CAS: 1653-16-3; 2-Ethylhexyl Iodide

相似化合物

1044598-79-9 4282-40-0 629-93-6

上下游产品

CAS号18908-66-2 溴代异辛烷 | CAS号104-76-7 2-乙基己醇 | CAS号123-04-6 氯代异辛烷 | CAS号592-41-6 1-己烯 | CAS号557-18-6 二乙基镁 | CAS号2983-37-1 2-乙基己酸乙酯 | CAS号589-81-1 3-甲基庚烷 | CAS号10137-80-1 N-(2-ethylhexyl... | CAS号691899-73-7 1-[1-(2-ethylhe...

📜2-乙基己醇置于咪唑,碘,三苯基膦体系中,用 二氯甲烷 用作溶剂,以95%的收率获得2-乙基碘己烷
参考文献:三组分反应的无配位钯催化的α-三氟甲基丙烯酸及其相关丙烯酸酯的合成
标题:三组分反应的无配位钯催化的α-三氟甲基丙烯酸及其相关丙烯酸酯的合成
摘要:芳基碘化物和2-(三氟甲基)丙烯酸一起在无配体的mizoroki-Heck反应中反应,可快速有效地获得高价值的α-三氟甲基丙烯酸.就芳基取代基的电子性质而言,有用的转化是独立的.还开发了三组分一锅法版本,以提供各种取代的丙烯酸酯.快速获得3-Cf 3-香豆素以及治疗剂或美容剂的氟化类似物证明了α-三氟甲基丙烯酸的多功能性.最后,我们提出了基于羧酸银盐的催化循环,该羧酸银盐被确定为反应中的关键中间体.
Doi:10.1002/adsc.201901446

专利信息

专利号:US-7199276-B2
优先权日:2003-11-19
标 题 :Controlling the ratio of ethylene to propylene produced in an oxygenate to olefin conversion process
发明人：SHER JAIMES; VAN EGMOND CORNELIS F; MARTENS LUC R M; JANSSEN MECHILIUM JOHANNES; LATTNER JAMES R; XU TENG
权利人:EXXONMOBIL CHEM PATENTS INC
摘要:The present invention provides various processes for producing methanol and ethanol, preferably in a mixed alcohol stream. In one embodiment, the invention includes directing syngas to a synthesis zone wherein the syngas contacts a methanol synthesis catalyst and an ethanol synthesis catalyst (either a homologation catalyst or a fuel alcohol synthesis catalyst) under conditions effective to form methanol and ethanol. The methanol and ethanol, in a desired ratio, are directed to an oxygenate to olefin reaction system for conversion thereof to ethylene and propylene in a desired ratio. The invention also relates to processes for varying the weight ratio of ethylene to propylene formed in an oxygenate to olefin reaction system.

专利号:US-4490559-A
优先权日:1984-03-27
标题:Process for making aldehydes from diesters of carbonic acid
发明人：WEGMAN RICHARD W; LETTS JOHN B
权利人:SHELL OIL CO
摘要:Saturated aliphatic aldehydes are prepared by contacting diesters of carbonic acid with synthesis gas and a Group VIII compound, preferably a cobalt compound, a halogen, and optionally a Group V trivalent ligand.

专利号:US-4727200-A
优先权日:1987-03-27
标 题 :Alcohol homologation
发明人：WEGMAN RICHARD W; MOLOY KENNETH G
权利人:UNION CARBIDE CORP
摘要:A process for the homologation of an alkanol by reaction with synthesis gas in contact with a system containing rhodium atom, ruthenium atom, iodine atom and a bis(diorganophosphino) alkane to selectivity produce the next higher homologue.