硝基氯苯置于cuo N-甲基吡咯烷酮,Potassium Carbonate,苯胺体系中,用 5,5-Dimethyl-1,3-Cyclohexadiene 用作溶剂,化学反应生成2-硝基二苯胺 参考文献:Copper-N-Methylpyrrolidone Catalyst Useful In The Production Of 标题:Copper-N-Methylpyrrolidone Catalyst Useful In The Production Of 摘要:由铜化合物与n-甲基吡咯烷酮反应生成的催化剂,可以加速硝基氯苯与芳香胺的反应.
专利号:US-8202985-B2 优先权日:2005-10-31 标 题:Monomer compositions for the synthesis of polynucleotides, methods of synthesis, and methods of deprotection 发明人:DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINO; CARUTHERS MARVIN H 权利人:DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINO; CARUTHERS MARVIN H; AGILENT TECHNOLOGIES INC; UNIV COLORADO 摘要:Nucleotide monomers, polynucleotides, methods of making each, and methods of deprotecting each, are disclosed. An embodiment of the nucleotide monomer, among others, includes a nucleotide monomer having a heterobase protecting group selected from structures I through III as described herein. An embodiment of the polynucleotide, among others, includes a plurality of nucleotide moieties having a heterobase protecting group selected from one of structures I through III as described herein.
专利号:US-7759471-B2 优先权日:2005-10-31 标题 :Monomer compositions for the synthesis of RNA, methods of synthesis, and methods of deprotection 发明人:DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINE; CARUTHERS MARVIN H 权利人:AGILENT TECHNOLOGIES INC; UNIV COLORADO 摘要:Nucleotide monomers, polynucleotides, methods of making each, methods of deprotecting each, and the like are disclosed herein.
专利号:US-4202714-A 优先权日:1970-09-11 标 题:Ballistic modifiers and synthesis of the ballistic modifiers 发明人:ALLEY BERNARD J; DAKE JAMES D; DYKES HIRAM W H 权利人:US ARMY 摘要:A new class of ballistic modifiers and the synthesis thereof is disclosed herein and are used in propellants either individually or as admixtures in percentages of approximately 0.5 to 6 weight percent to impart mesa or plateau burning rate characteristics over a wide pressure range and reduce the temperature sensitivity of the propellants in relation to burning rates. The modifiers are chelate type compounds comprised of lead and/or copper, and various predetermined molar ratios of compounds such as salicylic acid and beta-resorcylic acid.
专利号:US-6242602-B1 优先权日:1999-03-29 标 题:One pot synthesis of 5,10-dihydrophenazine compounds and 5,10-substituted dihydrophenazines 发明人:GIRI PUNAM; BYKER HARLAN J; BAUMANN KELVIN L 权利人:GENTEX CORP 摘要:Dihydrophenazines and bis(dihydrophenazines) are prepared in high yield under commercially viable reaction conditions by reacting a catechol with a 1,2-diaminoaryl compound, wherein either the catechol or the 1,2-diaminoaryl compound is provided in at least 50% molar stoichiometric excess. The product may be oxidized to the corresponding phenazine, but is preferably derivatized at one or both of the 5,10-positions to form a monosubstituted or disubstituted dihydrophenazine or bis(dihydrophenazine). Most preferably, 5,10-dialkyl-5,10-dihydrophenazines are prepared starting from catechol and 1,2-diaminoaryl compound in a one pot synthesis. The products are useful as dyes, and in particular as chromophores in electrochromic systems.
专利号:US-2007100138-A1 优先权日:2005-10-31 标题:Monomer compositions for the synthesis of polynucleotides, methods of synthesis, and methods of deprotection
专利号:US-4243444-A 优先权日:1970-09-11 标 题 :Ballistic modifiers, synthesis . . . propellants 发明人:ALLEY BERNARD J; DAKE JAMES D; DYKES HIRAM W H 权利人:US ARMY 摘要:A new class of ballistic modifiers and the synthesis thereof is disclosed herein and are used in propellants either individually or as admixtures in percentages of approximately 0.5 to 6 weight percent to impart mesa or plateau burning rate characteristics over a wide pressure range and reduce the temperature sensitivity of the propellants in relation to burning rates. The modifiers are chelate type compounds comprised of lead and/or copper, and various predetermined molar ratios of compounds such as salicylic acid and beta-resorcylic acid.
1. Drzyzga, O. Diphenylamine and derivatives in the environment: A review. Chemsphere 53(8), 809-818 (2003). 2. Jin, R., Li, Y., Saito, Y., et al. Amino accelerators and antioxidants in sediments from the Dong Nai River System, Vietnam: Distribution and influential factors. Environ. Chem. 227, 115712 (2023).
合成参考文献
摘要:Xia, J.-B.; You, S.-L., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 2, 132. 摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 1985. Acute oral toxicity and repellency of 933 chemicals to house and deer mice. Archives of Environmental Contamination and Toxicology 14:111-129. https://www.aphis.usda.gov/ws/nwrc/chem-effects-db/S_schafer851.pdf