CAS: 111-21-7; Triethylene Glycol Diacetate

该化合物是化学化合物,其结构特征包括两个乙氧基组和二氧氧烷骨干;该化合物是聚醚化合物类别的成员,其醚联系有助于其在不同有机溶剂中的溶解性;该化合物一般看上去无色,为黄色的黄色液体,其粘度相对较低;乙氧基组的存在具有回动性,使其在各种化学合成应用中有用,特别是在形成酯和其他衍生物方面;其分子结构允许在聚合化学领域和作为有机合成的建筑块进行潜在应用;此外,该化合物的特性,如沸点和熔点,受其分子重量和功能组的影响;在处理和储存时,应参考安全数据,如任何化学物质,以确保采取适当的预防措施.

结构式图片

上下游产品

CAS号108-24-7 乙酸酐 | CAS号112-27-6 三甘醇 | CAS号463-51-4 乙烯酮 | CAS号64-19-7 冰醋酸 | CAS号75-21-8 环氧乙烷

合成工艺路线路线简述

    📜乙酸酐,三乙二醇置于phosphorus Pentoxide,Silica Gel体系中,用93%的收率获得三甘醇二乙酸酯
    参考文献:Eshghi,Hossein; Shafieyoon,Parvaneh,Journal Of Chemical Research,2004,# 12,P. 802-805
    标题:Eshghi,Hossein; Shafieyoon,Parvaneh,Journal Of Chemical Research,2004,# 12,P. 802-805

    海关参考信息

    专利信息


    专利号:US-2024383831-A1
    优先权日:2021-10-07
    标 题 :Alkoxylation of cannabidiol and other cannabinoids
    发明人:LAHASKY SAMUEL; SHARP KIP DOUGLAS; SLIKTA ALBERTO; PRESTRIDGE BRITNEY HEBERT; BARKER EMILY MATTHEWS; RICHARDSON RYAN
    权利人:INDORAMA VENTURES OXIDES LLC
    摘要:The present disclosure generally relates to the synthesis of an alkoxylated cannabinoid using a double metal cyanide (DMC) catalyst. This procedure affords a novel process for preparing water-dispersible and water-soluble versions of cannabidiol (CBD) and other cannabinoids in high yields through mild reaction conditions.

    专利号:US-11673874-B2
    优先权日:2018-08-17
    标 题 :Synthesis of chromanol derivatives
    发明人:WEINGARTEN MELANIE; SIEGEL WOLFGANG; PUHL MICHAEL
    权利人:BASF SE
    摘要:The present invention relates to a process for the production of chromanol derivatives, more specifically to a process for preparing a compound of the general formula I wherein R 1 , R 2 and R 3 independently of each other are selected from hydrogen and methyl, R 4 is selected from C- 1 -C 6 -alkyl, and X is selected from C 1 -C 20 -alkyl and C 2 -C 20 -alkenyl.

    专利号:US-12103918-B2
    优先权日:2018-08-17
    标题 :Synthesis of chromanol derivatives
    发明人:WEINGARTEN MELANIE; SIEGEL WOLFGANG; PUHL MICHAEL
    权利人:BASF SE
    摘要:The present invention relates to a process for the production of chromanol derivatives, more specifically to a process for preparing a compound of the general formula (I) wherein R 1 , R 2 and R 3 independently of each other are selected from hydrogen and methyl, R 4 is selected from hydrogen and C 1 -C 6 -alkanoyl, and X is selected from C 1 -C 20 -alkyl and C 2 -C 20 -alkenyl.

    专利号:US-12168649-B2
    优先权日:2018-08-17
    标 题 :Synthesis of chromanol and 2-methyl-1,4-naphthoquinone derivatives
    发明人:WEINGARTEN MELANIE; SIEGEL WOLFGANG; PUHL MICHAEL
    权利人:BASF SE
    摘要:The present invention relates to a process for the production of chromanol and 2-methyl-1,4-naphthoquinone derivatives, more specifically to a process for preparing a compound of the general formula (I) or (II) wherein the variables are as defined in the claims and the description.

    专利号:US-12247239-B2
    优先权日:2019-06-21
    标题:Chemo-enzymatic process for the preparation of homopropargylic alcohol
    发明人:CHANDRASEKHAR SRIVARI; GHOSH SUBHASH; KRISHNA AVULA SHIVA; REDDY CHADA RAJI; SUDHAKAR GANGARAJULA; THENKRISHNAN KUMARAGURU; PABBARAJA SRIHARI; MAINKAR PRATHAMA SATYENDRA; NASAM RAJESH
    权利人:COUNCIL SCIENT IND RES; COUNCIL SCIENT IND RES
    摘要:The present invention relates to an enzymatic process for preparation of optically pure enantiomers of homopropargylic alcohol compounds of formula I, which are useful intermediates for the synthesis of Halichondrin B and analogs. wherein, P is H or an alcohol protecting group, n is an integer ranging from 0-12.

    专利号:US-5556924-A
    优先权日:1993-11-01
    标题 :Synthesis of photoreactive polymeric binders
    发明人:FITZGERALD MAURICE J; KEARNEY FREDERICK R; LIANG RONG-CHANG; SCHWARZEL WILLIAM C
    权利人:POLAROID CORP
    摘要:A photoreactive binder that may be used to enhance photospeed in either conventional plates or on-press developable lithographic printing plates. Briefly, a polymer of m-isopropenyl- alpha , alpha -dimethylbenzyl isocyanate is derivatized for vinyl group reactivity by reacting the isocyanate groups thereof with hydroxyalkyl acrylate. The resulting photopolymeric binder provides significantly higher photospeed than the non-reactive binder currently utilized in the production of conventional printing plates. The resulting lithographic printing plate also shows better durability (as manifested by longer run-length) and is more easily developed by the microencapsulated developers utilized in the present invention. As to the preparation of the photoreactive binders, the application discloses a method of copolymerizing m-isopropenyl- alpha , alpha -dimethylbenzyl isocyanate (m-TMI) through complexation with an electron-deficient monomer such as maleic anhydride to accelerate free radical copolymerization with other monomers, and thus, provides greater monomer-to-polymer conversion. Use of the resulting product in the photoresist of a lithographic printing plate improves its adhesion to an underlying substrate.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题: Synthesis Of Chromanol And 2-Methyl-1,4-Naphthoquinone Derivatives Synthèse De Dérivés De Chromanol Et De 2-Méthyl-1,4-Naphtoquinone
    摘要:The Present Invention Relates To A Process For The Production Of Chromanol And 2-Methyl-1,4-Naphthoquinone Derivatives, More Specifically To A Process For Preparing A Compound Of The General Formula (I) Or (II) Wherein The Variables Are As Defined In The Claims And The Description.

    合成参考文献


    摘要:NIOSH; National Occupational Exposure Survey (NOES) (1983)
    摘要:Weast, R.C. and M.J. Astle. CRC Handbook of Data on Organic Compounds. Volumes I and II. Boca Raton, FL: CRC Press Inc. 1985., p. V2 395
    摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
    摘要:Mill T et al; Environmental Fate and Exposure Studies Development of a PC-SAR for Hydrolysis: Esters, Alkyl Halides and Epoxides. EPA Contract No. 68-02-4254. Menlo Park, CA: SRI International (1987)
    摘要:Department of Health & Human Services/National Institute of Environmental Health Sciences, National Toxicology Program; Triethylene Glycol Diacetate (CAS #111-21-7): Reproduction and Fertility Assessment in CD-1 Mice When Administered in Drinking Water, NTP Study No. RACB84116 (January 1986)
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