CAS: 7790-33-2; Manganese(Ii) Iodide

该化合物是一种无机化合物,由加2氧化状态中的锰组成,结合成两个碘原子,通常是粉色至褐色晶状固体,在水和极有机溶剂中可溶解. MnI2主要用作合成化学的前体,特别是用于制造锰复合物和催化剂. 它的高活性和碘含量使其在有机转化中具有价值,例如C-I债券形成.该化合物还用于材料科学,用于合成锰纳米材料. 适当处理是必要的, 因为它对水分敏感, 在某些条件下可能释放碘.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

manganese iodine aluminium(III) iodide manganese(IV) oxide6H5)4(1+)*MnI3(C4H8O)(1-)=(C6H5)4PMnI3(C4H8O)P(C6H5)4(1+)*MnI3(C4H8O)(1-)=(C6H5)4PMnI3(C4H8O) 2(P(C6H5)2CH3)2}{MnI2(P(C6H5)2CH3)2}

合成工艺路线路线简述

    📜锰,碘置于al体系中,用 Neat (No Solvent) 作为反应溶剂,化学反应生成 无水碘化锰(II),
    参考文献:Schiefenhoevel; Binnewies; Janetzko,Zeitschrift Fur Anorganische Und Allgemeine Chemie,2001,Vol. 627,# 7,P. 1513-1517
    标题:Schiefenhoevel; Binnewies; Janetzko,Zeitschrift Fur Anorganische Und Allgemeine Chemie,2001,Vol. 627,# 7,P. 1513-1517

    专利信息


    专利号:US-2025197439-A1
    优先权日:2022-03-18
    标 题:Decarboxylative acetoxylation using mn(ii) or mn(iii) reagent for synthesis of 4'-acetoxy-nucleoside and use thereof for synthesis of corresponding 4'-(dimethoxyphosphoryl)methoxy-nucleotide
    发明人:VAGLE KURT EDRIC; BHADURI SAYANTAN; YANG GUOHAN
    权利人:DICERNA PHARMACEUTICALS INC
    摘要:The present invention relates to the preparation of nucleic acids, nucleosides, nucleotides, and analogues thereof useful as potent and stable RNA interference agents. The present invention provides improved yields and avoids the use of lead tetraacetate for decarboxylative acetylation which decreases the overall cost of production by removing the need for lead remediation and offers a significant reduction in the environmental costs in production.

    专利号:US-11274247-B2
    优先权日:2017-02-02
    标题:Methods for the synthesis of transition metal dichalcogenide (TMDC) nanoparticles
    发明人:DANIELS STEVEN
    权利人:NANOCO TECHNOLOGIES LTD
    摘要:Methods of synthesizing transition metal dichalcogenide nanoparticles include forming a metal-amine complex, combining the metal-amine complex with a chalcogen source in at least one solvent to form a solution, heating the solution to a first temperature for a first period of time, and heating the solution to a second temperature that is higher than the first temperature for a second period of time.

    专利号:EP-4493568-A1
    优先权日:2022-03-18
    标 题 :Decarboxylative acetoxylation using mn(ii) or mn(iii) reagent for synthesis of 4'-acetoxy- nucleoside and use thereof for synthesis of corresponding 4'-(dimethoxyphosphoryl)methoxy- nucleotide

    专利号:WO-2023177866-A1
    优先权日:2022-03-18
    标题 :Decarboxylative acetoxylation using mn(ii) or mn(iii) reagent for synthesis of 4'-acetoxy- nucleoside and use thereof for synthesis of corresponding 4'-(dimethoxyphosphoryl)methoxy- nucleotide

    专利号:US-2025270101-A1
    优先权日:2023-06-07
    标 题:Catalyst-Sorbent Structure for Ammonia Synthesis And Sorption and Method of Ammonia Production
    发明人:GILBERT TRISTAN; BAERT KAREN; TONKOVICH LEE
    权利人:AMMOBIA INC
    摘要:An active catalyst for ammonia synthesis is integrated with a specialty sorbent in a composition or composite, such that the catalyst portion and the sorbent portion are in direct intimate contact, which overcomes the thermodynamic limits for conversion. The sorbent may comprise a metal halide absorbent, zeolite adsorbent, other material absorbents or adsorbents, to capture ammonia as it is produced in intimate or near molecular contact with the catalyst, wherein the composition/composite may be provided in the form of a granular or pellet structure. By removing ammonia essentially as it forms, the forward reaction for producing ammonia can continue nearly unabated such that high net conversion can be achieved in a single pass or cumulative within segmented reactors as operated in series.

    专利号:CN-118891266-A
    优先权日:2022-03-18
    标题:Decarboxylation acetoxylation using Mn (II) or Mn (III) reagent for synthesis of 4 '-acetoxy-nucleoside and use thereof for synthesis of corresponding 4' - (dimethoxyphosphoryl) methoxy-nucleotide

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Oshima, K., Science of Synthesis, (2003) 2, 48.
    摘要:Oshima, K., Science of Synthesis, (2003) 2, 52.
    摘要:Oshima, K., Science of Synthesis, (2003) 2, 58.
    摘要:Oshima, K., Science of Synthesis, (2003) 2, 41.
    摘要:Gribble, G. W., Science of Synthesis, (2006) 8, 410.
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