CAS: 2407-94-5; 1,1'-Dihydroxycyclohexyl Peroxide

⚠️危险化学品目录(2015年版) 有机过氧化物,D型
英文名称1,1'-Dihydroxycyclohexyl Peroxide
中文名称1-(1-羟基环己基)过氧环己烷-1-醇
IUPAC名称1-(1-hydroxycyclohexyl)peroxycyclohexan-1-ol
其它别名Cyclohexanol,1,1'-dioxydi- (8CI); Peroxide, bis(1-hydroxycyclohexyl) (6CI,7CI); 1,1'-Dihydroxydicyclohexyl peroxide; 1,1'-Peroxydicyclohexanol; Bis(1-hydroxycyclohexyl) peroxide; Di(1-hydroxycyclohexyl) peroxide
CAS编号2407-94-5
EINECS号:219-306-2
FDA UNII编号:7XR9J84XLH
分子式:C12H22O4
分子量:230.30068
产品CID: 1185694
产品分类有机原料 → 醇,酚,酚醇类化合物及衍生物

相似结构搜索
InChIKey: ZPOUDMYDJJMHOO-UHFFFAOYSA-N
1S\/C12H22O4\/c13-11(7-3-1-4-8-11)15-16-12(14)9-5-2-6-10-12\/h13-14H,1-10H2…
计算化学: 氢键受体数4.0氢键供体数2.0可旋转键数3.0

物理性质

熔点66-68 °C
沸点444.4°C (粗估)
闪点161.3°C
密度1.1266 (粗估)
pKa:13.13±0.20(预测)
PSA:58.92
LogP:2.24
折射率1.6000 (估算)
敏感性The explosive instability of the lower dialkyl peroxides (e.g. dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class [Bretherick 2nd ed., p 44 1979]. Very temperature and shock sensitive.

MSDS等安全信息

危险类别Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]: | Fire may produce irritating, corrosive and/or toxic gases. Ingestion or contact (skin, eyes) with substance may cause severe injury or burns. Runoff from fire control or dilution water may cause environmental contamination. (ERG, 2024)
警示词Danger
危险描述H242: Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]
H302: Harmful if swallowed [Warning Acute toxicity, oral]
H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
防范说明P210, P234, P235, P240, P260, P264, P270, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P330, P363, P370+P378, P403, P405, P410, P411, P420, and P501
危险等级5.2
UN编号3106.0
包装等级II
危险类别码A strong oxidizing agent; Explosive; [CAMEO] See Cyclohexanone peroxide.

上下游产品

cyclohexanone 1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide diethyl ether triphenylphosphine 1,12-dodecanedioic acid bis-(1-hydroperoxycyclohexyl)peroxide t-enedioic acid11-vinyl-°Ctadec-8t-enedioic acid 7,11-°Ctadecadiene-1,18-dicarboxylic acid

合成工艺路线路线简述

环己烷置于n-羟基邻苯二甲酰亚胺,Cobalt (II)Acetate Tetrahydrate 氧气体系中,用乙腈用作溶剂,90.0 °C,101.33 Kpa 条件下,反应 1.0H,以20%的收率获得1-(1-羟基环己基)过氧环己烷-1-醇
参考文献:Process For Producing Organic Peroxides
标题:Process For Producing Organic Peroxides
摘要:该发明的一个过程允许环烷烃在催化亚胺化合物的存在下与氧气发生反应,从而产生相应的双(1-羟基环烷基)过氧化物.催化亚胺化合物包括例如由以下化学式(1)表示的化合物:其中r1和r2可以分别是氢原子,卤素原子,烷基,芳基或环烷基,其中r1和r2可以结合形成双键,芳香环或非芳香环;X是氧原子或羟基.环烷烃包括例如具有5至15个成员的环烷烃.该发明可以从廉价材料轻松生产双(1-羟基环烷基)过氧化物.

海关参考信息

2905122000-异丙醇
2905142000-仲丁醇
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详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-6911339-B2
优先权日:2001-04-09
标题:Transparent polymer support for organic synthesis
发明人：DUMAS DAVID P
摘要:The invention provides polyol (allyl carbonate) polymer solid supports. The supports can be modified for attachment of a chemical moiety or ligand. A solid support comprising one or more ligands immobilized to a polyol (allyl carbonate) polymer solid support. The solid support can be in the form of a bead, fiber, flat surface, microfluidic device, molded device, machined device, container, multi-well container such as a multi-well plate, and mass spectrometry sample holder. The solid supports can be used for a variety of applications, including chemical storage, chemical synthesis, combinatorial library synthesis, analytical devices, diagnostic devices, and tissue culture applications. The invention also provides methods of using the polyol (allyl carbonate) polymer solid supports.