专利号:US-4939112-A 优先权日:1988-10-06 标 题:Catalyst for synthesis of vesicular phenoxy resins 发明人:BENNETT EVERETT W 权利人:JAMES RIVER PAPER CO 摘要:A catalyst for synthesis of vesicular phenoxy resins is disclosed. The catalyst includes a water-insoluble complex of a hydric phenol and a quaternary ammonium or phosphonium salt of the hydric phenol. Preferably, the hydric phenol is an intermediate of the phenoxy resin being produced. Dihydric phenols, such as sulfonyldiphenol are preferred. The invention further relates to a reaction medium for polymerization of phenoxy resins including the above-described catalyst and a solvent medium capable of dissolving the phenoxy resins and otherwise not interfering with the polymerization reaction. The solvent medium is advantageously free of toxic Methyl Cellosolve.
专利号:US-4092351-A 优先权日:1976-02-17 标 题 :Method of synthesis of 4,5,6-trihydroxyisophthalic acid 发明人:SHIPCHANDLER MOHAMMED T 权利人:IMC CHEMICAL GROUP 摘要:A process for the synthesis of 4,5,6-trihydroxyisophthalic acid by reacting dialkyl glutarate with dialkyl dialkoxymalonate.
专利号:US-4046817-A 优先权日:1974-07-19 标题 :Method of synthesis of pyrogallol 发明人:SHIPCHANDLER MOHAMMED T 权利人:IMC CHEMICAL GROUP 摘要:A process for the synthesis of pyrogallol from glutaric ester and dialkoxymalonic ester.
专利号:US-6342582-B1 优先权日:1989-12-04 标 题 :Reaction and dissolving medium for peptides and synthesis method using this medium 发明人:GALVEZ MARIE; MAURICE MARIE-FRANCE 权利人:RHODIA CHIMIE SA 摘要:The present invention relates to a reaction and dissolving medium for the synthesis of peptides. This reaction and dissolving medium for peptide synthesis and/or purification comprises a diluent A chosen from a group of water-immiscible solvents and a phenol B. By employing this reaction and dissolving medium, peptides can be synthesized which are useful as medicaments, vaccines, agro-foodstuff products or plant protection products.
专利号:US-4161609-A 优先权日:1977-09-14 标题:Synthesis of carboxylic acid esters 发明人:CRAMER RICHARD D 权利人:DU PONT 摘要:A method is provided for converting a carboxylic acid amide to a carboxylic acid ester by reacting a vaporized mixture of the amide and an aliphatic alcohol or a phenol in the presence of a suitable catalyst at temperatures of from 100 DEG C. to 400 DEG C. The process is especially useful for the conversion of methacrylamide to methyl methacrylate.
专利号:US-10017391-B2 优先权日:2015-04-23 标题:Direct polymer templating synthesis of mesoporous carbon 发明人:DAI SHENG; NELSON KIMBERLY M 权利人:UT BATTELLE LLC; UNIV TENNESSEE RES FOUND 摘要:The invention is directed to a method for fabricating a mesoporous carbon composite material. The method comprises providing a precursor composition and subjecting the precursor material to a curing step followed by carbonization step. The precursor composition comprises (i) a templating component comprised of a linear homopolymer material, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) an acid catalyst.
摘要:Barsegyan, Y. A.; Vil’, V. A.; Tomkinson, N. C. O.; Terent’ev, A. O., Science of Synthesis Knowledge Updates, (2022) 1, 239. 摘要:P. Demerseman, J. P. Lechartier, R. Reynaud, A. Cheutin, R. Royer and P. Rumpf, Bull. Soc. Chim. Fr. 1963, 2559. 参考文献:10.1007/bf00114627 摘要:van Ginkel CG. Complete degradation of xenobiotic surfactants by consortia of aerobic microorganisms. Biodegradation. 1996 Apr;7(2):151–64. doi: 10.1007/bf00114627. 参考文献:10.1007/s00216-008-2005-0 摘要:Stoichev T, Baptista MS, Basto MCP, Carvalho PN, Vasconcelos MTSD. Application of SPME to the determination of alkylphenols and bisphenol A in cyanobacteria culture media. Analytical and Bioanalytical Chemistry. 2008 Apr 01;391(1):425–32. doi: 10.1007/s00216-008-2005-0. 参考文献:10.1007/s00204-019-02506-6 摘要:Pyo JJ, Ahn S, Jin SH, An S, Lee E, Choi J, Shin JC, Choi H, Kim HJ, Choi D, Noh M. Keratinocyte-derived IL-36γ plays a role in hydroquinone-induced chemical leukoderma through inhibition of melanogenesis in human epidermal melanocytes. Arch Toxicol. 2019 Aug;93(8):2307–20. doi: 10.1007/s00204-019-02506-6.