CAS: 6396-07-2; Diiodotriphenylphosphorane

该化合物是有机磷化合物,其独特结构包括三联苯基组和两个碘原子,其特点是有机磷原子,该化合物一般是黄色至橙色固体,以其在有机合成中作为试剂的作用而著称,特别是在形成碳-碳链方面.二碘三联苯磷磷是一种很强的核素,可以参与各种反应,包括维蒂格反应,它促进碳基化合物转化成藻类.其再活动可归因于磷原子的存在,它能够稳定负电荷,使其成为合成途径的有效中间体.此外,该化合物对湿度敏感,应在水性条件下处理,以保持其稳定性.

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84591-80-0 18437-78-0 4576-56-1

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上下游产品

pentaphenylphosphorane triphenylphosphine trimethylsilyl iodide dichlorotriphenylphosphoranemanganese(II) iodide 2(P(C6H5)3)2MnI2(P(C6H5)3)2 diiodobis(triphenylphosphine)zinc zinc(II) iodide

合成工艺路线路线简述

    📜二溴三苯基膦置于碘代三甲硅烷体系中,用 二氯甲烷 作为反应溶剂,化学反应 1.5H,以86%的收率获得产物三苯基膦二碘化物
    参考文献:Applications Of Iodotrimethylsilane For The Synthesis Of Iodophosphines,Iodophosphoranes,And Iodomethylphosphine Oxides
    标题:Applications Of Iodotrimethylsilane For The Synthesis Of Iodophosphines,Iodophosphoranes,And Iodomethylphosphine Oxides
    摘要:
    DOI:10.1055/s-1980-29222

    海关参考信息

    专利信息


    专利号:US-4503254-A
    优先权日:1982-03-24
    标 题:Process for making bis(halophenyl)hexafluoropropanes
    发明人:KELLEGHAN WILLIAM J
    权利人:HUGHES AIRCRAFT CO
    摘要:A new process for preparing diphenyl derivatives of hexafluoropropane containing halogen substituents on the phenyl rings and new halogen-substituted diphenyl derivatives of hexafluoropropane prepared thereby are disclosed. The new compounds of this invention are useful as intermediates for the synthesis of high temperature polymer systems.

    专利号:US-6506701-B1
    优先权日:1996-05-03
    标题:Rapid purification by polymer supported quench
    发明人:BOLTON GARY L; BOOTH RICHARD J; CRESWELL MARK W; HODGES JOHN C; WARMUS JOSEPH S; WILSON MICHAEL W
    权利人:WARNER LAMBERT CO
    摘要:Novel polymer-supported quenching reagents of Formula I,whereinP is a polymer of low chemical reactivity which is soluble or insoluble;Q is one or more quenching reagents, or an acid or base addition salts thereof, that are capable of selective covalent reaction with unwanted byproducts, or excess reagents; andL is one or more chemically robust linkers that join P and Q;are described, as well as methods for their preparation and methods for their use in the rapid purification of synthetic intermediates and products in organic synthesis, combinatorial chemistry and automated organic synthesis.

    专利号:WO-0039055-A1
    优先权日:1998-12-23
    标 题:Rapid purification by polyaromatic quench reagents
    发明人:DA SILVA MARIANNE; DOWNING DENNIS MICHAEL; WARMUS JOSEPH SCOTT; ZHANG LU-YAN
    权利人:WARNER LAMBERT CO; DA SILVA MARIANNE; DOWNING DENNIS MICHAEL; WARMUS JOSEPH SCOTT; ZHANG LU YAN
    摘要:Novel polyaromatic hydrocarbon quenching reagents of Formula (I), wherein: P is a polyaromatic hydrocarbon of low chemical reactivity which is soluble; Q is one or more quenching reagents, or an acid or base addition salts thereof, that are capable of selective covalent reaction with unwanted byproducts, or excess reagents; and L is one or more chemically robust linkers or dendritic linkers that join P and Q; are described, as well as methods for their preparation and methods for their use in the rapid purification of synthetic intermediates and products in organic synthesis, combinatorial chemistry and automated organic synthesis.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 841.
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