CAS: 1277-43-6; Cobaltocene

该化合物是有机金属化合物,其含钴结构的三明治结构与铁环状结构类似,由两个环球二甲基乙酰阴离子(Cp)混合成的钴原子组成,形成CHCo 公式.钴的特点是深蓝色,以其在有机溶剂中的稳定性和溶解性而著称.它具有有趣的红氧化特性,使其能够参与各种化学反应,包括电子转移过程.钴可以作为减少剂,并经常用于合成有机化学和材料科学.它独特的电子结构有助于其在催化中的再活性和潜在应用,并成为其他含钴化合物的前体.此外,钴溶解行为还可能受到溶剂极性和温度等因素的影响,因此它成为有机金属化学研究和协调综合体的一个主题.

结构式图片

欧盟法规

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上下游产品

bromine cobalt cyclopenta-1,3-diene cobalt(II) chloridepyrographite deuterium

合成工艺路线路线简述

    📜Carbon Monoxide,Cobalt,Cyclopenta-1,3-Diene 以85%的收率获得双(环戊二烯)钴
    参考文献:η的闪热解真空5-环戊二烯基-Dicarbonylcobalt.钴茂的形成
    标题:η的闪热解真空5-环戊二烯基-Dicarbonylcobalt.钴茂的形成
    摘要:环戊二烯二羰基钴[cpco(co)2 ]的快速真空热解(350°C,0.1托)在热解管末端提供了钴茂(产率为85%).这种化合物是在双管反应的双分子反应中在失去了co配体的物质之间形成的.
    Doi:10.1016/0022-328X(86)80427-2

    海关参考信息

    专利信息


    专利号:US-10472241-B2
    优先权日:2015-10-06
    标 题:Process for the synthesis of carbon nanotubes
    发明人:GOSWAMI GOPAL KRISHNA; PATIL SWANAND DILIP; VEEDU SREEKUMAR THALIYIL; BALACHANDRAN VIJAI SHANKAR
    权利人:RELIANCE INDUSTRIES LTD
    摘要:The present disclosure relates to a process for the synthesis of highly crystalline carbon nanotubes (CNTs). Processes known in the art employ post-synthesis processes such as oxidation or hydrothermal treatment to produce CNTs with high crystallinity. The present disclosure produces highly crystalline CNTs at a low growth temperature and without hydrogen flow condition and without employing any post-production process. The process disclosed in the present disclosure produces CNTs having a crystallinity greater than 5 which makes them suitable for various industrial applications.

    专利号:US-10930473-B2
    优先权日:2015-12-15
    标 题:Apparatus and method for plasma synthesis of carbon nanotubes
    发明人:PAUKNER CATHARINA; KURZEPA LUKASZ; KOZIOL KRZYSZTOF KAZIMIERZ
    权利人:FGV CAMBRIDGE NANOSYSTEMS LTD
    摘要:Apparatus and method for plasma synthesis of carbon nanotubes couple a plasma nozzle to a reaction tube/chamber. A process gas comprising a carbon-containing species is supplied to the plasma nozzle. Radio frequency radiation is supplied to the process gas within the plasma nozzle, so as to sustain a plasma within the nozzle in use, and thereby cause cracking of the carbon-containing species. The plasma nozzle is arranged such that an afterglow of the plasma extends into the reaction tube/chamber. The cracked carbon-containing species also pass into the reaction tube/chamber. The cracked carbon-containing species recombine within the afterglow, so as to form carbon nanotubes in the presence of a catalyst.

    专利号:US-11952280-B2
    优先权日:2019-02-19
    标 题:Synthesis of quantum carbon nanotubes
    发明人:LASHMORE DAVID S; BYSTRICKY PAVEL; PERERA SUSANTHRI CHANDIMA; TARY IMRE; LICATA VITO M
    权利人:AMERICAN BORONITE CORP
    摘要:The present disclosure provides systems and methods for producing a volume of substantially all armchair nanotubes of a preselected chirality for fabricating yarn consisting of substantially all metallic conducting armchair tubes. The systems and methods can be used for the synthesis of (10,10), (11,11), and (12,12) metallic armchair carbon nanotubes and potentially other chiralities. The elements of the present disclosure include: (i) a carbon source that provides substantial numbers of ethylene and acetylene radicals in combination with a high population of ethylene groups and a small amount of methane, (ii) a hydrogen to carbon ratio sufficient to “passivateâ€? all other chiral growth sites to a higher degree than armchair growth sites, and (iii) a CVD process that can be tuned to create a well-controlled population of catalyst with tight diameter distribution with sparse modal distribution that falls within a range of the desired single wall diameters.

    专利号:US-2023212204-A1
    优先权日:2020-01-16
    标题:Reagents and their use for modular enantiodivergent synthesis of c-p bonds
    发明人:XU DONGMIN; RIVAS-BASCÓN NAZARET; KNOUSE KYLE W; PADIAL NATALIA; ZHENG BIN; VANTOUROUT JULIEN; SCHMIDT MICHAEL; EASTGATE MARTIN D; BARAN PHI
    权利人:BRISTOL MYERS SQUIBB CO; SCRIPPS RESEARCH INST
    摘要:The disclosure describes chiral P(V)-based reagents and their uses for the modular, scalable, and stereospecific synthesis of chiral phosphines, phosphine oxides and particular oligonucleotides.

    专利号:US-9339784-B2
    优先权日:2014-01-03
    标题 :Plasma synthesis of metal and lithium fluoride nanostructures
    发明人:JU YIGUANG; WADA TOMOYA; YAO NAN; SUN WENTING; SHAN JINGNING
    权利人:QUANTUMSCAPE CORP
    摘要:Provided are methods and apparatus for forming electrode active materials for electrochemical cells. These materials include a metal (e.g., iron, cobalt), lithium, and fluorine and are produced using plasma synthesis or, more specifically, non-equilibrium plasma synthesis. A metal containing material, organometallic lithium containing material, and fluorine-containing material are provided into a flow reactor, mixed, and exposed to the electrical energy generating plasma. The plasma generation enhances reaction between the provided materials and forms nanoparticles of the electrode active materials. The nanoparticles may have a mean size of 1-30 nanometers and may have a core-shell structure. The core may be formed by metal, while the shell may include lithium fluoride. A carbon shell may be disposed over the lithium fluoride shell. The nanoparticles are collected and may be used to form an electrochemical cell. Besides fluoride components, these methods may be used to form oxides, chlorides, nitrides, and sulfides.

    专利号:US-11932966-B2
    优先权日:2020-04-16
    标 题 :Metal sulfide filled carbon nanotubes and synthesis methods thereof
    发明人:LI WENZHI; POUDEL YUBA
    权利人:LI WENZHI; POUDEL YUBA; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES
    摘要:Filled carbon nanotubes (CNTs) and methods of synthesizing the same are provided. An in situ chemical vapor deposition technique can be used to synthesize CNTs filled with metal sulfide nanowires. The CNTs can be completely and continuously filled with the metal sulfide fillers up to several micrometers in length. The filled CNTs can be easily collected from the substrates used for synthesis using a simple ultrasonication method.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Progress Report for Contract No. PH-43-64-886, Submitted to the National Cancer Institute by The Institute of Chemical Biology, University of San Francisco., PH43-64-886
    参考文献:10.1007/s00232-003-0614-2
    摘要:Castelli L, Tanzi F, Taglietti V, Magistretti J. Cu 2+ , Co 2+ , and Mn 2+ Modify the Gating Kinetics of High-Voltage-Activated Ca 2+ Channels in Rat Palaeocortical Neurons. Journal of Membrane Biology. 2003 Oct 01;195(3):121–36. doi: 10.1007/s00232-003-0614-2.
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