CAS: 56096-89-0; 4-Fluoro-2-Iodobenzoic Acid

上下游产品

CAS号909545-47-7 4-氟-2-碘苯甲醛 | CAS号446-32-2 2-氨基-4-氟苯甲酸 | CAS号459-57-4 对氟苯甲醛 | CAS号345-29-9 4-氟水杨酸 | CAS号365-54-8 4-FLUORO-2-PHEN... | CAS号88848-16-2 1-(chloromethyl... | CAS号60086-46-6 4-fluoro-2-(4-f... | CAS号56096-95-8 1-(chloromethyl... | CAS号56096-91-4 2-(4-chlorophen... | CAS号56096-93-6 [2-(4-chlorophe...

📜4-氟-2-碘苯甲醛置于sodium Chlorite,氨基磺酸体系中,用 水,丙酮 作为反应溶剂,化学反应 3.5H,以85%的收率获得产物4-氟-2-碘苯甲酸
参考文献:Studies On The Synthesis And Biosynthesis Of The Fungal Alkaloid Necatorone
标题:Studies On The Synthesis And Biosynthesis Of The Fungal Alkaloid Necatorone
摘要:An Alternative Pathway For The Biosynthesis Of The Fungal Alkaloid Necatorone Has Been Studied Using Fluorine-Labeled 3-(2-Carboxyphenylamino)-L-Tyrosine. Although No Incorporation Of This Compound Could Be Detected In Feeding Experiments With Young Specimens Of Lactarius Necator,An Analogous 3-Aminotyrosine Derivative Could Be Converted Synthetically Into The Oxopyridoacridine Core Structure Of Necatorone. In Experiments Aimed At The Synthesis Of Aaptamine-Type Alkaloids,An Unprecedented Cyclization Of A 3-Aminotyrosine-Methyl Propiolate Adduct To A Methyl Isoquinoline-3-Carboxylate Was Observed. A Mechanism Is Proposed,In Which C3 Of The Propiolate Delivers C1 Of The Isoquinoline Nucleus. (C) 2013 Elsevier Ltd. All Rights Reserved.
DOI:10.1016/j.Tetlet.2013.07.118

专利信息

专利号:CN-115785052-A
优先权日:2022-11-21
标题 :A method for highly selective synthesis of isocoumarins under polyacid catalysis

专利号:CN-115785052-B
优先权日:2022-11-21
标 题 :A method for highly selective synthesis of isocoumarin under polyacid catalysis