CAS: 5089-28-1; 1,8-Bis(Chlorodimethylsilyl)Octane

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66604-31-7 18162-84-0 38051-57-9

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CAS号1066-35-9 二甲基一氯硅烷 | CAS号3710-30-3 1,7-辛二烯

📜二甲基一氯硅烷,1,7-辛二烯置于铂体系中,化学反应生成 1,8-双(氯二甲基甲硅烷基)辛烷
参考文献:反式-二-μ-氢化物-双(三环己基膦)双(甲硅烷基)二铂配合物催化的烯烃的氢化硅烷化
标题:反式-二-μ-氢化物-双(三环己基膦)双(甲硅烷基)二铂配合物催化的烯烃的氢化硅烷化
摘要:双铂配合物[{pt(sir 3)(µ-H)[(c 6 H 11)3 P]} 2]催化硅烷r 3 Sih的添加(r = Me,Et,Phch 2,Ph,Oet,或cl)为戊-1-烯,己-1-烯,苯乙烯,烯丙基氯和2-甲基丙烯.硅烷的反应性从高到低依次为:Me 2 Etsih≃me 2 Phsih≃me 2(phch 2)sih Clme 2 Sih> Me 3 Sih> Cl 3 Sih Et 3 Sih (eto)3 Sih,但烯丙基氯除外它是cl3 Sih> Cl 2 Mesih> Me 2 Phsihclme 2 Sih.加氢甲硅烷基化反应经常强烈放热,在催化剂:反应物比率为10-4-10-6:1的情况下以高收率进行反应.六元-1,5-二烯,八元-1,7-二烯和4-乙烯基环己烯也会发生反应使用相同的催化剂体系,可以轻松地与硅烷一起使用.六(1,5-二烯)和八(1,7-二烯)可提
DOI:10.1039/dt9770001519

专利信息

专利号:US-5455367-A
优先权日:1993-04-22
标 题:Method for the synthesis of silanes or organosilicon hydrides by the reduction of the corresponding silicon halides or organosilicon halides
发明人：KLEIN KLAUS-DIETER; KNOTT WILFRIED; KOERNER GOETZ
权利人:GOLDSCHMIDT AG TH
摘要:A method for the synthesis of silanes or organosilicon hydrides by the reduction of the corresponding silicon halides or organosilicon halides with a magnesium hydride in a liquid reaction medium is carried out by utilizing the following distinguishing features: n a) the use of non-pyrophoric, preferably autocatalytically produced, storage magnesium hydride as magnesium hydride, n b) the use of conventional ethers as reaction medium, and n c) the continuous removal of the magnesium halide formed being deposited on the surface of the magnesium hydride particles during the reaction by the action of mechanical energy or ultrasound so as to form a fresh surface.

专利号:CA-2121931-C
优先权日:1993-04-22
标 题:Method for the synthesis of silanes or organosilicon hydrides by the reduction of the corresponding silicon halides or organosilicon halides