N-甲基咪唑,三乙基氧翁四氟硼酸置于氩体系中,用 1,2-二氯乙烷 用作溶剂,化学反应 1.5H,反应生成1-乙基-3-甲基咪唑四氟硼酸盐 参考文献:Preparation Of A Molten Salt From Trialkyloxonium Anion And Amine 标题:Preparation Of A Molten Salt From Trialkyloxonium Anion And Amine 摘要:制备离子化合物q+a−液体的过程,在低于150oc的条件下,将阴离子的三烷氧铵与胺在烃溶剂中反应.上述离子化合物可用作许多催化反应中的溶剂.
专利号:US-2010191010-A1 优先权日:2007-07-02 标题 :Process for the synthesis of carbamates using co2 发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY 权利人:HUNTSMAN INT LLC 摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.
专利号:US-9267213-B1 优先权日:2005-03-25 标题:Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array 发明人:MAURER KARL; COOPER JOHN J 权利人:CUSTOMARRAY INC 摘要:There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.
专利号:WO-2022153326-A1 优先权日:2021-01-14 标 题:High performance sodium ion battery (sib) anode material using rice straw and its method of synthesis 发明人:KUMAR NAGESH; SONI AKASH; SAHOO ASIT; KUMAR SHARMA YOGESH 权利人:INDIGENOUS ENERGY STORAGE TECH PVT LTD 摘要:The present invention relates to the field of electrode materials for Sodium ion batteries. Rice Straw derived pure-phase hard carbon material has been synthesized as a high performance anode material for Sodium-ion batteries (SIBs). The synthesized pure phase hard carbon material delivers high performance as anode in Sodium-ion batteries. Moreover, the synthesis process is novel, facile and easily industrially scalable. Therefore, the invention provides synthesis of low cost, facile, industrially scalable and high performance Hard Carbon anode material for SIBs.
专利号:WO-2011000481-A1 优先权日:2009-07-02 标 题 :Synthesis of pyrazine derivates 发明人:IGNATYEV NIKOLAI MYKOLA; SHEREMETEV ALEXEI B; ALEXANDROVA NATALIA S 权利人:MERCK PATENT GMBH; IGNATYEV NIKOLAI MYKOLA; SHEREMETEV ALEXEI B; ALEXANDROVA NATALIA S 摘要:The present invention relates to a method for producing pyrazine derivates, wherein the reaction medium comprises at least one ionic liquid, and to the use of ionic liquids for producing pyrazine derivates.
专利号:US-8147792-B2 优先权日:2007-07-05 标 题 :Method for the preparation of reactive compositions containing superoxide ion 发明人:AL NASHEF INAS MUEN; AL ZAHRANI SAEED M 权利人:AL NASHEF INAS MUEN; AL ZAHRANI SAEED M; UNIV KING SAUD 摘要:The subject invention provides a potentially economically viable method for the preparation of reactive superoxide ion in deep eutectic solvents (DES). The superoxide ion can be used for many applications, e.g. the degradation of hazardous chemicals at ambient conditions or in the synthesis of some special chemicals, e.g. carboxylic acids, aldehydes, and ketones from the corresponding alcohols. The superoxide ion can be formed by either the electrochemical reduction of oxygen in DES or by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in DES, with/without chemicals used for the enhancement of the solubility of the metal superoxide in the DES, e.g. crown ethers.
专利号:US-9458021-B2 优先权日:2013-07-27 标 题 :Sol-gel method for synthesis of nano-porous carbon 发明人:MITRA SHANTANU 权利人:FARAD POWER INC 摘要:The present patent application discloses a novel sol-gel process to synthesize a nano-porous solid carbon material—suitable for use in electrodes in energy storage applications—from a combination of liquid reagents that undergo a polymerization reaction to form a matrix.
[参考文献]: Daisuke Sugioka, Et Al. Single-Step Preparation Of Two-Dimensionally Organized Gold Particles Via Ionic Liquid/metal Sputter Deposition. Phys Chem Chem Phys. 2015 May 21;17(19):13150-9. [参考文献]: K Kinoshita, Et Al. Influence Of The Molecular-Oriented Structure Of Ionic Liquids On The Crystallinity Of Aluminum Hydroxide Prepared By A Sol-Gel Process In Ionic Liquids. Phys Chem Chem Phys. 2015 Jul 28;17(28):18705-9. [参考文献]: M T Ubeda-Torres, Et Al. Gaining Insight In The Behaviour Of Imidazolium-Based Ionic Liquids As Additives In Reversed-Phase Liquid Chromatography For The Analysis Of Basic Compounds. J Chromatogr A. 2015 Feb 6:1380:96-103.
合成参考文献
摘要:Chessum, N.; Couty, S.; Jones, K., Science of Synthesis, (2009) 48, 286. 参考文献:10.1016/j.chroma.2006.05.049 摘要:Tang F, Tao L, Luo X, Ding L, Guo M, Nie L, Yao S. Determination of octopamine, synephrine and tyramine in Citrus herbs by ionic liquid improved 'green' chromatography. J Chromatogr A. 2006 Sep 01;1125(2):182–8. doi: 10.1016/j.chroma.2006.05.049. 参考文献:10.1007/s11356-022-19191-1 摘要:Zhang W, Hu Q, Jiang S, Wang L, Chai J, Mei J. Experimental study on coal dust wettability strengthened by surface active ionic liquids. Environmental Science and Pollution Research. 2022 Feb 15;29(30):46325–40. doi: 10.1007/s11356-022-19191-1. 参考文献:10.1021/ja055956u 摘要:Choudhury AR, Winterton N, Steiner A, Cooper AI, Johnson KA. In situ crystallization of low-melting ionic liquids. J Am Chem Soc. 2005 Dec 07;127(48):16792–3. doi: 10.1021/ja055956u.