CAS: 13825-76-8; Holmium(Iii) Bromide

上下游产品

hydrogen bromide bromine aluminium bromide N,N-dimethyl acetamide5H2N(C6H5))4}(Br)Ho{(C5H2N(C6H5))4} Ho(III)(dibenzylsulphoxide)5(bromide)3 18H17N3O2)2Br2](1+)*Br(1-) = [Ho(C18H17N3O2)2Br2]Br[Ho(C18H17N3O2)2Br2](1+)*Br(1-) = [Ho(C18H17N3O2)2Br2]Br

📜[ho(Water)8](Br)3 以 Neat (No Solvent,Solid Phase) 用作溶剂,以99%的收率获得溴化钬
参考文献:甲醇取代的卤化镧的结构表征
标题:甲醇取代的卤化镧的结构表征
摘要:使用甲醇(meoh)进行了卤化镧[lax(3)]衍生物的醇溶化作为降低labr(3)闪烁体生产温度的一种手段的首次研究.最初,通过在室温下简单地将1溶解在meoh中,研究了{[la(micro-Br)(h(2)o)(7)](br)(2)}(2)(1)的脱水.分离出混合的溶剂化物单体[la(h(2)o)(7)(meoh)(2)](br)(3)(2)化合物,其中la金属中心通过与两种其他的meoh溶剂,但必须将内球br转移到外球.为了尝试将1的甲醇中的反应混合物在cah(2)上干燥,分离了[ca(meoh)(6)](br)(2)(3)的晶体.在回流温度下将化合物1溶解在meoh中,导致分离出异常结构,该结构被确定为盐衍生物{[labr(2.75)* 5.25(meoh)](+ 0.25)[labr(3.25)* 4.75(meoh)](-0.25)}(4).最终,通过将干燥的labr(3)溶
Doi:10.1016/j.Poly.2010.02.027

专利信息

专利号:US-12209104-B1
优先权日:2018-07-11
标 题:Metal complexes and methods of making the same
发明人：KIPLINGER JAQUELINE; BEATTIE ROSS; PAGANO JUSTIN; ERICKSON KARLA
权利人:TRIAD NAT SECURITY LLC
摘要:Disclosed herein are embodiments of metal complexes and methods of making the same. The disclosed method embodiments provide a one-step approach to making metal complexes, such as complexes comprising lanthanide metals, rare earth metals, transition metals, main group metals, and/or actinide metals that can be used various applications, such as in separations technology, catalysis (e.g., catalysts for pharmaceutical synthesis and/or catalysts for biomass conversion), nuclear chemistry, LED phosphors, scintillator materials, magnetic materials, and nuclear fuels.