专利号:WO-9119832-A1 优先权日:1990-06-12 标题 :Method for producing glyoxylic acid by electroreduction with cathodic reactivation of oxalic acid 发明人:OCHOA GOMEZ JOSE RAMON; DE DIEGO ZORI ASUNCION; GARRIDO FRUTOS JOSE MARIA 权利人:ERCROS SA 摘要:Method for producing glyoxylic acid by electroreduction, with cathodic reactivation, of oxalic acid in a divided eletrolytic cell comprised of an anodic compartment formed of an anode and an aqueous solution of a strong mineral acid as anolite and of a cathodic compartment formed of a lead cathod and an aqueous solution saturated with oxalic acid, the two compartments being separated by a cationic exchange membrane. The method comprises the addition of Pb(II) salts to the catholite or to the anolite in order to keep at high and constant levels throughout the operation both the current efficiency and the selectivity of the process. The effect of Pb (II) salts may be potentiated by washing the cathode with nitric acid. The glyoxylic acid is an intermediary in the industrial synthesis of p-hydroxyphenylglycine and vanillin, inter alia.
专利号:US-12043553-B2 优先权日:2019-10-31 标题:Quantum material/vanadium oxide heterostructures, methods of making same, and uses thereof 发明人:BANERJEE SARBAJIT; WATSON DAVID F; ANDREWS JUSTIN L; CHO JUNSANG; SUWANDARATNE NUWANTHI; SHENG AARON 权利人:UNIV NEW YORK STATE RES FOUND; TEXAS A & M UNIV SYS 摘要:The subject invention pertains to the synthesis and characterization of V2O5/CdE NW/QD heterostructures. The V2O5/CdE heterostructures are versatile new materials constructs for light harvesting, charge separation, and the photocatalytic production of solar fuels; polymorphism of V2O5 and compositional alloying of both components provides for a substantial design space for tuning of interfacial energy offsets. Also provided are a new class of type-II heterostructures composed of cadmium chalcogenide QDs (CdE where E=S, Se, or Te) and α-V2O5 nanowires (NWs). The synthesis and characterization of V2O5/CdE NW/QD heterostructures, prepared via successive ionic layer adsorption and reaction (SILAR) and linker-assisted assembly (LAA), the characterization of their photoinduced charge-transfer reactivity using transient absorption spectroscopy, and their performance in the photocatalytic reduction of protons to hydrogen are also disclosed.
专利号:CN-1153764-A 优先权日:1996-01-02 标题:A new method for the synthesis of borneol by esterification and saponification of pinene and a boron-titanium based composite catalyst
专利号:CN-106607024-A 优先权日:2015-10-21 标 题:Catalyst, preparation method and application of CO gas phase synthesis of oxalate
专利号:CN-101279257-B 优先权日:2008-03-27 标题:A kind of catalyst for the synthesis of oxalate ester and its preparation method and application
专利号:CN-85101616-A 优先权日:1985-04-01 标 题:Catalytic Coupling of Carbon Monoxide to Synthesis of Oxalic Acid
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