CAS: 5111-69-3; 5-Methoxy-2,3-Dihydro-1H-Indene

上下游产品

CAS号1470-94-6 5-茚醇 | CAS号74-88-4 碘甲烷 | CAS号77-78-1 硫酸二甲酯 | CAS号5111-70-6 5-甲氧基-1-茚酮 | CAS号3199-77-7 5-甲氧基-2,3-二氢-1H... | CAS号496-11-7 茚满 | CAS号67-56-1 甲醇 | CAS号562-54-9 甲基硫酸钾 | CAS号5111-70-6 5-甲氧基-1-茚酮 | CAS号13623-25-1 6-甲氧基-1-茚满酮 | CAS号3469-08-7 5-甲氧基-1H-茚 | CAS号1885-13-8 4-甲氧基邻苯二甲酸 | CAS号73615-83-5 6-甲氧基-2,3-二氢-5-甲酰基茚 | CAS号76413-89-3 5-甲氧基-2-茚满酮 | CAS号3199-77-7 5-甲氧基-2,3-二氢-1H... | CAS号1470-94-6 5-茚醇 | CAS号29278-11-3 2-BROMO-2,3-DIH... | CAS号77366-70-2 6-methoxy-5-ind...

📜5-甲氧基-2,3-二氢-1H-茚-1-醇置于palladium Dichloride体系中,用 甲醇 作为反应溶剂,化学反应 18.0H,以99%的收率获得产物5-甲氧基茚满
参考文献:聚甲基氢硅氧烷对钯醇和芳族酮进行钯催化的co加氢水解
标题:聚甲基氢硅氧烷对钯醇和芳族酮进行钯催化的co加氢水解
摘要:已经开发出一种简单的方法,用于在聚甲基氢硅氧烷(pmhs)存在下对芳族酮和苄醇进行还原性脱氧.使用氯化钯(pdcl 2)作为催化剂,以pmhs作为氢化物源,可以很好地实现芳族酮和苄醇(包括仲醇)到相应的亚甲基烃的还原脱氧.用芳基烷基酮和二芳基酮成功地进行了这种脱氧,例如分别通过对苯乙酮和二苯甲酮的还原性脱氧来说明.相应的苯甲醇和仲醇类似物也可以通过pdcl 2 / Pmhs系统转化成它们各自的亚甲基烃.
DOI:10.1002/adsc.201200832

专利信息

专利号:EP-1851188-A1
优先权日:2005-02-22
标 题 :Improved process for the synthesis of enantiomeric indanylamine derivatives

专利号:WO-2021097139-A1
优先权日:2019-11-15
标 题 :Chiral synthesis of a tertiary alcohol

专利号:WO-2006120577-A1
优先权日:2005-02-22
标 题:Improved process for the synthesis of enantiomeric indanylamine derivatives

专利号:US-7176312-B2
优先权日:2001-10-12
标 题:Kinase inhibitor scaffolds and methods for their preparation
发明人：DING SHENG; DING QIANG; GRAY NATHANAEL S
权利人:IRM LLC
摘要:General methods for the solution phase as well as solid phase synthesis of various substituted heteroaryls has been demonstrated. These substituted heteroaryls can be further elaborated by aromatic substitution with amines at elevated temperature or by anilines, boronic acids and phenols via palladium catalyzed cross-coupling reactions.