CAS: 14014-88-1; Ruthenium Tribromide

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CAS号20427-56-9 四氧化钌 | CAS号10035-10-6 氢溴酸 | CAS号7726-95-6 溴素 | CAS号7440-18-8 钌 | CAS号1304-29-6 过氧化钡 | CAS号7726-95-6 溴素 | CAS号7440-18-8 钌

📜溴,钌 以 Neat (No Solvent) 用作溶剂,化学反应生成溴化钌(III)
参考文献:关于具有 Tii3 链结构的三卤化物:通过温度相关的单晶 X 射线分析证明 α-Rucl3 和 Rubr3 中的阳离子对
标题:关于具有 Tii3 链结构的三卤化物:通过温度相关的单晶 X 射线分析证明 α-Rucl3 和 Rubr3 中的阳离子对
摘要:在不同温度下对 β-Rucl3 和 Rubr3 进行的单晶 X 射线研究证实,这两种化合物都是二晶型的,并在 206 K 时显示出可逆的相变.384 K.置于ht 形式中,六方 Tii3 结构的 Aristo 型,空间群为 P63/mcm (Z = 2,β-Rucl3 At 293(2) K: A = 6.121(2) A,C =5.655 (2) A,Rubr3 At 423(3) K: 6.5215(12) A,C= 5.8851(13) A) 已发现,在 Lt 形式的 Rubr3 型结构中,具有空间群 Pmmn 的正交扭曲变体(Z = 4,β-Rucl3置于170(3) K: A= 10.576(2) A,B = 5.634(1) A,C = 6.106(1) A,Rubr3置于293(2) K: A = 11.2561 (16)A,B = 5.8725(12)A,C
Doi:10.1002/zaac.200400106

专利信息

专利号:WO-2023039068-A1
优先权日:2021-09-08
标题:Compositions and methods for synthesis of peptide nucleic acid intermediates
发明人：COULL JAMES M; GILDEA BRIAN D
权利人:NEUBASE THERAPEUTICS INC
摘要:The present disclosure provides intermediates for the synthesis of peptide nucleic acid (PNA) backbones and monomers, such as cyclic intermediates, and methods of making the same.

专利号:US-4497910-A
优先权日:1981-07-28
标题 :Process for methane synthesis by catalytic reduction of carbon monoxide in aqueous phase
发明人：QUANG DANG V; SUGIER ANDRE; COMMEREUC DOMINIQUE; CHAUVIN YVES
权利人:INST FRANCAIS DU PETROLE
摘要:Process for the catalytic synthesis of methane by reaction of carbon oxides with hydrogen in the presence of liquid water, wherein the catalyst is formed of a carrier consisting either of coal or charcoal, preferably of plant origin, or of alumina-silica, on which is deposited ruthenium, for example by impregnation with ruthenium acetylacetonate, said catalyst being preferably used as particles suspended in water.

专利号:US-4219684-A
优先权日:1979-04-02
标 题 :Synthesis of alcohols by hydroformylation with nitrile promoter
发明人：IMAI TAMOTSU
权利人:UOP INC
摘要:Alcohols may be synthesized by reacting an olefinic compound, carbon monoxide and hydrogen in the presence of a Group VIII organometallic complex catalyst at reaction conditions which include a temperature in the range of from about 50° to about 250° C. and a pressure in the range of from about 10 to about 300 atmospheres. In addition, the reaction is also effected in the presence of a promoter compound comprising a nitrile.

专利号:US-2004127584-A1
优先权日:2002-12-31
标题 :Chemical vapor deposition synthesis of polymerization catalyst composition
发明人：KALLENBACH LYLE R
权利人:PHILLIPS PETROLEUM CO
摘要:A catalyst composition and a process of using a catalyst composition for preparing high molecular weight hydrocarbons, such as polymethylene, from a fluid containing hydrogen and carbon monoxide are disclosed. The catalyst composition contains ruthenium and a support component. The ruthenium is initially present as ruthenium tetraoxide provided by contacting a ruthenium component and an oxidizing agent to provide the ruthenium tetraoxide that is deposited under a depositing condition on, in, or with the support component.

专利号:US-6548688-B1
优先权日:1999-05-25
标 题:Diammonium ruthenium diethylenethriaminepentaacetate or hydrates thereof and process for the preparation of both
发明人：NAMBU NOBUYOSHI; NAKAMURA ATSUSHI; ITO HIROSHI
权利人:CHUBU CHELEST CO LTD; CHELEST CORP
摘要:Diammonium ruthenium diethylenetriaminepentaacetate represented by formula (1) or hydrate thereof, which are water-soluble and excellent in handling and exhibit such high stability both in the air and in an aqueous solution as to withstand long-term storage. These novel compounds are useful as the catalyst for the synthesis of ammonia, the hydrogenation catalyst for carbonyl compounds or aromatic compounds, the raw material for the production of ruthenium-base metal oxide ceramics, and so on.

专利号:WO-2009077719-A1
优先权日:2007-12-17
标 题:Process for the conversion of hydrocarbons to ethanol
发明人：DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK; SUNLEY JOHN GLENN
权利人:BP P I C; DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK; SUNLEY JOHN GLENN
摘要:The present invention relates to a process for producing ethanol, and optionally methanol, from synthesis gas. In particular the present invention relates to a process for producing ethanol from a carbonaceous feedstock; wherein the carbonaceous feedstock is first converted to synthesis gas which is then converted to methanol which is then converted to dimethyl ether which is then converted to methyl ethanoate, which is then hydrogenated to produce ethanol in the same alcohol synthesis unit used for converting the said synthesis gas to methanol.