📜对甲苯磺酸正辛酯,Sodium O-Nitrophenate置于xylene体系中,化学反应生成2-硝基苯辛醚 参考文献:Nodzu Et Al.,Yakugaku Zasshi/journal Of The Pharmaceutical Society Of Japan,1951,Vol. 71,P. 173,174 标题:Nodzu Et Al.,Yakugaku Zasshi/journal Of The Pharmaceutical Society Of Japan,1951,Vol. 71,P. 173,174
专利号:US-5403895-A 优先权日:1993-04-07 标题:Synthesis of aminated PVCs by controlled reaction with piperazine 发明人:KUSY ROBERT P; COSOFRET VASILE V; WHITLEY JOHN Q; LINDNER ERNO; BUCK RICHARD P 权利人:UNIV NORTH CAROLINA 摘要:Disclosed are a copolymer composition comprising a substituted halo-polymer wherein from about 0.01% to about by weight of the halo moieties therein are replaced with piperazine, and a flexible plastic film made from the copolymer. The copolymer is inherently conductive.
专利号:US-5603074-A 优先权日:1995-03-28 标 题 :Preparation and use of tetra-alkyl cobalt dicarbollide for extraction of cesium and strontium into hydrocarbon solvents 发明人:MILLER REBECCA L; PINKERTON ANTHONY B; ABNEY KENT D; KINKEAD SCOTT A 权利人:UNIV CALIFORNIA 摘要:Preparation and use of tetra-C-alkyl cobalt dicarbollide for extraction of cesium and strontium into hydrocarbon solvents. Tetra-C-alkyl derivatives of cobalt dicarbollide, Co(C 2 R 2 B 9 H 9 ) 2 - (CoB 2 R 4 - ; R=CH 3 and C 6 H 13 ) are demonstrated to be significant cesium and strontium extractants from acidic and alkaline solutions into non-toxic organic solvent systems. Extractions using mesitylene and diethylbenzene are compared to those with nitrobenzene as the organic phase. CoB 2 -hexyl 4 - in diethylbenzene shows improved selectivity (10 4 ) for Cs over Na in acidic solution. In dilute alkaline solution, CoB 2 -hexyl 4 - extracts Cs less efficiently, but more effectively removes Sr from higher base concentrations. A general synthesis of tetra-C-alkyl cobalt dicarbollides is described.
专利号:US-12087564-B2 优先权日:2012-05-21 标题 :Tuned synthetic dendrimer calibrants for mass spectrometry 发明人:GRAYSON SCOTT 权利人:THE ADMINISTRATORS OF THE TULANE EDUCATIONAL FUND 摘要:Provided are synthetic dendrimer calibrants for mass spectrometry. The calibrants are distinguished by their relative case and rapidity of synthesis, comparatively low cost, long shelf life, high purity, and amenability to batch synthesis as mixtures. The latter characteristic enables parallel preparation of higher molecular weight compounds displaying useful distributions of discrete molecular weights, thereby providing multi-point mass spectrometry calibration standards. Methods of making, tuning and using said calibrants are provided.
专利号:US-5047563-A 优先权日:1987-09-10 标题:Chiral crown ethers 发明人:DENTON JAMES B; YIP KIN-FAI 权利人:MILES INC 摘要:The synthesis and use of optically active isomers of bis(12-crown-4-methyl) dialkylmalonates as sodium specific ionophores is described. The synthesis of optically active isomers of hydroxymethyl 12-crown-4 useful in synthesizing ionophores is also described.
专利号:WO-9422927-A1 优先权日:1993-04-07 标题 :Synthesis of aminated pvcs by controlled reaction with piperazine
专利号:EP-2332898-A1 优先权日:2009-12-10 标题:Benzoquinone-based antioxidants 发明人:GULABOSKI RUBIN; BOGESKI IVAN; KAPPL REINHARD; HOTH MARKUS PROF 权利人:UNIV SAARLAND 摘要:The invention relates to a new type of highly polar, at least double-negatively charged redox-active benzoquinones, notably derived from Coenzyme Q0, Q1 and dimethoxy benzoquinones, its production and use. The production of these benzoquinones comprises the reaction of dimethoxy benzoquinones with highly alkaline aqueous solutions. The benzoquinones of the invention have various potential applications in pharmaceutical and cosmetic industry (namely as antioxidants, anti-ageing agents and the like), in organic synthesis, metal complexations, metal separations, potentiometric titrations, interfacial catalysis, and ion-transfer reactions across biological membranes.
[参考文献]: Ayman A Abdel Aziz, Et Al. Development Of An Optode For Detection Of Trace Amounts Of Hg2+ In Different Real Samples Based On Immobilization Of Novel Tetradentate Schiff Bases Bearing Two Thiol Groups In Pvc Membrane. J Fluoresc. 2014 May;24(3):859-74. [参考文献]: Grzegorz Lisak, Et Al. Textile-Based Sampling For Potentiometric Determination Of Ions. Anal Chim Acta. 2015 Jun 2:877:71-9. [参考文献]: Ji Min Kim, Et Al. Quantitative Determination Of Fucoidan Using Polyion-Sensitive Membrane Electrodes. Anal Chim Acta. 2015 Jun 2:877:1-8. [参考文献]: Jiahong Lei, Et Al. Potentiometric Flow Injection Sensing System For Determination Of Heparin Based On Current-Controlled Release Of Protamine. Anal Chim Acta. 2015 Feb 9:858:60-5. [参考文献]: Jiawang Ding, Et Al. Potentiometric Aptasensing Of Listeria Monocytogenes Using Protamine As An Indicator. Anal Chem. 2014 Oct 7;86(19):9412-6.
合成参考文献
参考文献:10.2116/analsci.20.805 摘要:Farhadi K, Maleki R, Hosseinzadeh Yamchi R, Sharghi H, Shamsipur M. [Tetrakis(4-N,N-dimethylaminobenzene)porphyrinato]-manganese(III) Acetate as a Novel Carrier for a Selective Iodide PVC Membrane Electrode. Analytical Sciences. 2004 May 26;20(5):805–9. doi: 10.2116/analsci.20.805. 参考文献:10.2116/analsci.22.673 摘要:Mazloum Ardakani M, Akrami Z, Mansournia M, Zare HR. Sulfate-selective electrode based on a complex of copper. Anal Sci. 2006 May;22(5):673–8. doi: 10.2116/analsci.22.673. 参考文献:10.1021/ac701983x 摘要:Gemene KL, Bakker E. Direct sensing of total acidity by chronopotentiometric flash titrations at polymer membrane ion-selective electrodes. Anal Chem. 2008 May 15;80(10):3743–50. 参考文献:10.1016/j.talanta.2007.05.028 摘要:Patil SR, Turmine M, Peyre V, Durand G, Pucci B. Study of beta-cyclodextrin/fluorinated trimethyl ammonium bromide surfactant inclusion complex by fluorinated surfactant ion selective electrode. Talanta. 2007 Nov 15;74(1):72–7. doi: 10.1016/j.talanta.2007.05.028. 参考文献:10.1016/j.talanta.2007.11.016 摘要:Lizondo-Sabater J, Martínez-Máñez R, Sancenón F, Seguí MA, Soto J. Ion-selective electrodes for anionic surfactants using a cyclam derivative as ionophore. Talanta. 2008 Mar 15;75(1):317–25. doi: 10.1016/j.talanta.2007.11.016.