CAS: 14996-60-2; Osmium(Iii) Chloride Hydrate

该化合物是一种过渡性金属化合物,用于催化,材料科学和合成化学,其主要优点包括它作为复合物的前体的作用,在氧化反应和协调化学方面很有价值;水合物形式提高了极地溶剂的溶解性,促进了同质反应;由于它的红氧化作用特性,还使用(III)氯化物来制作薄膜和导体材料;高纯度确保研究和工业应用的一贯性;由于其湿度敏感度和潜在毒性,需要妥善处理;建议在惰性条件下进行储存以保持稳定性.

结构式图片

相似化合物

13444-93-4

欧盟法规

C&L通报

合成工艺路线路线简述

    📜Osmium(Iii,Iv) Chloride,Potassium Chloride 以 乙醇 用作溶剂,化学反应生成Potassium Hexachloroosmate(Iv),氯化锇三水合物
    参考文献:Moraht,H.; Wischin,C.,Zeitschrift Fur Anorganische Chemie,1893,Vol. 3,P. 167-175
    标题:Moraht,H.; Wischin,C.,Zeitschrift Fur Anorganische Chemie,1893,Vol. 3,P. 167-175

    专利信息


    专利号:WO-2009077719-A1
    优先权日:2007-12-17
    标 题:Process for the conversion of hydrocarbons to ethanol
    发明人:DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK; SUNLEY JOHN GLENN
    权利人:BP P I C; DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK; SUNLEY JOHN GLENN
    摘要:The present invention relates to a process for producing ethanol, and optionally methanol, from synthesis gas. In particular the present invention relates to a process for producing ethanol from a carbonaceous feedstock; wherein the carbonaceous feedstock is first converted to synthesis gas which is then converted to methanol which is then converted to dimethyl ether which is then converted to methyl ethanoate, which is then hydrogenated to produce ethanol in the same alcohol synthesis unit used for converting the said synthesis gas to methanol.

    专利号:US-7947746-B2
    优先权日:2007-12-17
    标题:Process for the conversion of hydrocarbons into ethanol
    发明人:DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK; SUNLEY JOHN GLENN
    权利人:BP PLC
    摘要:Process for converting synthesis gas to ethanol, including the steps of 1) introducing synthesis gas, together with methyl ethanoate and/or ethyl ethanoate, into an alcohol synthesis unit to produce methanol and ethanol, 2) separating the methanol from the ethanol of step 1, 3) introducing methanol, from step 2, together with CO, into a carbonylation unit in the presence of a methanol carbonylation catalyst, to produce ethanoic acid, and 4) introducing ethanoic acid, from step 3, together with methanol and/or ethanol, into an esterification unit to produce methyl ethanoate and/or ethyl ethanoate. In step 5), methyl ethanoate and/or ethyl ethanoate, produced in step 4, are fed into the alcohol synthesis unit of step 1, and in step 6) ethanol from step 2 is recovered.

    专利号:WO-2009077725-A1
    优先权日:2007-12-17
    标 题:Process for the production of ethanol from a carbonaceous feedstock
    发明人:DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK; SUNLEY JOHN GLENN
    权利人:BP P I C; DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK; SUNLEY JOHN GLENN
    摘要:A process for the production of ethanol (and optionally methanol) from a carbonaceous feedstock; wherein the methyl ethanoate (produced by a multi-step process from the carbonaceous feedstock) is hydrogenated to produce ethanol within the same alcohol synthesis unit and in the presence of the same catalyst(s) that is used to produce methanol from the said synthesis gas.

    专利号:WO-2009077729-A1
    优先权日:2007-12-17
    标题:Process for the production of ethanol from a carbonaceous feedstock
    发明人:DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK
    权利人:BP P I C; DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK
    摘要:The present invention relates to a process for the production of ethanol from a carbonaceous feedstock; wherein the carbonaceous feedstock is first converted to synthesis gas which is then converted to methanol which is then converted to methyl ethanoate, which is then hydrogenated to produce ethanol.

    专利号:US-9217088-B2
    优先权日:2006-08-03
    标 题:Particles and inks and films using them
    发明人:PARASHAR SACHIN; SARKAR SIULI; KHASELEV OSCAR; LEWIS BRIAN G; MARCZI MICHAEL T; SINGH BAWA; DESAI NITIN; LIBERATORE MICHAEL
    权利人:PARASHAR SACHIN; SARKAR SIULI; KHASELEV OSCAR; LEWIS BRIAN G; MARCZI MICHAEL T; SINGH BAWA; DESAI NITIN; LIBERATORE MICHAEL; ALPHA METALS
    摘要:Particles and particle films are provided. In certain examples, particles produced from a single phase process may be used to provide industrial scale synthesis of particles for use in devices such as printed wiring boards.

    专利号:US-8907140-B2
    优先权日:2007-11-14
    标 题 :Process for the production of alcohol from a carbonaceous feedstock
    发明人:DANIEL BERIAN JOHN; DEELEY JON MICHAEL STEWART; GRACEY BENJAMIN PATRICK; LI CONG RONG
    权利人:BP PLC
    摘要:The present invention relates to an improved process for the production of ethanol from a carbonaceous feedstock; wherein the carbonaceous feedstock is first converted to synthesis gas which is then converted to ethanoic acid, which is then esterified and which is then hydrogenated to produce ethanol.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/s00769-020-01437-5
    摘要:Asakai T. Consideration in potential titration paths to assay osmium compounds: toward the establishment of the mono-elemental standard solution. Accreditation and Quality Assurance. 2020 Jul 11;25(4):293–302. doi: 10.1007/s00769-020-01437-5.
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