📜Potassium Hydrogensulfate置于水,Fluorine体系中,用 水 作为反应溶剂,化学反应生成 过氧单硫酸 参考文献:Bancroft,W. D.; Jones,N. C.,Transactions Of The American Electrochemical Society,1929,Vol. 55,P. 183-195 标题:Bancroft,W. D.; Jones,N. C.,Transactions Of The American Electrochemical Society,1929,Vol. 55,P. 183-195
专利信息
专利号:US-5936080-A 优先权日:1996-05-24 标题 :Compositions and methods for the synthesis of organophosphorus derivatives 发明人:STEC WOJCIECH J; WOZNIAK LUCYNA 权利人:GENTA INC; POLSKA AKADEMIA NAUK INSTYTUT 摘要:New organophosphorus mononucleoside derivatives, methods of their synthesis and methods for the synthesis of organophosphorus dinucleotide derivatives utilizing the organophosphorus mononucleosides are provided. Synthesized organophosphorus mononucleoside derivatives of the present invention are characterized by the formula; ##STR1## Organophosphorus dinucleoside derivatives prepared from the synthesis methods provided in the present invention are characterized by the formula; ##STR2##
专利号:US-7527712-B2 优先权日:2002-07-23 标 题 :Method for the continuous purification by distillation of the solvent methanol, used in the synthesis of propylene oxide 发明人:BASSLER PETER; GOEBBEL HANS-GEORG; TELES JOAQUIM HENRIQUE; RUDOLF PETER 权利人:BASF AG 摘要:Process for the continuously operated purification by distillation of the methanol used as solvent in the synthesis of propylene oxide by reaction of a hydroperoxide with propylene, with the methoxypropanols being separated off simultaneously, wherein the solvent mixture obtained in the synthesis is separated in a dividing wall column into a low-boiling fraction including methanol, an intermediate-boiling fraction containing the methoxypropanols as azeotrope with water and a high-boiling fraction including water and propylene glycol.
专利号:US-7332634-B2 优先权日:2002-07-23 标题:Method for the continuous purification by distillation of 1,2-propylene glycol that accumulates during the synthesis of propylene oxide without coupling products 发明人:BASSLER PETER; GOEBBEL HANS-GEORG; TELES JOAQUIM HENRIQUE; RUDOLF PETER 权利人:BASF AG 摘要:The invention relates to a continuously operated process for the purification by distillation of the 1,2-propylene glycol formed as by-product in the synthesis of propylene oxide, wherein the mixture formed in the synthesis which contains the 1,2-propylene glycol is separated in a dividing wall column into low-, intermediate- and high-boiling fractions and the 1,2-propylene glycol is taken off as intermediate boiler at the side offtake of the column.
专利号:US-5856465-A 优先权日:1996-05-24 标 题:Compositions and methods for the synthesis of chirally pure organophosphorus nucleoside derivatives 发明人:STEC WOJCIECH JACEK; WOZNIAK LUCYNA 权利人:POLSKA AKAD NAUK CENTRUM 摘要:Methods for the stereospecific synthesis of chirally pure organophosphorus dinucleotide derivatives and nucleoside monomer synthons used in their synthesis are provided. These methods allow for conversion of nucleoside intermediates of unchosen sense of P-chirality to nucleoside monomer synthons of chosen sense of P-chirality. Also provided are novel nucleoside intermediates useful in such methods.
专利号:US-10053406-B2 优先权日:2015-10-23 标题 :Synthesis of honokiol 发明人:JARACZ STANISLAV; KOZLOWSKI MARISA; EUN LEE YOUNG; KIM SUN MIN 权利人:COLGATE PALMOLIVE CO; UNIV PENNSYLVANIA 摘要:Disclosed herein are improved methods for the synthesis of honokiol, as well as methods for the synthesis of 3,3′-di-tert-butyl-5,5′-dimethyl-[1,1′-biphenyl]-2,4′-diol, 3′,5-dimethyl-[1,1′-biphenyl]-2,4′-diol, and 2,4′-dimethoxy-3′,5-dimethyl-1,1′-biphenyl, 3,3′,5,5′-tetra-tert-butyl-[1,1′-biphenyl]-2,4′-diol, and certain tetrasubstituted bisphenols, and uses therefor.
专利号:EP-0850248-B1 优先权日:1995-09-01 标 题 :Compositions and methods for the synthesis of organophosphorus derivatives 发明人:STEC WOJCIECH J; WOZNIAK LUCYNA 权利人:POLSKA AKAD NAUK CENTRUM 摘要:Methods for the stereospecific synthesis of chirally pure organophosphorus dinucleotide derivatives and nucleoside monomer synthons used in their synthesis are provided. These methods allow for conversion of nucleoside intermediates of unchosen sense of P-chirality to nucleoside monomer synthons of chosen sense of P-chirality. Also provided are novel nucleoside intermediates useful in such methods.
参考标题:1-Fluoro-1-Halo-3,6-Dioxabicyclo [4.1.0]Heptane Preparation, Process And 摘要:A Class Of Compounds, Namely 1-Fluoro-1-Halo-3,6-Dioxabicyclo[4.1.0]Heptanes And A Process Using These Compounds In The Preparation Of Fluoromalonaldehyde Acetals. The 1-Fluoro-1-Halo-3,6-Dioxabicyclo[4.1.0]Heptane Is Brought Into Contact With An Alcohol In An Acid Medium. The Fluoromalonaldehyde Acetals Obtained Are Also New Products, Which Are Useful For The Synthesis Of Alkyl Fluoromalonates Or Of Fluorinated Nitrogen-Containing Heterocycles.
合成参考文献
摘要:S10 | SWISSPHARMA | Pharmaceutical List with Consumption Data | DOI:10.5281/zenodo.2623484 参考文献:10.1007/bf02150690 摘要:Gutmann HR. The oxidation of N-2-Fluorenamine and 4-Aminobiphenyl by peracetic acid. Cellular and Molecular Life Sciences. 1964 Mar;20(3):128–9. doi: 10.1007/bf02150690. 摘要:Yan, L.; Lin, S.; Liu, P., Science of Synthesis, (2007) 20, 761. 摘要:Yan, L.; Lin, S.; Liu, P., Science of Synthesis, (2007) 20, 736. 摘要:Aitken, K. M.; Aitken, R. A., Science of Synthesis, (2007) 31, 1290.