CAS: 1314-08-5; Palladium(Ii) Oxide

该化合物是一种无机化合物,其特征是深褐色至黑色外观,是的二氧化二氧化物,其氧化状态为+2.PdO以其催化特性而著称,它具有各种化学反应的价值,特别是在催化氧化过程中.该化合物在环境条件下相对稳定,但可以在加热中分解,释放氧气.该化合物在水中溶解,但可以在强酸中溶解,形成盐.PdO还被用于氢气的生产和其他化合物的合成.此外,它还具有半导体特性,可在电子应用中加以利用.安全考虑包括谨慎处理,因为它可以是皮肤和呼吸刺激剂.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    氯化钯 反应生成一氧化钯
    参考文献:Chiou,Bi-Shiou;Li,Jeng-Jen;Duh,Jeng-Gong,J. Electron. Mater.,17,(1988) N,C. 485-492
    标题:Chiou,Bi-Shiou;Li,Jeng-Jen;Duh,Jeng-Gong,J. Electron. Mater.,17,(1988) N,C. 485-492

    专利信息


    专利号:US-10450201-B2
    优先权日:2017-10-04
    标题 :Method for the synthesis of nanoparticles of heterometallic nanocomposite materials
    发明人:SOHAIL MANZAR; SHARIF MUHAMMAD; KHAN SAFYAN A; SHER MUHAMMAD; JAGADEESH RAJENAHALLY V
    权利人:UNIV KING FAHD PET & MINERALS
    摘要:A simple one pot sol-gel method for the synthesis of bi-metal nanostructures is based on non-noble metals (Fe, Co and Sn) and titanium. The method involves the synthesis of mixed metal nanoscale composites using low cost precursors which allow for the synthesis of desired nanocomposite materials with self-scarifying titanium or silica supports. The procedure does not require any surfactant or any need for pH controlled step. Applicants' method involves the in-situ generation of precursors and their simultaneous entrapment in a gel. This simple one pot synthesis allows for the synthesis of homogenous size, shape and distribution of targeted nanostructures. Further, this method can be applied for the preparation of various nanocomposite materials using different choices of metals and self-scarifying supports. Applicants also show that Pd, the noble metal based nanocomposite is feasible.

    专利号:US-2012165520-A1
    优先权日:2010-12-23
    标题:Process for the synthesis of prodrugs of opioids
    发明人:MCGEE PAUL; GARNETT IAN; JUAN E; MANAGE A; CARNIAUX JEAN-FRANCOIS
    权利人:MCGEE PAUL; GARNETT IAN; JUAN E; MANAGE A; CARNIAUX JEAN-FRANCOIS
    摘要:The present invention provides a process for the synthesis of opioid prodrugs. In particular, the present invention provides a process for the synthesis of opioid prodrugs comprising: treating an opioid, in the form of a salt or a freebase, with a carbonyl synthon to form an activated intermediate and subsequently reacting the activated intermediate with an amine, in the form of a salt or a freebase.

    专利号:US-2025023061-A1
    优先权日:2021-11-17
    标题 :Method for the synthesis of a metal catalyst surrounded with a carbon matrix
    发明人:CHATENET MARIAN; DOAN HUONG; SGARBI RICARDO
    权利人:INST POLYTECHNIQUE GRENOBLE; UNIV GRENOBLE ALPES; CENTRE NAT RECH SCIENT; UNIV SAVOIE MONT BLANC
    摘要:A method for a synthesis of a metal catalyst, including providing at least one metal complex including a metal ion and a non-chelating complexing agent having carbon, the complex having a decomposition temperature, and performing a pyrolysis of the complex at a temperature greater than or equal to a decomposition temperature of the complex, whereby inducing a formation of nanoparticles surrounded by a carbon matrix to form the catalyst. Thanks to the carbon matrix, the catalysts provided herein can be corrosion resistant, self-healing, more cost-effective, and can have higher catalytic activity. The synthesis of the catalyst and its properties can furthermore be improved compared to catalysts formed from a complex including a chelating.

    专利号:US-2022218741-A1
    优先权日:2019-05-31
    标 题 :Cell-Mediated Synthesis of Noble Metal Oxide Nanoparticles and Biomedical Applications Thereof
    发明人:CRUZ DAVID MEDINA; CHEN JUNJIANG; WEBSTER THOMAS J
    权利人:UNIV NORTHEASTERN
    摘要:Human dermal fibroblasts (HDF) and melanoma (MEL) cells are used herein for synthesis of metal nanoparticles. For example, synthesis of nanoparticles of gold (Au), palladium (Pd), platinum (Pt), and bimetallic formulations of gold-palladium (AuPd) and gold-platinum (AuPt) is demonstrated with HDF and MEL using a straightforward, eco-friendly and cost-effective approach. The nanostructures are purified and used in biomedical tests, which show selective behavior. The production of nanoparticles allows for stopping of the growth of cancer cells and the ability of new healthy cells to grow on top. The production of nanoparticles with the cells allows for an environmental-resistance behavior within the cells, showing the ability to stand for extreme environmental conditions.

    专利号:WO-2025215126-A1
    优先权日:2024-04-12
    标题:Synthesis of vidofludimus and its calcium salt
    发明人:VITT DANIEL; IGLICAR PETRA; GEGE CHRISTIAN; Mühler Andreas; KOHLHOF HELLA; GRÖPPEL MANFRED
    权利人:IMMUNIC AG
    摘要:The invention relates to the process of preparation of 2-fluoro-4-(3-methoxyphenyl)aniline (3) as an intermediate. Said intermediate 2-fluoro-4-(3-methoxyphenyl)aniline (3) is obtained in a Suzuki coupling reaction from (3-methoxyphenyl)boronic acid (1) and 4-bromo-2-fluoro-aniline (2). The invention further relates to the synthesis of vidofludimus (5) from said intermediate 2-fluoro-4-(3-methoxy-phenyl)aniline (3) and from 1-cyclopentene-1,2-dicarboxylic anhydride (4). The invention further relates to the synthesis of vidofludimus calcium (6) from said vidofludimus (5) and from a calcium salt, preferably Ca(OH)2.

    专利号:US-4282148-A
    优先权日:1980-01-14
    标 题:Synthesis of thienamycin via esters of (3SR, 4RS)-3-[(SR)-1-hydroxyethyl]-β,2-dioxo-4-azetidinebutanoic acid
    发明人:LIU THOMAS M H; MELILLO DAVID G; RYAN KENNETH M; SHINKAI ICHIRO; SLETZINGER MEYER
    权利人:MERCK & CO INC
    摘要:Disclosed is a process for the stereocontrolled total synthesis of thienamycin, which synthesis proceeds via intermediate II: II wherein R3 is a readily removable carboxyl protecting group.
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    合成参考文献


    摘要:Toyota, S., Science of Synthesis, (2010) 45, 880.
    摘要:Jux, N.; Montforts, F.-P.; Haake, E., Science of Synthesis Knowledge Updates, (2022) 1, 59.
    摘要:Coote, S. C.; Smith, L. H. S.; Procter, D. J., Science of Synthesis Knowledge Updates, (2010) 3, 464.
    摘要:Kashemirov, B. A.; Błażewska, K.; Justyna, K.; Lyu, J.; McKenna, C. E., Science of Synthesis Knowledge Updates, (2021) 1, 334.
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