CAS: 3406-03-9; 1-Phenyl-2-(Phenylsulfonyl)Ethanone

上下游产品

methylphenylsulfonate benzoic acid ethyl ester β-phenyl-β-hydroxyethyl phenyl sulfone 2-chloro-1-phenyl-2-(phenylsulfonyl)ethanone α-phenylsulfonyl (3,4-dioxymethylene chalcone) β-phenyl-β-hydroxyethyl phenyl sulfone benzenesulfonyl-acetic acid anilide cis-chalconeα-benzenesulfonyl-4-methyl-cis-chalcone

📜Phosphoric Acid Diethyl Ester-(1-Phenyl-Vinyl Ester)置于水,氧气体系中,用 二氯甲烷 用作溶剂,化学反应 3.5H,反应生成2-(苯基磺酰)苯乙酮
参考文献:水中活化烯烃的无催化剂双官能化:β-酮基硫化物和砜的高效合成
标题:水中活化烯烃的无催化剂双官能化:β-酮基硫化物和砜的高效合成
摘要:直接合成一系列β-酮硫醚和β-酮砜的化学合成中,有效的策略是活化烯烃的双官能团化.由o 2介导的转化在水中顺利进行且没有任何催化剂.该方法的显着优势包括温和的反应条件,纯化简便和克级合成,这突显了该方法的实际实用性.
Doi:10.1002/chem.201603041

专利信息

专利号:EP-1105359-B1
优先权日:1998-08-21
标 题:Solid phase synthesis of compounds by carbon-carbon bond forming mitsunobu reactions
发明人：CHATURVEDI SURENDRAKUMAR
权利人:PE CORP NY
摘要:Processes are provided for the Mitsunobu alkylation reaction of carbon-carbon bond formation between a solid support reagent and a reagent in solution. The resulting novel products can be prepared as a combinatorial library by high-throughput, parallel synthesis under robotic automation. Cleaved or support-bound products are useful precursors to biologically active compounds.

专利号:US-8236853-B1
优先权日:2007-12-03
标题 :Formation of cyclopentene nitro-ester and derivatives
发明人：BISHT KIRPAL S; KHAN PASHA M; VAN OLPHEN ALBERTO; WU RUIZHI
权利人:BISHT KIRPAL S; KHAN PASHA M; VAN OLPHEN ALBERTO; WU RUIZHI; UNIV SOUTH FLORIDA
摘要:Disclosed is a method of synthesizing new optically pure heterocyclic compounds using Pd(0) catalyzed intramolecular cyclizations. Analogs of cyclopentanes, like isoxazoline-2-oxide and furan, with similar framework to the cyclopentanes act as anti-HIV and anticancer agents which opens a whole new field for application of these compounds. Starting from a meso-diol, optically pure compounds were prepared without utilizing chiral ligands at any stage of the synthesis. The stereochemical outcome of the product (>99% ee) was influenced by desymmetrization catalyzed by Pseudomonas cepacia lipase and the stereoselective nature of the palladium catalyzed transformations.

专利号:WO-0010942-A1
优先权日:1998-08-21
标题:Solid phase synthesis of compounds by carbon-carbon bond forming mitsunobu reactions

专利号:DE-69903740-T2
优先权日:1998-08-21
标 题 :SOLID PHASE SYNTHESIS OF COMPOUNDS BY MEANS OF SUNOBU REACTIONS WITH THE FORMATION OF CARBON CARBON BONDINGS

专利号:US-8318804-B2
优先权日:2007-12-10
标题:Antiviral activity of cyclopentene nitro-ester and derivatives
发明人：BISHT KIRPAL S; VAN OLPHEN ALBERTO; KHAN PASHA M; BUCHER CYNTHIA
权利人:BISHT KIRPAL S; VAN OLPHEN ALBERTO; KHAN PASHA M; BUCHER CYNTHIA; UNIV SOUTH FLORIDA
摘要:Disclosed is a method of synthesizing new optically pure heterocyclic compounds using Pd(0) catalyzed intramolecular cyclizations. Analogs of cyclopentanes, like isoxazoline-2-oxide and furan, with similar framework to the cyclopentanes act as anti-HIV and anticancer agents which opens a whole new field for application of these compounds. Starting from a meso-diol, optically pure compounds were prepared without utilizing chiral ligands at any stage of the synthesis. The stereochemical outcome of the product (>99% ee) was influenced by desymmetrization catalyzed by Pseudomonas cepacia lipase and the stereo selective nature of the palladium catalyzed transformations.

专利号:KR-20090102733-A
优先权日:2006-12-27
标 题 :Method for synthesis of hyperbranched polymer, hyperbranched polymer, resist composition, semiconductor integrated circuit, and method for production of semiconductor integrated circuit