub-Naphtalocyanine (subNc), sub-Porphyrazine (subPz), sub-Porphyrine (subPr), and relates to the synthesis of these complexes and derivatives. The subject matter dyes can be used in solar cell photovoltaic (PV) panels, in OLEDS which are organic structured light emitting diodes, in polymers, in textile and in photodynamic therapy PDT applications. Moreover, industrial applications are possible which depend on strong fluorescence characteristics.

专利号:US-11673874-B2
优先权日:2018-08-17
标 题 :Synthesis of chromanol derivatives
发明人:WEINGARTEN MELANIE; SIEGEL WOLFGANG; PUHL MICHAEL
权利人:BASF SE
摘要:The present invention relates to a process for the production of chromanol derivatives, more specifically to a process for preparing a compound of the general formula I wherein R 1 , R 2 and R 3 independently of each other are selected from hydrogen and methyl, R 4 is selected from C- 1 -C 6 -alkyl, and X is selected from C 1 -C 20 -alkyl and C 2 -C 20 -alkenyl.

专利号:US-12103918-B2
优先权日:2018-08-17
标题 :Synthesis of chromanol derivatives
发明人:WEINGARTEN MELANIE; SIEGEL WOLFGANG; PUHL MICHAEL
权利人:BASF SE
摘要:The present invention relates to a process for the production of chromanol derivatives, more specifically to a process for preparing a compound of the general formula (I) wherein R 1 , R 2 and R 3 independently of each other are selected from hydrogen and methyl, R 4 is selected from hydrogen and C 1 -C 6 -alkanoyl, and X is selected from C 1 -C 20 -alkyl and C 2 -C 20 -alkenyl.

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品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


参考文献:10.1063/1.3599047
摘要:Olson C, Heth CL, Lapidus SH, Stephens PW, Halder GJ, Pokhodnya K. Spectroscopic study of (two-dimensional) molecule-based magnets: [M(II)(TCNE)(NCMe)2][SbF6] (M = Fe, Mn, Ni). J Chem Phys. 2011 Jul 14;135(2):024503. doi: 10.1063/1.3599047.
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