a -Amyrin CAS Registry Number: 638-95-9 α-香树脂醇
CAS Name: (3b)-Urs-12-en-3-ol
Additional Names: a-amyrenol; viminalol
Percent Composition: C 84.44%, H 11.81%, O 3.75%
📌 参考资料/链接:
Literature References: Occurs mostly as acetate in latex of rubber trees, in latex from Ficus variegata Blume, Moraceae, also in Balanophora elongata Blume, Balanophoraceae, and in Erythroxylum coca Lam. var. novogranatense Morris, and var. spruceanum Burck, Erythroxylaceae. Isoln from Manila elemi: Vesterberg, Westerlind, Ann. 428, 247 (1922). Structural studies: Spring, Vickerstaff, J. Chem. Soc. 1937, 249; Beynon et al., ibid. 1938, 1233; Meisels et al., Helv. Chim. Acta 32, 1075 (1949), 38, 1298 (1955); Melera et al., ibid. 39, 441 (1956). Identity with viminalol: Soldin, Marais, J. Pharm. Soc. 55, 452 (1966). Formation from ursolic acid: Goodson, J. Chem. Soc. 1938, 999; from boswellic acid: Ruzicka, Wirz, Helv. Chim. Acta 22, 948 (1939). Partial synthesis from glycyrrhetic acid and stereochemistry: Corey, Cantrall, J. Am. Chem. Soc. 81, 1745 (1959). Review: J. Simonsen, W. C. J. Ross, The Terpenes vol. IV (University Press, Cambridge, 1957) pp 116-148.
📄 详细内容
Properties: Needles from alcohol, mp 186°. bp0.7 243°. [a]D17 +91.6° (c = 1.3 in benzene). Sol in 22 parts 98% alc. Sol in ether, benzene, chloroform, glacial acetic acid. Slightly sol in petr ether.
Melting point: mp 186°
Boiling point: bp0.7 243°
Optical Rotation: [a]D17 +91.6° (c = 1.3 in benzene)
Derivative Type: Acetate
Percent Composition: C 81.99%, H 11.18%, O 6.83%
Properties: Leaflets from petr ether, mp 227°. [a]D20 +76.35° (c = 0.572 in CHCl3).
Melting point: mp 227°
Optical Rotation: [a]D20 +76.35° (c = 0.572 in CHCl3)
Derivative Type: Benzoate
Percent Composition: C 83.72%, H 10.25%, O 6.03%
Properties: Prisms from benzene + acetone, mp 195-196°. [a]D10 +94.6° (c = 1.9 in CHCl3).
Melting point: mp 195-196°
Optical Rotation: [a]D10 +94.6° (c = 1.9 in CHCl3)
产品链接: 638-95-9››