合成目标产物 Diallyl Phthalate 主要起始原料 Phthalic Anhydride And Allyl Alcohol
(文献来源)合成步骤主要原料 Phthalic Anhydride 和 Allyl Alcohol
1-O-Prop-2-Enyl 2-O-Prop-2-Ynyl Benzene-1,2-Dicarboxylate置于indium体系中,用 乙醇 用作溶剂,化学反应 40.0H,以95%的收率获得邻苯二甲酸二烯丙酯玻璃纤维增强塑料 参考文献:Selective Reduction Of Terminal Alkynes To Alkenes By Indium Metal 标题:Selective Reduction Of Terminal Alkynes To Alkenes By Indium Metal 摘要: Doi:10.1021/jo010262Z
专利号:WO-2023102600-A1 优先权日:2021-12-06 标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom 发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI 权利人:NEWSOUTH INNOVATIONS PTY LTD 摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.
专利号:US-10941231-B2 优先权日:2015-10-02 标 题 :Method for the synthesis of acrylic (co)polymers from oligomers of acrylic acid 发明人:SUAU JEAN-MARC; CHAMPAGNE CLEMENTINE 权利人:ARKEMA FRANCE 摘要:The present invention relates to the synthesis of an associative acrylic (co)polymer by aqueous emulsion radical polymerization. The (co)polymer contains at least one oligomer of acrylic acid represented by the formula (I): n nwhere n is an integer ranging from 1 to 10. The oligomer is prepared from acrylic acid at a temperature of between 50° C. and 200° C. in the presence of a basic or acid catalyst, water, and polymerization inhibitors. The present invention also relates to the associative acrylic (co)polymer obtained from the method and also to the use of this (co)polymer as a thickener in various formulations.
专利号:US-3960805-A 优先权日:1974-04-19 标 题:Direct synthesis of organic polymer-inorganic oxide composites 发明人:TAYLOR LYNN JOHNSTON 权利人:TAYLOR LYNN JOHNSTON 摘要:There is disclosed an in situ process for the preparation of a composite material consisting essentially of an organic polymer or copolymer having dispersed therein an inorganic oxide or mixture of oxides, said process comprising the simultaneous or sequential synthesis of the organic polymer from at least one non-polymeric organic precursor and of the inorganic oxide or oxide mixture derived from at least one inorganic-oxide precursor.
专利号:US-2003130433-A1 优先权日:2001-10-30 标题 :Process for the production of graft polymers 发明人:WENZ ECKHARD; BUCHHOLZ VERA; EICHENAUER HERBERT; WOLF UDO; BORN RALF-JURGEN; JANSEN ULRICH; DIETZ WOLFGANG 摘要:A process of preparing a graft polymer (e.g., an ABS graft copolymer), which involves determining the concentration of at least one reaction component during the course of the reaction by means of Raman spectroscopy, is disclosed. The process, more particularly, comprises: (a) synthesizing the graft polymer from a reaction mixture comprising reactive components (e.g., monomers such as styrene and acrylonitrile, and a graft base); (b) analyzing the reaction mixture, at intervals, during the synthesis of the graft polymer, by means of Raman spectra; (c) recording the results of the Raman spectra analysis; (d) determining the concentration of at least one of said reactive components (e.g., styrene) by means of spectral evaluation of the recorded Raman spectra; and (e) terminating the synthesis reaction of the graft polymer when the concentration of at least one of the reactive components has reached a predetermined concentration value.
专利号:US-9006345-B2 优先权日:2011-03-25 标题 :Heterotrifunctional molecules and methods for the synthesis of dendrimeric materials 发明人:LANCASTER JEFFREY; KOBERSTEIN JEFFREY T; TURRO NICHOLAS J 权利人:LANCASTER JEFFREY; KOBERSTEIN JEFFREY T; TURRO NICHOLAS J; UNIV COLUMBIA 摘要:In one aspect, the present invention is directed to dendrimers comprised of macromolecules and trifunctional branches. In another aspect, the invention relates to methods for generating dendrimeric compositions comprising macromolecules and trifunctional branches. In certain embodiments, the radial density of the dendrimeric composition is controlled by selective incorporation of branches.
专利号:US-5869706-A 优先权日:1995-12-27 标题 :Epoxidation process using a synthetic crystalline material oxides of silicon and titanium 发明人:DARTT CHRISTOPHER B; DAVIS MARK E 权利人:CALIFORNIA INST OF TECHN 摘要:Zeolite SSZ-33 containing titanium in its framework is prepared by post-synthesis treatment with titanium tetrachloride. The titanium-containing SSZ-33 is useful as a catalyst in oxidation reactions.
1: Fan YL, Ma M, Cui HZ, Liu S, Yang ML, Hou XF. Simultaneous determination of 22 phthalate esters in polystyrene food-contact materials by ultra performance convergence chromatography with tandem mass spectrometry. J Sep Sci. 2018 May 29. doi: 10.1002/jssc.201800094. [Epub ahead of print] doi: 10.1016/j.foodchem.2018.04.132. Epub 2018 Apr 30. doi: 10.1038/srep41020. 4: Liu N, Wen F, Li F, Zheng X, Liang Z, Zheng H. Inhibitory mechanism of phthalate esters on Karenia brevis. Chemosphere. 2016 Jul;155:498-508. doi: 10.1016/j.chemosphere.2016.04.082. Epub 2016 May 2. doi: 10.1002/jssc.201501290. Epub 2016 Mar 10. doi: 10.1016/j.biortech.2015.01.122. Epub 2015 Feb 16. doi: 10.1002/jssc.201401457. Epub 2015 Mar 14. doi: 10.1002/tox.21985. Epub 2014 Mar 11. doi: 10.1016/j.aca.2013.03.072. Epub 2013 Apr 22. doi: 10.1016/j.talanta.2013.02.008. Epub 2013 Feb 8. doi: 10.1080/19440049.2013.781683. Epub 2013 Apr 24. Chinese. doi: 10.1016/j.aca.2011.05.040. Epub 2011 Jun 23. doi: 10.1016/j.chemosphere.2010.01.052. Epub 2010 Mar 1. doi: 10.1016/j.talanta.2008.03.002. Epub 2008 Mar 13. doi: 10.1016/j.marpolbul.2008.05.005. Epub 2008 Jul 2. doi: 10.1016/j.fct.2008.02.012. Epub 2008 Feb 21. Epub 2007 Oct 10. Epub 2007 Sep 14.
合成参考文献
摘要:40 CFR 716.120 (USEPA); U.S. National Archives and Records Administration's Electronic Code of Federal Regulations. Available from, as of April 16, 2008: 摘要:Raymond MD et al; Patty's Toxicology. (2007). NY, NY: John Wiley & Sons, Inc. Esters of Aromatic Mono-, Di-, and Tricarboxylic Acids, Aromatic Diacids and Di-, Tri- or Polyalcohols. On-line posting date: Apr 16, 2001. 摘要:Franke C et al; Chemosphere 29: 1501-14 (1994) 摘要:Commission of the European Communities. Legislation on Dangerous Substances - Classification and Labelling in the European Communities. Vol. II. London and Trotman Ltd., 1989., p. 597 摘要:NITE; Chemical Risk Information Platform (CHRIP). Biodegradation and Bioconcentration. Ver 2006.01.30 Updated. National Institute of Technology and Evaluation. Tokyo, Japan. Diallyl phthalate. (131-17-9). Available from the database query page at https://www.safe.nite.go.jp/english/kizon/KIZON_start_hazkizon.html as of June 2008.