Sodium 反应生成硫化碱 参考文献:Kutty,Keloth K.;James,Velamkalam A. 标题:Kutty,Keloth K.;James,Velamkalam A.
专利信息
专利号:WO-2025132036-A1 优先权日:2023-12-21 标题 :Method for solution synthesis of sodium or lithium thiophosphate particles 发明人:POIRIER ROMAIN; GARNERO CYRIL; PASQUIER DAVID; LAMBERT ARNOLD; UZIO DENIS 权利人:IFP ENERGIES NOW 摘要:The present invention relates to a method for synthesis of thiophosphate particles Li3PS4 or Na3PS4 from a reagent A2S and a phosphorus reagent P2S5, where A is selected from Li or Na, the method comprising at least the following steps, carried out under an inert atmosphere: A) bringing the reagent A2S, previously suspended in at least one first polar solvent (solvent 1), into contact with a suspension containing at least the phosphorus reagent P2S5 in at least one second polar solvent and forming, in suspension under reflux, an intermediate compound in the form of a solvate-complex A3PS4-solvent; B) centrifuging, redispersing in a solvent, then filtering and washing the intermediate compound; C) drying the intermediate compound; d) optional heat treatment.
专利号:US-12365760-B2 优先权日:2019-05-13 标题 :Process for the synthesis of polycarbonates from cyclic monothiocarbonates 发明人:RUDOLF PETER; THIEL INDRE; WURM THOMAS MAXIMILIAN 权利人:BASF SE 摘要:A process can be used for the synthesis of compounds containing at least one non-cyclic carbonate group, wherein a compound A) containing at least one five-membered cyclic monothiocarbonate group is reacted with at least one hydroxy group of a compound B) or of compound A) itself.
专利号:US-12344943-B2 优先权日:2020-08-06 标 题:Catalyst for electrochemical synthesis of ammonia, method for preparing same, and method for regenerating same 发明人:PARK HYUN S; YOO SUNG JONG; JANG JONG HYUN; PARK HEE-YOUNG; SEO BORA; KIM JIN YOUNG; KIM HYOUNG-JUHN; LEE SO YOUNG; CHOI JIHYUN; KONG JIMIN; KIM HEE SOO; YI GYU SEONG 权利人:KOREA INST SCI & TECH 摘要:The present disclosure relates to a catalyst for electrochemical synthesis of ammonia, which includes a metal sulfide, a method for preparing the same and a method for regenerating the same.
专利号:US-11905296-B2 优先权日:2020-01-27 标题:Process for the synthesis of buprenorphine 发明人:ZINSER HARTMUT; DANIELYAN TAMAR; GRIGORYAN MERI; GHARIBYAN MARIAM; MOVSISYAN MIKAYEL; NERKARARYAN KRISTINE 权利人:AZAD PHARMA AG 摘要:The present invention relates to a novel route of synthesis for the opioid receptor antagonist Buprenorphine or a pharmaceutically acceptable salt thereof, starting from thebaine, wherein the route comprises the reaction of thebaine with a dienophile; forming an alkylated reaction product by reaction with a Grignard-reagent; formation of an cyanamide; deprotection of the cyanamide- and the phenolic-oxygen-moiety, wherein the cleavage of one or both groups is performed in the presence of an alkali or alkaline earth sulfide; followed by derivatization with a cyclopropyl-halogen and hydrogenation to yield Buprenorphine.
专利号:US-12240801-B2 优先权日:2019-06-05 标 题 :Method of synthesis and purification of citrulline 发明人:BULL JAMES ALAN; FISCHER HOLGER CHRISTIAN; KAISER KARL JUERGEN; MONNOT-CHASE BETTE 权利人:ASKLEPION PHARMACEUTICALS LLC 摘要:This invention provides for synthesis of citrulline from a transition metal complex of ornithine using cyanate to derivatize the terminal amino group of ornithine. The invention also provides improved methods for purification of citrulline produced by reaction of cyanate with ornithine via the steps of reprecipitation of copper complex of citrulline, removal of the complexing metal by sulfide precipitation, activated carbon adsorption and antisolvent crystallization.
专利号:US-12103872-B1 优先权日:2023-07-10 标题 :Polycyclic azide desulfurizer and synthesis method thereof 发明人:PENG XINGYU; GONG JIANHUA; GE FENG; REN YANG; SUN HUAIYU; LIU LISHENG; YUAN ZHIHUA; YAN KE; YE FENG; LI HONG 权利人:UNIV SOUTHWEST PETROLEUM 摘要:Disclosed is a polycyclic azide desulfurizer, including the following raw materials in parts by mass: 20-35 parts of an alcohol amine, 20-35 parts of an amide, and an aldehyde, which is 10-15 parts of a small-molecule aldehyde or 20-35 parts of a polyaldehyde. Also disclosed is a method for synthesis of the polycyclic azide desulfurizer, including: mixing an alcohol amine with an amide and stirring, heating, adding a catalyst I dropwise, and performing reaction to obtain a monocyclic triazine, heating the monocyclic triazine, mixing with a polyaldehyde and stirring, adding a catalyst II dropwise, and performing coupling while stirring; alternatively, mixing a small-molecule aldehyde with an amide and stirring, heating, adding a catalyst I dropwise, and performing reaction, adding an alcohol amine, adding a catalyst II dropwise, and performing coupling while stirring; and separating a by-product from a product obtained after the coupling out, and purifying the product.
摘要:Chang, C.-S.; Wu, Y.-T., Science of Synthesis, (2010) 45, 985. 摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 829. 摘要:Tobe, Y.; Takeda, T., Science of Synthesis, (2010) 45, 1339. 摘要:Association of American Railroads. Emergency Handling of Hazardous Materials in Surface Transportation. Washington, DC: Association of American Railroads, Bureau of Explosives, 1994., p. 994 摘要:Kirk-Othmer Encyclopedia of Chemical Technology. 4th ed. Volumes 1: New York, NY. John Wiley and Sons, 1991-Present., p. V22 417