专利号:US-2024075466-A1 优先权日:2021-04-09 标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites 发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE 权利人:UMICORE AG & CO KG 摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.
专利号:US-11718536-B2 优先权日:2020-07-29 标题 :Solvent-free synthesis of lanthanide oxide and mixed lanthanide oxide nanoparticles 发明人:Treadwell LaRico Juan; BREGMAN AVI GABRIEL; RINGGOLD MARISSA 权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC 摘要:Lanthanide oxides and mixed lanthanide oxides can be produced using furnace or microwave assisted solid-state synthesis. The use of Ln-tri(methylsilyl)amide-based precursors yields spherical nanoparticles. The formation of spherical shaped nanoparticles is likely due to the preferential single-step decomposition of the Ln-TMS as well as the low activation energy to overcome decomposition. Reaction temperature, initial metal ion ratio, and reaction dwell time can be used to control the final nanoparticle size. The method enables solvent-free, high-yield synthesis of morphology-controlled lanthanide oxides.
专利号:US-2023295102-A1 优先权日:2020-08-11 标 题 :A process for preparation of 2, 5-furan dicarboxylic acid from 5-hydroxymethyl furfural 发明人:DHEPE PARESH LAXMIKANT; SONONE KALYANI GAJANANRAO; LOKHANDE PRIYA LAXMANRAO 权利人:COUNCIL SCIENT IND RES 摘要:The present invention provides a process for the synthesis of furan dicarboxylic acid (FDCA) from glucose or crude hydroxy methyl furfural (HMF) using mixed metal oxides catalyst. The present invention further provides a process for preparation of the mixed metal oxides catalyst.
专利号:US-11773046-B2 优先权日:2020-05-11 标题:Solvothermal synthesis of metal alkanoate and metal oxide nanoparticles 发明人:Treadwell LaRico Juan; DAVIS-WHEELER CLARE 权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC 摘要:A facile solvothermal method can be used to synthesize metal alkanoate nanoparticles using a metal nitrate precursor, alcohol/water, and alkanoic acid. The method can produce lanthanide (e.g., La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, or Yb) and transition metal (e.g., Ag, Co, Cu, or Pb) alkanoate nanoparticles (<100 nm) with spherical morphology. These hybrid nanomaterials adopt a lamellar structure consisting of inorganic metal cation layers separated by an alkanoate anion bilayer and exhibit liquid crystalline phases during melting. The metal alkanoate nanoparticles can be calcined to produce metal oxide nanoparticles.
专利号:WO-2024228414-A1 优先权日:2023-05-04 标 题 :Catalyst for ammonia synthesis which exhibits high activity under low-pressure and low-temperature conditions, and ammonia synthesis method using same 发明人:CHO KANGHEE; YOON HYUNG-CHUL; KIM SUN HYUNG; JU HYUNG KUK; BEUM HEE-TAE; JEON SANG-GOO; LEE KI BONG 权利人:KOREA INST ENERGY RES 摘要:The present invention relates to a catalyst for ammonia synthesis including a cocatalyst, and an ammonia synthesis method using same. According to the catalyst material of the present invention and the method for preparing same, ammonia can be synthesized with high efficiency at a lower temperature and pressure compared to those of conventional commercial Haber-Bosch processes, and thus the present invention has the effects of significantly reducing process energy consumption and carbon dioxide emissions.
专利号:US-2025296842-A1 优先权日:2022-06-07 标题:Integrated production of thiophene and carbon nanotubes 发明人:CAO GUANG; WANG KUN; NANDI PARTHA; BOSSE AUGUST W; GRANKINA VERA 权利人:EXXONMOBIL TECHNOLOGY & ENGINEERING COMPANY 摘要:Systems and methods are provided for integrated production of both thiophene (and/or substituted thiophenes) and carbon nanotubes. The product effluent from thiophene synthesis can include thiophene, a sulfur-containing organic compound, and unreacted hydrocarbons from the thiophene synthesis process. Such a product effluent can be used as a feed for carbon nanotube synthesis. The effluent provides hydrocarbons for pyrolysis to form H2 and carbon. Additionally, the thiophene provides sulfur that can be used for in-situ catalyst formation for formation of carbon nanotubes.
[参考文献]: B Mandal, Et Al. Laser Photoacoustic Spectra Of Sm3+ Ion In Sm2O3 And Smcl3.6H2O In The Spectral Profile 484-542 Nm. Spectrochim Acta A Mol Biomol Spectrosc. 2004 Mar;60(4):933-9. [参考文献]: Guohui Zhang, Et Al. Measurement Of Cross Sections For The 147Sm(N, Alpha)144Nd Reaction At 5.0 And 6.0 Mev. Appl Radiat Isot. 2009 Jan;67(1):46-9. [参考文献]: H M T U Herath, Et Al. In Vitro Evaluation Of Samarium (Iii) Oxide As A Bone Substituting Material. J Biomed Mater Res A. 2010 Jul;94(1):130-6. [参考文献]: Janne Marvola, Et Al. Neutron Activation-Based Gamma Scintigraphy In Pharmacoscintigraphic Evaluation Of An Egalet Constant-Release Drug Delivery System. Int J Pharm. 2004 Aug 20;281(1-2):3-10. [参考文献]: Lloyd G Tillman, Et Al. Oral Delivery Of Antisense Oligonucleotides In Man. J Pharm Sci. 2008 Jan;97(1):225-36.
合成参考文献
摘要:Chciuk, T. V.; Flowers, R. A.; Flowers, R. A., Science of Synthesis Knowledge Updates, (2016) 2, 184.