CAS: 89823-23-4; 6-((4'-Cyano-[1,1'-Biphenyl]-4-yl)Oxy)Hexyl Acrylate

该化合物是一种液晶单体,具有双联核心,具有终端的西诺组和丙烯酸盐功能组,通过灵活的丙氧空间仪连接.这一结构使得能够将其用于先进的聚合物和液晶应用,提供了极好的色素特性和光性.丙烯酸酯组有利于紫外线或热启动下的聚合,使之适合将侧链液晶聚合物(SCLCPs)与定制的电子光学特性合成.它与其他单体高度兼容,可以精确地调整物质特性,如相向温度和双倍宽度,使其在光电子设备,显示和反应材料中具有价值.复合物在标准条件下具有良好的稳定性和可操作性.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

C&L通报

上下游产品

4'-[(6-Hydroxyhexyl)Oxy]Biphenyl-4-Carbonitrile 111232-16-7
4'-(6-Bromohexyloxy)-4-Cyanobiphenyl 137763-04-3
氰基联苯酚 4-Cyano-4'-Hydroxybiphenyl 19812-93-2

合成工艺路线路线简述

  • 合成目标产物 6-(4-Cyano-Biphenyl-4'-Yloxy)Hexyl Acrylate 主要起始原料 Acrylic Acid And Ethanamine, N-[(3,5-Dichlorophenyl)Methylene]-2,2-Diethoxy-
  • 137763-04-3 = 89823-23-4
    反应条件:1.1 Reagents: Potassium Bicarbonate Solvents: Dimethylformamide; 15 H,Rt -> 100 °C
    标题:Programmable 3D Shape-Change Liquid Crystalline Elastomer Based On A Vertically Aligned Monodomain With Cross-Link Gradient
    作者:Hu,Jun; Kuang,Ze-Yang; Tao,Lei; Huang,Yi-Fei; Wang,Qing; Et Al
    参考文献:Acs Applied Materials & Interfaces 日期:2019 卷标:11(51) 页码:48393-48401]

    137763-04-3 = 89823-23-4
    反应条件:1.1 Reagents: Potassium Bicarbonate Solvents: Dimethylformamide; 12 H,Heated
    标题:Electro-Optical Property And Stability Of Liquid Crystal Physical Gels Controlled By Copolymerization
    作者:Zhao,Jianhang; Chen,Lei; Yuan,Yongjie; Li,Ye; Gu,Mengfan; Et Al
    参考文献:Reactive & Functional Polymers 日期:2018 卷标:131 页码:44-55]

    814-68-6 + 111232-16-7 = 89823-23-4
    反应条件:1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran; Cooled; 1 H,Cooled; 5 H,Rt
    标题:Photoinduced Volume Transition In Liquid Crystalline Polymer Gels Swollen By A Nematic Solvent
    作者:Hayata,Yuki; Nagano,Shusaku; Takeoka,Yukikazu; Seki,Takahiro
    参考文献:Acs Macro Letters 日期:2012 卷标:1(11) 页码:1357-1361]

    814-68-6 + 111232-16-7 = 89823-23-4
    反应条件:1.1 Catalysts: Triethylamine Solvents: Tetrahydrofuran; 0 °C1.2 Solvents: Tetrahydrofuran; 0 °C; 6 H,Rt
    标题:Synthesis,Characterisation And Comparative Study Of The Hydroxyl,Acrylate And Vinyl-Ether Terminated Cyanobiphenyl Bridged With Different Spacer Lengths
    作者:Zhang,Shuaifeng; Zhong,Tingjun; Wang,Qian; Li,Chenyue; Wang,Xiao; Et Al
    参考文献:Liquid Crystals 日期:2021 卷标:48(2) 页码:168-181]

    814-68-6 + 111232-16-7 = 89823-23-4
    反应条件:1.1 Reagents: Triethylamine Solvents: Dichloromethane; Cooled; 12 H,Cooled
    标题:Noncovalent Functionalization Of Graphene With Pyrene-Terminated Liquid Crystalline Polymer
    作者:Ji,Liangliang; Wu,Yanhong; Ma,Lijun; Yang,Xiaoming
    参考文献:Composites 日期:2015 卷标:72 页码:32-39]

    814-68-6 + 111232-16-7 = 89823-23-4
    反应条件:1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran; Rt; 1 H,0 °C; 12 H,Rt
    标题:Amphiphilic Cross-Linked Liquid Crystalline Fluoropolymer-Poly(Ethylene Glycol) Coatings For Application In Challenging Conditions: Comparative Study Between Different Liquid Crystalline Comonomers And Polymer Architectures
    作者:Zigmond,Jennifer S.; Letteri,Rachel A.; Wooley,Karen L.
    参考文献:Acs Applied Materials & Interfaces 日期:2016 卷标:8(49) 页码:33386-33393]

    814-68-6 + 111232-16-7 = 89823-23-4
    反应条件:1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran; Cooled; 12 H,Rt
    标题:Poly(Propyleneimine) Dendrimers Peripherally Modified With Mesogens
    作者:Yonetake,Koichiro; Masuko,Toru; Morishita,Takashi; Suzuki,Kazuhiro; Ueda,Mitsuru; Et Al
    参考文献:Macromolecules 日期:1999 卷标:32(20) 页码:6578-6586]

    111232-16-7 = 89823-23-4
    反应条件:1.1 Reagents: Triethylamine,Methanaminium,N-[(Dimethylamino)Fluoromethylene]-N-Methyl-,Hexafluorophosphate... Solvents: Dichloromethane; 30 Min,Rt1.2 Catalysts: 4-(Dimethylamino)Pyridine; Overnight,Rt
    标题:Tffh As An Excellent Reagent For Acylation Of Alcohols,Thiols And Dithiocarbamates
    作者:Pittelkow,Michael; Kamounah,Fadhil S.; Boas,Ulrik; Pedersen,Brian; Christensen,Jorn B.
    参考文献:Synthesis 日期:2004 卷标:(15) 页码:2485-2492]

    814-68-6 + 111232-16-7 = 89823-23-4
    反应条件:1.1 Reagents: Triethylamine Solvents: Dichloromethane; Rt; 14 H,Rt
    标题:Mesogenic Polyelectrolyte Gels Absorb Organic Solvents And Liquid Crystalline Molecules
    作者:Nishikori,Yusuke; Iseda,Kazuya; Kokado,Kenta; Sada,Kazuki
    参考文献:Polymers (Basel 日期:2016 卷标:8(4) 页码:148/1-148/10]

    814-68-6 + 111232-16-7 = 89823-23-4
    反应条件:1.1 Solvents: Tetrahydrofuran
    标题:Formation And Properties Of Liquid Crystalline Supramolecules With Anisotropic Fluorescence Emission
    作者:Wu,Jun; Yi,Zeyuan; Lu,Xuemin; Chen,Shuangshuang; Lu,Qinghua
    参考文献:Polymer Chemistry 日期:2014 卷标:5(7) 页码:2567-2573
📜丙烯酸,4'-(6-Bromohexyloxy)-4-Cyanobiphenyl置于potassium Hydrogencarbonate体系中,用 N,N-二甲基甲酰胺 作为反应溶剂,化学反应 12.0H,以80%的收率获得产物4-(6-丙烯酰氧基己氧基)-4'-氰基联苯
参考文献:Electro-Optical Property And Stability Of Liquid Crystal Physical Gels Controlled By Copolymerization
标题:Electro-Optical Property And Stability Of Liquid Crystal Physical Gels Controlled By Copolymerization
摘要:A Series Of Side Chain Liquid Crystal Copolymers With Different Copolymerization Ratios Have Been Successfully Synthesized By Copolymerization Of (4'-Cyanobiphenyl-4-Oxy) Acrylate] (M0Acb,Rigid Component) And (4-Cyanobiphenyl-4'-Oxy) Hexyl Acrylate (M6Acb,Flexible Component). The Liquid Crystal Physical Gel (Lc-Pgel) Can Be Prepared By Blending The Copolymer With 5Cb. The Introduction Of The Flexible Component Improves The Compatibility Of The Copolymers And 4-Pentyl-4'-Cyanobiphenyl (5Cb),So That The Transparent Gel Can Be Obtained Above The 5Cb Clear Point. The Gelation Ability Of The Copolymer And The Mechanical Properties Of The Liquid Crystalline Physical Gels Formed By The Side Chain Liquid Crystal Copolymers Can Be Effectively Regulated By Changing Copolymerization Ratios. Further Studies Have Found That The Surface Anchoring Between The Copolymers And 5Cb Also Can Be Regulated By Changing The Proportion Of Two Components In The Copolymer And The Composition Of Copolymer With The Maximum Surface Anchoring Is Poacb (0.80)-Co-P6Acb (0.20). The Copolymerization Ratios Can Further Regulate The Electro-Optical Properties Of The Lc-Pgel .By Changing The Surface Anchoring. The Stronger Surface Anchoring Can Lead To Higher Driving Voltage And Contrast Ratio Of Lc-Pgel. However,After Orientation In An Electric Field,The Increased Surface Anchoring Can Help The Lc-Pgel Recover Faster To Its Original State.
DOI:10.1016/j.Reactfunctpolym.2018.07.008

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摘要:Compound: 2-Propenoic acid, 6-[(4′-cyano[1,1′-biphenyl]-4-yl)oxy]hexyl ester, homopolymer
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