Iodine Chloride Compound With Neon (1:1) 以 Neat (No Solvent,Gas Phase) 作为反应溶剂,化学反应生成 氖气,一氯化碘 参考文献:Near Threshold Photofragmentation Dynamics Of Icl-neastate Van Der Waals Complexes 标题:Near Threshold Photofragmentation Dynamics Of Icl-neastate Van Der Waals Complexes 摘要:The Nascent Icl Product State Distribution Is Examined Following Vibrational Predissociation Of Icl-ne A(Va=23) Complexes Via An Optical-optical Double Resonance Technique. Icl Fragments Are Produced In Approximately Equal Proportion In The Va=22 And 21 Levels Of The A(3π1) State. Low Rotational Levels Of Icl A(Va=22) Are Primarily Populated,Ja=1-8,Accessing Only A Small Portion Of Allowed States. Icl A(Va=21) Fragments Are Produced With Up To 69 Cm−1 Of Rotational Energy In A Broad Distribution Which Extends To Nearly The Energetic Limit. Homogeneous Broadening Of The Icl-ne Feature Indicates A Vibrational Predissociation Lifetime Between 2.3 And 50 Ps. DOI:10.1063/1.454644
专利信息
专利号:US-2016214860-A1 优先权日:2013-09-19 标题:Method of synthesis of unsolvated mixed cation borohydrides 发明人:JARON TOMASZ; WEGNER WOJCIECH; GROCHALA WOJCIECH 权利人:JAROÑ Tomasz; WEGNER WOJCIECH; GROCHALA WOJCIECH 摘要:The present invention relates to a novel method of synthesis of unsolvated mixed cation borohydrides of a general formula M x M′ y (BH 4 ) z , where M and M′ stand for metal cations, x, y, and z are stoichiometric coefficients. The method of synthesis according to the present invention is characterised in that the precursors having a general formula M[A n ] u and [Cat] v M′(BH 4 ) w are used for the synthesis, where [An] stands for a weakly coordinating anion; [Cat] stands for weakly coordinating cation; u, v, and w are the stoichiometric coefficients; and the synthesis is carried out under an inert to the reagents atmosphere—according to the general reaction equation: x M[An] u +y [Cat] v M′(BH 4 ) w →M x M′ y (BH 4 ) z +xu [Cat][An] where z=yw, xu=yv; M x M′ y (BH 4 ) z is the product of the reaction.
专利号:US-10661239-B2 优先权日:2016-04-29 标 题 :Catalytic reactor configuration, preparation and method of direct synthesis of ethylene through oxygen-free catalysis of methane 发明人:BAO XINHE; GUO XIAOGUANG; FANG GUANGZONG; PAN XIULIAN; MENG JINGHENG; YU QINQIN; TAN DALI 权利人:DALIAN INST CHEM & PHYSICS CAS 摘要:A reactor configuration comprises an inlet section I, a preheating section II, a transition section III, a reaction section IV and an outlet section V; except for the preheating section II and the reaction section IV, the existence of the inlet section I, the transition section III and the outlet section V depends on reaction conditions; and the process realizes no coke deposition synthesis of methane and high selectivity synthesis of ethylene. The methane conversion rate is 20-90%; ethylene selectivity is 65-95%; propylene and butylene selectivity is 5-25%; aromatic hydrocarbon selectivity is 0-30%; and coke deposition is zero.
专利号:US-2023257270-A1 优先权日:2020-07-10 标 题 :Synthesis of carbon nano-onions by nanodiamond annealing and functionalization of carbon materials 发明人:GOLSHARIFI NIMA; AMAKUBO SUGURU FREDERICK 权利人:NDB INC 摘要:Disclosed herein are methods of synthesizing carbon nano-onions, their functionalization methods, and their use as electrode material. More specifically, disclosed are methods of converting nanodiamonds into carbon nano-onions, chemical synthesis of carbon nano-onions from reagents, and functionalization using reagents, reactive gases, and photoexcitation. The use of the synthesized and functionalized carbon nano-onions as an electrode by using them as a composite structure is also disclosed.
专利号:US-9120848-B2 优先权日:2010-09-23 标题 :Non-aqueous synthesis of polysaccharide-protein conjugates for vaccines 发明人:KAPLAN HARVEY 权利人:KAPLAN HARVEY 摘要:The invention is a novel chemical coupling methodology for the synthesis of a stable polysaccharide-protein conjugates as the immunogenic component for vaccines. A covalent bond is formed between polysaccharide and protein in the dry state in the absence of water and oxygen. A polysaccharide antigen is covalently linked to the protein by activating the polysaccharide with periodate to introduce aldehyde groups into the polysaccharide, lyophilizing an aqueous mixture of a protein and activated polysaccharide, sealing the dry lyophilized mixture in a vessel under vacuum or inert gas and then incubating the sealed vessel at an elevated temperature.
专利号:US-8784766-B1 优先权日:2009-01-16 标 题 :Diamond synthesis employing nanoparticle seeds 发明人:UPPIREDDI KISHORE; MORELL GERARDO; WEINER BRAD R 权利人:UPPIREDDI KISHORE; MORELL GERARDO; WEINER BRAD R; UNIV PUERTO RICO 摘要:Iron nanoparticles were employed to induce the synthesis of diamond on molybdenum, silicon, and quartz substrates. Diamond films were grown using conventional conditions for diamond synthesis by hot filament chemical vapor deposition, except that dispersed iron oxide nanoparticles replaced the seeding. This approach to diamond induction can be combined with dip pen nanolithography for the selective deposition of diamond and diamond patterning while avoiding surface damage associated to diamond-seeding methods.
专利号:US-11919071-B2 优先权日:2020-10-30 标 题:Systems and methods for synthesis of spheroidized metal powders 发明人:BADWE SUNIL BHALCHANDRA; TURCHETTI SCOTT JOSEPH; BHATTACHARYA SUDIP; REDJDAL MAKHLOUF 权利人:6K INC 摘要:Disclosed herein are embodiments of systems and method for processing feedstock materials using microwave plasma processing. Specifically, the feedstock materials disclosed herein pertain to metal powders. Microwave plasma processing can be used to spheroidize the metal powders and form metal nitride or metal carbide powders. The stoichiometry of the metal nitride or metal carbide powders can be controlled by changing the composition of the plasma gas and the residence time of the feedstock materials during plasma processing.
参考文献:10.1063/1.3605595 摘要:Garand E, Neumark DM. Study of RgS- and RgS (Rg = Ne, Ar, and Kr) via slow photoelectron velocity-map imaging spectroscopy and ab initio calculations. J Chem Phys. 2011 Jul 14;135(2):024302. doi: 10.1063/1.3605595.