(氯甲基)三氯硅烷置于红铝体系中,用 四氢呋喃 作为反应溶剂,化学反应 1.0H,反应生成 甲基硅烷 参考文献:Method For Producing-Hetero-Substituted Alkylhalohydrosilane And Use Thereof 标题:Method For Producing-Hetero-Substituted Alkylhalohydrosilane And Use Thereof
专利信息
专利号:US-6127489-A 优先权日:1996-05-20 标题:Silyl linker for solid phase organic synthesis of aryl-containing molecules 发明人:NEWLANDER KENNETH A; MOORE MICHAEL L 权利人:SMITHKLINE BEECHAM CORP 摘要:This invention relates to improved silyl linkers, methods for their preparation and their use in the solid phase synthesis of aromatic carbocycles, especially electron deficient aromatic carbocycles.
专利号:US-5859268-A 优先权日:1996-04-09 标 题:Process for the synthesis of α, β-unsaturated esters 发明人:ANGELICI ROBERT J; SHIH KUO-CHEN 权利人:UNIV IOWA STATE RES FOUND INC 摘要:The present invention provides a process for the synthesis of an α,β-unsaturated ester from a mono-olefin-ester using Fe(CO) 5 .
专利号:US-7435855-B2 优先权日:2004-06-18 标题:Process for the continuous synthesis of methylamines 发明人:BOSCH MARCO; EBERHARDT JAN KURT; ROETTGER RODERICH; KRUG THOMAS; MELDER JOHANN-PETER 权利人:BASF SE 摘要:Process for the continuous synthesis of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the catalyst used is a shaped body which comprises a microporous material and at least one organosilicon compound as binder and can be produced by a process comprising the stepsn (I) preparation of a mixture comprising the microporous material, the binder, a pasting agent and a solvent, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body, (IV) drying of the shaped body and (V) calcination of the dried shaped body.
专利号:US-6410767-B2 优先权日:1998-01-30 标 题 :Silylated and N-silylated compound synthesis 发明人:GATELY DANIEL A 权利人:BOULDER SCIENT CO 摘要:Synthesis of N-silylated mono(cyclopentadienyl) ligands and similar indenyl ligands utilizing the novel silanes is described.
专利号:US-9963723-B2 优先权日:2004-04-22 标题:Synthesis of long-chain polyunsaturated fatty acids by recombinant cells 发明人:SINGH SURINDER PAL; ROBERT STANLEY SURESH; NICHOLS PETER DAVID; BLACKBURN SUSAN IRENE ELLIS; ZHOU XUE-RONG; PETRIE JAMES ROBERTSON; GREEN ALLAN GRAHAM 权利人:COMMW SCIENT IND RES ORG 摘要:The present invention relates to methods of synthesizing long-chain polyunsaturated fatty acids, especially eicosapentaenoic acid, docosapentaenoic acid and docosahexaenoic acid, in recombinant cells such as yeast or plant cells. Also provided are recombinant cells or plants which produce long-chain polyunsaturated fatty acids. Furthermore, the present invention relates to a group of new enzymes which possess desaturase or elongase activity that can be used in methods of synthesizing long-chain polyunsaturated fatty acids.
专利号:US-2007049766-A1 优先权日:2005-06-06 标题 :Synthesis of tetrakis(dialkylamino)silanes 发明人:BELOT JOHN A; BANERJEE CHIRANJIB 权利人:BELOT JOHN A; BANERJEE CHIRANJIB 摘要:A method of synthesizing a substantially pure homoleptic tetrakis secondary amine derivative of silicon, said derivative being substantially free of halogen and having the formula: n nSi(NRR 1 ) 4 n wherein: R and R 1 are the same or different and are substituted or unsubstituted straight or branched chain alkyl, groups having from 1 to 6 carbon atoms, said method comprising reacting a silicon halide having the formula: n nSiX 4 nwherein: X is bromine or iodine, with an excess of a secondary amine having the formula: n nHNRR 1 n wherein: R and R 1 are as defined as above, n nfor a time and under conditions sufficient to produce a reaction product mixture containing the desired product, Si(NRR 1 ) 4 .