CAS: 313222-91-2; Lithium Citrate Hydrate,0.97

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    专利号:US-2012168686-A1
    优先权日:2009-09-03
    标 题:Continuous Synthesis of Carbon-Coated Lithium-Iron-Phosphate
    发明人:METZ HANS JOACHIM; WASER OLIVER; BUECHEL ROBERT; PRATSINIS SOTIRIS E
    权利人:METZ HANS JOACHIM; WASER OLIVER; BUECHEL ROBERT; PRATSINIS SOTIRIS E; CLARIANT FINANCE BVI LTD
    摘要:The invention relates to a continuous process for preparing carbon-coated lithium-iron-phosphate particles, wherein the carbon-coated lithium-iron-phosphate particles have a mean (d 50 ) particle size of 10 to 150 nm, and wherein the carbon-coating is an acetylene-black coating, comprising performing in a reactor a flame-spray pyrolysis step (i) in a particle formation zone of the reactor, and a carbon-coating step (ii) in a carbon-coating zone of the reactor, wherein inn (i) a combustible organic solution containing a mixture of lithium or a lithium compound; iron or an iron compound; and phosphorus or a phosphorous compound in an organic solvent, is fed through at least one nozzle where said organic solution is dispersed, ignited and combusted, to give a flame spray thereby forming an aerosol of lithium iron phosphate particles; (ii) acetylene gas is injected into said aerosol thereby forming an acetylene-black coating on the lithium iron phosphate particles; (iii) the coated particles are cooled by an inert quench gas and collected on a filter.

    专利号:WO-2011026581-A1
    优先权日:2009-09-03
    标题:Continuous synthesis of carbon-coated lithium-iron-phosphate

    专利号:EP-2292557-A1
    优先权日:2009-09-03
    标题 :Continuous synthesis of carbon-coated lithium-iron-phosphate

    专利号:EP-2475615-A1
    优先权日:2009-09-03
    标题:Continuous synthesis of carbon-coated lithium-iron-phosphate

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    合成参考文献


    参考文献:10.1007/s10870-017-0701-3
    摘要:Piro OE, Echeverría GA, Parajón-Costa BS, Baran EJ. Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na+, K+, Rb+, Cs+, Isomorphic Series. Journal of Chemical Crystallography. 2017 Oct 25;47(6):226–32. doi: 10.1007/s10870-017-0701-3.
    参考文献:10.1385/bter:76:2:183
    摘要:Bovi Mitre MG, Wierna NR, Wagner CC, Baran EJ. Spectroscopic and magnetic properties of a Ni(II) complex with citric acid. Biol Trace Elem Res. 2000 Aug;76(2):183–90. doi: 10.1385/bter:76:2:183.
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