CAS: 959-28-4; Trans-1,2-Dibenzoylethylene

该化合物其结构特征为结构特征,有两个苯甲醚组,附在两个碳原子之间的双联结上,该化合物是二甲苯族的成员,具有几何异构体特征,其变形结构表明苯并基组位于双联体的对面,在室温度下一般为固体,以其稳定性和水溶性相对较低而著称,但可溶于乙醇和丙酮等有机溶剂中. Trans-1-2-Dibenzyl乙烯由于能够进行各种反应,包括光化学变异,经常用于有机合成和光化学中.此外,它可能具有有趣的光学特性,从而引起对材料科学和光学应用的兴趣.应参考安全数据,以便处理,如任何化学物质一样,确保采取适当的预防措施.

结构式图片

物理性质

MSDS等安全信息

上下游产品

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合成工艺路线路线简述

  • 959-27-3 = 959-28-4
    反应条件:1.1 Reagents: Aluminum Isopropoxide Solvents: Isopropanol
    标题:Reduction Of Unsaturated 1,4-Diketones By Aluminum Isopropoxide
    作者:Lutz,Robert E.; Gillespie,J. S. Jr.
    参考文献:Journal Of The American Chemical Society 日期:1950 卷标:72 页码:344-6]

    98-86-2 = 959-28-4
    反应条件:1.1 Reagents: Diphenyl Sulfoxide,Potassium Persulfate Catalysts: Tetrabutylammonium Iodide; 10 Min,100 °C; 100 °C -> Rt1.2 Solvents: Water; Rt
    标题:Diastereoselective Sp3-C-H Functionalization Of Arylmethyl Ketones And Transformation Of E- To Z-Products Through Photocatalysis
    作者:Rastogi,Gaurav K.; Deka,Bhaskar; Deb,Mohit L.; Baruah,Pranjal K.
    参考文献:European Journal Of Organic Chemistry 日期:2020 卷标:2020(4) 页码:424-428]

    1071081-04-3 = 959-28-4
    反应条件:1.1 Reagents: Sodium Ethoxide Solvents: Ethanol
    标题:The Ramberg-Backlund Rearrangement
    作者:Paquette,Leo A.
    参考文献:Organic Reactions (Hoboken 日期:1977 卷标:25]

    72709-59-2 = 959-28-4
    反应条件:1.1 Reagents: Sodium Iodide Solvents: Dimethyl Sulfoxide; 2 Min; Cooled
    标题:Studies On Nai/dmso-Induced Retro-Michael Addition (Rma) Reactions On Some 1,5-Dicarbonyl Compounds
    作者:Rao,H. Surya Prakash; Jothilingam,S.
    参考文献:Journal Of Chemical Sciences (Bangalore 日期:2005 卷标:117(1) 页码:27-32]

    = 959-28-4
    反应条件:1.1 Reagents: Aluminum Chloride Solvents: Benzene
    标题:Trans-Dibenzoylethylene
    作者:Lutz,R. E.
    参考文献:Organic Syntheses 日期:1940 卷标:20 页码:29-32]

    13343-79-8 = 959-28-4
    反应条件:1.1 Catalysts: Silver Triflate,[1,3-Bis[2,6-Bis(1-Methylethyl)Phenyl]-1,3-Dihydro-2H-Imidazol-2-Ylidene](1,1,1-... Solvents: Acetonitrile,Water; 10 H,80 °C; 80 °C -> Rt1.2 Reagents: Selectfluor; Rt; 12 H,50 °C
    标题:Znii- And Aui-Catalyzed Regioselective Hydrative Oxidations Of 3-En-1-Ynes With Selectfluor. Realization Of 1,4-Dioxo And 1,4-Oxohydroxy Functionalizations
    作者:Jadhav,Appaso Mahadev; Gawade,Sagar Ashok; Vasu,Dhananjayan; Dateer,Ramesh B.; Liu,Rai-Shung
    参考文献:Chemistry - A European Journal 日期:2014 卷标:20(7) 页码:1813-1817]

    3282-32-4 = 959-28-4
    反应条件:1.1 Catalysts: Nickelocene Solvents: Cyclohexane; 1 H,50 °C; 18 H,Reflux
    标题:An Approach To The Synthesis Of Stipitatic Acid
    作者:Maupin,Paul Hutsell Ii
    参考文献:1983]

    3282-32-4 = 959-28-4
    反应条件:1.1 Reagents: Copper Solvents: Benzene
    标题:The Copper-Catalyzed Decomposition Of Diazo Ketones
    作者:Yates,Peter
    参考文献:Journal Of The American Chemical Society 日期:1952 卷标:74 页码:5376-81]

    859-65-4 = 959-28-4
    反应条件:1.1 Catalysts: Cyclobutenediylium,1,3-Dihydroxy-2,4-Bis(2,3,6,7-Tetrahydro-8-Hydroxy-1,1,7,7-T... Solvents: 1,2-Dichloroethane; 24 H,Rt
    标题:Squaraines As Near-Infrared Photocatalysts For Organic Reactions
    作者:Sellet,Nicolas; Sebbat,Malik; Elhabiri,Mourad; Cormier,Morgan; Goddard,Jean-Philippe
    参考文献:Chemical Communications (Cambridge 日期:2022 卷标:58(99) 页码:13759-13762]

    = 959-28-4
    反应条件:1.1 Reagents: Aluminum Chloride
    标题:Syntheses And Applications Of Vinylstannanes
    作者:Darwish,Alla
    参考文献:2009 卷标:71(1)]

    859-65-4 = 959-28-4
    反应条件:1.1 Reagents: (+)-(Camphorsulfonyl)Oxaziridine Solvents: Dichloromethane
    标题:Chemistry Of Oxaziridines. 12. Oxidation Of Alkylidenetriphenylphosphoranes With N-Sulfonyloxaziridines
    作者:Davis,Franklin A.; Chen,Bang Chi
    参考文献:Journal Of Organic Chemistry 日期:1990 卷标:55(1) 页码:360-3]

    495-71-6 = 959-28-4
    反应条件:1.1 Reagents: Iodine Catalysts: Copper Bromide (Cubr2) Solvents: Dimethylformamide; 20 H,80 °C
    标题:A Highly Tunable Stereoselective Dimerization Of Methyl Ketone: Efficient Synthesis Of E- And Z-1,4-Enediones
    作者:Xu,Kun; Fang,Yang; Yan,Zicong; Zha,Zhenggen; Wang,Zhiyong
    参考文献:Organic Letters 日期:2013 卷标:15(9) 页码:2148-2151]

    495-71-6 = 959-28-4
    反应条件:1.1 Reagents: Trifluoroacetic Acid,Oxygen Catalysts: Cupric Acetate,Palladium Diacetate Solvents: Dimethyl Sulfoxide; 48 H,80 °C
    标题:Aerobic Oxidative Dehydrogenation Of Ketones To 1,4-Enediones
    作者:Zhao,Bao-Yin; Zhang,Xing-Long; Guo,Rui-Li; Wang,Meng-Yue; Gao,Ya-Ru; Et Al
    参考文献:Organic Letters 日期:2021 卷标:23(4) 页码:1216-1221]

    32147-16-3 = 959-28-4
    反应条件:1.1 Reagents: Trimethyl Phosphite Solvents: Toluene
    标题:Debromination With Trialkyl Phosphite
    作者:Dershowitz,S.; Proskauer,S.
    参考文献:Journal Of Organic Chemistry 日期:1961 卷标:26 页码:3595-6]

    3708-04-1 + 70-11-1 = 959-28-4
    反应条件:1.1 Reagents: Potassium Carbonate Solvents: Acetone; 5 Min,Rt1.2 Solvents: Acetone; 4 H,Reflux
    标题:Synthesis Of (E)-1,4-Diaryl-2-Butene-1,4-Diones
    作者:Chan,Chieh-Kai; Chang,Meng-Yang
    参考文献:Arkivoc (Gainesville 日期:2016 卷标:(5) 页码:390-405]

    859-65-4 = 959-28-4
    反应条件:1.1 Reagents: Pyridinium,1-Fluoro-2,4,6-Trimethyl-,1,1,1-Trifluoromethanesulfonate (1:1) Solvents: Tetrahydrofuran,Water
    标题:Reaction Of N-Fluoropyridinium Salts With Wittig Reagents: A Novel And Convenient Approach To Symmetric Trans-Olefins
    作者:Kiselyov,Alexander S.
    参考文献:Tetrahedron Letters 日期:1994 卷标:35(48) 页码:8951-4]

    70-11-1 = 959-28-4
    反应条件:1.1 Reagents: Potassium Carbonate,Sodium P-Toluenesulfinate,Oxygen Solvents: Dimethylformamide; 12 H,Rt
    标题:Synthesis Of (E)-1,4-Enediones From α-Halo Ketones Through A Sodium Sulfinate Mediated Reaction
    作者:Li,Su-Yi; Wang,Xiao-Bing; Jiang,Neng; Kong,Ling-Yi
    参考文献:European Journal Of Organic Chemistry 日期:2014 卷标:2014(36) 页码:8035-8039]

    = 959-28-4
    反应条件:1.1 Reagents: Aluminum Chloride
    标题:A New Method Of Preparing Dibenzoylethylene And Related Compounds
    作者:Conant,J. B.; Lutz,R. E.
    参考文献:Journal Of The American Chemical Society 日期:1923 卷标:45 页码:1303-7]

    20718-17-6 = 959-28-4
    反应条件:1.1 Reagents: Azobisisobutyronitrile Catalysts: Copper Acetylacetonate Solvents: 1,2-Dichloroethane; 4 H,60 °C
    标题:Copper-Catalyzed Reaction Of Acylmethylide Sulfur Ylides With Dialkyl Azodicarboxylates
    作者:Zhou,Bing-Nan; Dong,Jun; Xu,Jia-Xi
    参考文献:Huaxue Shiji 日期:2019 卷标:41(9) 页码:899-904]

    = 959-28-4 [标题:Reaction Conditions
    标题:Asymmetric Diastereoselective Synthesis Of Spirocyclopropane Derivatives Of Oxindole
    作者:Oseka,Maksim; Noole,Artur; Zari,Sergei; Oeeren,Mario; Jaerving,Ivar; Et Al
    参考文献:European Journal Of Organic Chemistry 日期:2014 卷标:2014(17) 页码:3599-3606
📜2-二氮杂-1-苯乙酮置于copper Dichloride,苯体系中,化学反应生成 反-1,2-二苯酰乙烯
参考文献:Diazoketones As Reagents For The Identification Of Organic Acids
标题:Diazoketones As Reagents For The Identification Of Organic Acids
摘要:
DOI:10.1021/ja01155A086

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合成方法参考DOI号:10.1021/ol4006344
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