CAS: 23108-72-7; Methyl(Triphenylphosphine)Gold(I)

该化合物是一个定义明确的有机体综合体,通常用于同质催化和有机合成,其主要优点包括在环境条件下高度稳定,Au(I)介质变异,如循环和混合反应等极佳的再活动.三联苯磷素离子和增强有机溶剂的溶解性,便利各种合成应用的处理.该复合体因其在黄金催化反应中的作用而特别受到重视,对选择性和效率提供了精确的控制.其精细的结构确保了研究和工业过程的再生性.在精细的化学合成中,它可用作在催化系统中生成活跃的金种的可靠前体.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

C&L通报

合成工艺路线路线简述

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    专利信息


    专利号:US-10384201-B2
    优先权日:2016-02-17
    标题:Direct synthesis method of nanostructured catalyst particles on various supports and catalyst structure produced by the same
    发明人：JEONG NAMJO; KIM CHAN-SOO; JWA EUN-JIN; CHOI JI YEON; NAM JOO-YOUN; PARK SOON-CHUL; JANG MOON-SEOK; SEO YONG SEOK; HWANG KYO SIK; KIM HAN KI; HAN JI HYUNG; KIM TAE YOUNG; YOON YOUNG GI
    权利人:KOREA INST ENERGY RES
    摘要:Disclosed is a direct synthesis method of nanostructured catalyst particles on surfaces of various supports. In the disclosed synthesis method of a catalyst structure having a plurality of nanostructured catalyst particles dispersed in a support by a one-step process using a high-temperature high-pressure closed reactor, the one-step process includes supplying the support and a catalyst source into the high-temperature high-pressure closed reactor; supplying an atmosphere forming gas of the reactor into the reactor; perfectly sealing the high-temperature high-pressure closed reactor and heating the reactor to produce the catalyst structure in the reactor under self-generated pressure and synthesis temperature conditions, the catalyst structure including the plurality of nanostructured catalyst particles dispersed in the support; removing internal gases of the reactor to allow the reactor to be in a high-temperature, atmospheric pressure state and supplying an inert gas into the reactor to remove unreacted materials and byproducts remaining in the reactor; and cooling the reactor to room temperature while supplying the inert gas to synthesize the catalyst structure.

    专利号:EP-3207991-B1
    优先权日:2016-02-17
    标 题:Direct synthesis method of a catalyst structure having nanostructured catalyst particles dispersed in a support
    发明人：JEONG NAMJO; KIM CHAN-SOO; JWA EUN-JIN; CHOI JI YEON; NAM JOO-YOUN; PARK SOON-CHUL; JANG MOON-SEOK; SEO YONG SEOK; HWANG KYO SIK; KIM HAN KI; HAN JI HYUNG; KIM TAE YOUNG; YOON YOUNG GI
    权利人:KOREA INST ENERGY RES

    专利号:US-2017232431-A1
    优先权日:2016-02-17
    标 题 :Direct synthesis method of nanostructured catalyst particles on various supports and catalyst structure produced by the same

    专利号:EP-3207991-A1
    优先权日:2016-02-17
    标 题:Direct synthesis method of nanostructured catalyst particles on various supports and catalyst structure produced by the same

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    合成参考文献


    摘要:Kantchev, E. A. B.; Organ, M. G., Science of Synthesis, (2009) 48, 83.
    摘要:Celik, I.; Hummel, S.; Kirsch, S. F., Science of Synthesis Knowledge Updates, (2019) 1, 23.
    摘要:Hopkinson, M. N.; Gouverneur, V., Science of Synthesis Knowledge Updates, (2011) 2, 124.
    摘要:López-Carrillo, V.; Echavarren, A. M., Science of Synthesis Knowledge Updates, (2011) 2, 24.
    摘要:Ipaktschi, J.; Saidi, M. R., Science of Synthesis Knowledge Updates, (2011) 3, 375.
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