CAS: 7693-26-7; Potassium Hydride

该化合物是一种无机化合物,其特点是形成一种白色至灰色的固体,这种固体特别对水具有高度反应性,由钾离子(K)和氢离子(H)组成,使其成为一个强大的基质和强大的减少剂.KH通常用于有机合成,特别是脱质反应和氢源.它与水分,释放氢气和形成氢氧化钾(可造成安全危害)发生强烈反应.该化合物的熔点很高,在液体氨中溶解,但在大多数有机溶剂中无法溶解.由于其反应性,氢化钾必须在惰性大气中处理,例如或氮,以防止不必要的反应.它的应用扩大到其他氢化物的生产,以及在需要强基的地方进行各种化学反应.在气密容器中适当储存对于保持其稳定性和防止降解至关重要.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

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hydrogen potassium

合成工艺路线路线简述

  • 合成目标产物 Potassium Hydride 主要起始原料 Hydrogen And Potassium
  • (文献来源)合成步骤主要原料 Hydrogen 和 Potassium
📜Potassium Hydroxide置于magnesium体系中,用 Neat (No Solvent) 作为反应溶剂,化学反应生成 氢化钾
参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: K: Mvol.1,10,Page 65-68
标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: K: Mvol.1,10,Page 65-68

专利信息


专利号:US-2009326281-A1
优先权日:2008-06-30
标题:Catalytic system and process for direct synthesis of dimethyl ether from synthesis gas
发明人:APPEL LUCIA GORENSTIN; DE FARIAS ANDREA MARIA DUARTE; ESTEVES ANGELA MARIA LAVOGADE; FRAGA MARCO ANDRE; RAMOS BARBOSA FLAVIA DE SOUZA; BORGES LUIZ EDUARDO PIZZARO; MONTEIRO JOSE LUIZ FONTES; HUERTAS FLORES JHONNY OSWALDO; DA SILVA MARIA ISABEL PAIS; SOUSA AGUIAR EDUARDO FALABELLA
权利人:PETROLEO BRASILEIRO SA; INT INST NAC DE TECNOLOGIA
摘要:A mixed-bed catalytic system and its activation for direct synthesis of dimethyl ether from synthesis gas are described, comprising a catalyst for methanol synthesis and the zeolite ferrierite in its acid form as the methanol dehydrating component, the two being mixed physically in the form of powder of defined granulometry or as pellets. Another object of the present invention is a process for production of the acid form of the zeolite ferrierite. Another object of the present invention is a process for direct synthesis of dimethyl ether from a synthesis gas, using the catalytic system of the present invention.

专利号:US-2007249874-A1
优先权日:2004-06-23
标题 :Synthesis of the Micro-Porous Silica Gel and Its Application to the Preparation of Catalysts for C2 Oxygenates Synthesis from Syngas
发明人:LUO HONGYUAN; DING YUNJIE; YIN HONGMEI
权利人:BP PLC
摘要:A synthesis of the micro-porous silica gel and its application to preparation of catalysts for C 2 oxygenates synthesis from syngas is invented. The small particles of silica gel which are, produced by sol gel process are heated in a basic solution, followed by drying and/or calcinations, and thus form micro-porous silica as catalyst support. The basic solution can be one or a mixed solution of hydroxides, carbonates, bicarbonates, formates and acetates of alkali metal and ammonium. The obtained micro-porous silica can be impregnated with the solutions of rhodium salt and other transition element salts (as promoter precursors), followed by drying and/or calcinations, thus forming a micro-porous silica supported rhodium based catalyst. The rhodium salt can be RhCl 3 or Rh(NO 3 ) 3 . The promoter precursors can be water-dissolvable transition metal salts, rare earth metals salts, alkali metal salts and alkali earth metal salts. The obtained catalysts show high activity and selectivity in the synthesis of C 2 -oxygenates by the hydrogenation of CO under mild process conditions.

专利号:US-2024075466-A1
优先权日:2021-04-09
标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites
发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE
权利人:UMICORE AG & CO KG
摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.

专利号:US-8350031-B2
优先权日:2008-06-02
标 题:Processes for the synthesis of levocetirizine and intermediates for use therein
发明人:RAO DHARMARAJ RAMACHANDRA; KANKAN RAJENDRA NARAYANRAO; GHAGARE MARUTI; CHIKHALIKAR SANDIP VASANT
权利人:CIPLA LTD; RAO DHARMARAJ RAMACHANDRA; KANKAN RAJENDRA NARAYANRAO; GHAGARE MARUTI; CHIKHALIKAR SANDIP VASANT
摘要:The present invention provides a compound of formula (IV) n nwherein R is Cl, Br, NO 2 , OH or OR′, and R′ is alkyl, and its use in the synthesis of levocetirizine, including its use in the synthesis of (−)-1-[(4-chlorophenyl)-phenylmethyl]piperazine, an intermediate useful in the synthesis of levocetirizine. The present invention also provides compounds (II) and (III) which are useful in the synthesis of compound (IV).

专利号:US-2024294462-A1
优先权日:2023-02-15
标题:Method for the Synthesis of Ionizable Lipids Using a Doubly Alkylated Intermediate
发明人:SAADATI FARIBA; TRAN HUY; CIUFOLINI MARCO; ATMURI N D PRASAD
权利人:NANOVATION THERAPEUTICS INC
摘要:Provided herein is a method for the preparation of ionizable, cationic amino lipids using a doubly alkylated nucleophilic intermediate to produce a ketone. The ketone, or a corresponding alcohol, is subjected to one or more synthesis steps to add an ionizable moiety thereto. The method can be advantageously employed for the synthesis of unsymmetrical analogues of the above lipids that would be considerably more difficult to make by alternative strategies. The method can also be used to prepare symmetrical ionizable, cationic amino lipids with fewer steps and/or with the use of fewer hazardous chemicals than known synthesis methods.

专利号:US-4078331-A
优先权日:1976-04-28
标题:Process and culture composition for growth of alga and synthesis of biopolymer
发明人:SAVINS JOSEPH GEORGE; PAUL JAMES M
权利人:MOBIL OIL CORP
摘要:This specification discloses a process and a culture composition for growth of an alga and synthesis of biopolymer by the alga. The process involves growth of the alga and concomitant synthesis of the biopolymer in an aqueous culture containing as a source of phosphate for said alga dibasic sodium or dibasic potassium phosphate. The nitrogen source can be sodium nitrate or urea. Control of the pH of the culture is effected by injecting a mixture of carbon dioxide and air into the culture during growth of the alga and synthesis of the biopolymer. The carbon dioxide also serves as a source of carbon for growth of the alga and synthesis of the biopolymer and provides agitation/mixing within the culture chamber. Preferably, the mixture of carbon dioxide and air is injected continuously into the culture during the entire growth period of the alga.

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📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Abell, A. D.; Edmonds, M. K., Science of Synthesis, (2009) 46, 49.
摘要:Rawal, V. H.; Kozmin, S. A., Science of Synthesis, (2009) 46, 1.
摘要:Black, D. A.; Fagnou, K., Science of Synthesis, (2010) 45, 562.
摘要:Abell, A. D.; Edmonds, M. K., Science of Synthesis, (2009) 46, 47.
摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 809.
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