
MSDS等安全信息
- GHS象形图


- GHS符号GHS08 & GHS09;
注释: Health hazard & Environment - 危险类别致癌性 类别1A
特定目标器官毒性-重复接触 类别1
呼吸道致敏 类别1
皮肤致敏 类别1
水生急性毒性 类别1
水生慢性毒性 类别1
急性毒性 类别4(经口) - 警示词Danger(危险)
- 危险描述H350 |可能致癌.
H372 |长期或反复接触损害器官.
H334 |吸入可能引起过敏或哮喘症状或呼吸困难.
H317 |可能引起皮肤过敏反应.
H400 |对水生生物毒性极大.
H410 |对水生生物毒性极大并具有长期持续影响.
H350i |May cause cancer by inhalation.
H302 |吞咽有害. - 防范说明P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P260-P264-P270-P314-P501-P273-P391-P501-P261-P285-P304+P341-P342+P311-P501
- 安全声明Nickel is known to substitute for other essential elements in certain enzmes, such as calcineurin. It is genotoxic, and some nickel compounds have been shown to promote cell proliferation. Nickel has a high affinity for chromatin proteins, particularly histones and protamines. The complexing of nickel ions with heterochromatin results in a number of alterations including condensation, DNA hypermethylation, gene silencing, and inhibition of histone acetylation, which have been shown to disturb gene expression. Nickel has also been shown to alter several transcription factors, including hypoxia-inducible transcription factor, activating transcription factor, and NF-KB transcription factor. There is also evidence that nickel ions inhibit DNA repair, either by directly inhibiting DNA repair enzymes or competing with zinc ions for binding to zinc-finger DNA binding proteins, resulting in structural changes in DNA that prevent repair enzymes from binding. Nickel ions can also complex with a number of cellular ligands including amino acids, peptides, and proteins resulting in the generation of oxygen radicals, which induce base damage, DNA strand breaks, and DNA protein crosslinks. (L41, A40)
- 危险类别码See Nickel and linked occupational diseases.
欧盟法规
统一分类与标签ECHA物质工作场所安全标识要求ECHA物质化妆品禁用物质清单C&L通报食品接触材料-禁用CMR物质REACH预注册废弃物危险特性清单专利信息
专利号:US-2014342177-A1
优先权日:2011-12-07
标 题 :Synthesis of cupronickel nanowires and their application in transparent conducting films
发明人:WILEY BENJAMIN
权利人:UNIV DUKE
摘要:A method of synthesis to produce a conductive film including cupronickel nanowires. Cupronickel nanowires can be synthesized from solution, homogeneously dispersed and printed to make conductive films (preferably < 1,000 Ω/sq) that preferably transmit greater than 60% of visible light.
专利号:US-5876587-A
优先权日:1995-12-29
标题 :Electrochemical synthesis of transition metal/phosphine catalysts
发明人:HORBEZ DOMINIQUE; HUSER MARC; PERRON ROBERT
权利人:RHONE POULENC CHIMIE
摘要:Catalyst compounds comprising at least one transition metal in an oxidation state of 0 to 1, and at least one monodentate or bidentate water-soluble phosphine, well suited for the hydrocyanation of ethylenically unsaturated compounds, are electrochemically synthesized, by electrolyzing an aqueous solution catholyte (contained in the cathode compartment of any suitable electrolytic cell) comprising at least one transition metal compound and at least one monodentate or bidentate water-soluble phosphine, advantageously at least one phosphine having the following formulae (I) and/or (II): P(Ar1)a(Ar2)b(Ar3)c(D1)d(D2)e(D3)f(I) (Ar1)a(Ar2)b(D1)d(D2)eP-L-P(Ar1)g(Ar2)h(D1)i(D2)j(II).
专利号:US-8920688-B2
优先权日:2008-06-18
标题:Microwave-assisted synthesis of transition metal phosphide
发明人:VISWANATHAN TITO
权利人:VISWANATHAN TITO; UNIV ARKANSAS
摘要:A method of synthesizing transition metal phosphide. In one embodiment, the method has the steps of preparing a transition metal lignosulfonate, mixing the transition metal lignosulfonate with phosphoric acid to form a mixture, and subjecting the mixture to a microwave radiation for a duration of time effective to obtain a transition metal phosphide.
专利号:WO-2010115199-A1
优先权日:2009-04-03
标 题:Microwave-assisted synthesis of transition metal phosphide
发明人:VISWANATHAN TITO
权利人:UNIV ARKANSAS; VISWANATHAN TITO
摘要:A method of synthesizing transition metal phosphide. In one embodiment, the method has the steps of preparing a transition metal lignosulfonate, mixing the transition metal lignosulfonate with phosphoric acid to form a mixture, and subjecting the mixture to a microwave radiation for a duration of time effective to obtain a transition metal phosphide.
专利号:US-7485741-B2
优先权日:2002-12-02
标 题:Method of producing nitrile compounds from ethylenically-unsaturated compounds
发明人:BOURGEOIS DAMIEN; GALLAND JEAN-CHRISTOPHE; DIDILLON BLAISE; MARION PHILIPPE
权利人:RHODIA POLYAMIDE INTERMEDIATES
摘要:The present invention relates to a process for hydrocyanating a hydrocarbon-based compound containing at least one ethylenic unsaturation by reaction in liquid medium with hydrogen cyanide in the presence of a catalyst comprising a metal element chosen from transition metals and an organophosphorus ligand, characterized in that the organophosphorus ligand is a monodentate organophosphorus compound. The present invention is in particular useful for the synthesis of adiponitrile from butadiene.
专利号:US-5679237-A
优先权日:1994-12-06
标题:Electrochemical synthesis of transition metal/phosphine catalyst compounds
发明人:CHAMARD ALEX; HORBEZ DOMINIQUE; HUSER MARC; PERRON ROBERT
权利人:RHONE POULENC FIBRES
摘要:Catalyst compounds comprising at least one transition metal having an oxidation number of 0 or 1 and at least one sulfonated phosphine are electrochemically synthesized, by electrolyzing an aqueous solution catholyte (contained in the cathode compartment of any suitable electrolytic cell) comprising at least one transition metal compound and at least one sulfonated phosphine.