CAS: 506-25-2; Octadec-17-En-9,11-Diinsaeure

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    9-癸炔酸 Dec-9-Ynoic Acid 1642-49-5

    合成工艺路线路线简述

      📜6-氯-1-己烯置于盐酸,Ammonium Chloride,丙酮,Sodium Iodide,Copper(L) Chloride体系中,化学反应生成 17-十八碳烯-9,11-二炔酸
      参考文献:368.不饱和脂肪酸.第一部分:赤藓酸(壬酸)和其他炔酸的合成
      标题:368.不饱和脂肪酸.第一部分:赤藓酸(壬酸)和其他炔酸的合成
      摘要:
      DOI:10.1039/jr9530001785

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      专利信息


      专利号:US-6599972-B2
      优先权日:1996-12-24
      标 题 :Latex compositions containing ethylenically unsaturated esters of fatty compounds and applications thereof
      发明人:THAMES SHELBY FRELAND; PANJNANI KAMLESH GOPICHAND; FRUCHEY OLAN STANLEY
      权利人:UNIV SOUTHERN MISSISSIPPI
      摘要:Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated derivatives of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of fatty alcohols. A process for the synthesis of the latex composition is also disclosed, which involves (a) polymerization of the ethylenically unsaturated derivatives of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from -5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

      专利号:US-6203720-B1
      优先权日:1996-12-24
      标题 :Low MFT and high Tg , internally plasticizing, and low voc latex compositions
      发明人:THAMES SHELBY FRELAND; PANJNANI KAMLESH GOPICHAND; HARIHARAN RAJAN; WANG ZHIYU
      权利人:UNIV SOUTHERN MISSISSIPPI
      摘要:Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (T g ) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

      专利号:CN-1337967-A
      优先权日:1999-01-28
      标 题 :Synthesis of Polyol Fatty Acid Polyester

      专利号:US-6624223-B1
      优先权日:1996-12-24
      标题 :Internally plasticized and low VOC latex compositions and applications thereof
      发明人:THAMES SHELBY FRELAND; WANG ZHIYU; BRISTER ELIZABETH H; HARIHARAN RAJAN; KING COREY L; PANJNANI KAMLESH GOPICHAND
      权利人:UNIV SOUTHERN MISSISSIPPI
      摘要:Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (T g ) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

      专利号:JP-2001511186-A
      优先权日:1997-02-07
      标 题:Lower alkyl esters reused in the synthesis of polyol fatty acid polyesters

      专利号:AU-647634-B2
      优先权日:1991-07-01
      标 题:New process for the synthesis of enantiomers of 3-aminochroman compounds

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      合成参考文献


      摘要:Russell, A. T., Science of Synthesis, (2008) 36, 206.
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