专利号:WO-2023152730-A1 优先权日:2022-02-14 标题 :Amine-borane adducts in the synthesis of polyester and its copolymers using cyclic esters and compositions thereof 发明人:FENG XIAOSHUANG; LIU JINGJING; GNANOU YVES 权利人:UNIV KING ABDULLAH SCI & TECH 摘要:Embodiments of the present disclosure provide for the process of synthesis of polyester and its copolymers through (co)polymerization of cyclic esters and with other oxygenated monomers using amine-borane adduct. Embodiments of the present disclosure further describe the controlled anionic ring-opening polymerization of the cyclic compounds. Embodiments of the present disclosure also describe the polymerization of cyclic compounds using the synergistic effect of amines and thioureas. Embodiments of the present disclosure also describe compositions of polymers formed by the said process.
专利号:US-5606077-A 优先权日:1995-02-21 标 题:Method for the synthesis of organopolysiloxanes containing carbonate groups 发明人:LERSCH PETER; WEITEMEYER CHRISTIAN 权利人:GOLDSCHMIDT AG TH 摘要:The invention relates to a method for the synthesis of organopoiysiloxanes of the general formula which contains cyclic carbonate groups. The inventive compounds have a high polarity, can be synthesized easily and, because of their compatibility with polar media, find use as additives for dispersion paints or lacquers and for coating the surfaces of pigments and fillers.
专利号:US-11753503-B2 优先权日:2018-05-17 标 题:Supported onium salts as initiators for the synthesis of polycarbonates by copolymerization of CO2 with epoxides 发明人:FENG XIAOSHUANG; PATIL NAGANATHA; LUCIANI CAROLINE; GNANOU YVES; HADJICHRISTIDIS NIKOS 权利人:UNIV KING ABDULLAH SCI & TECH 摘要:Supported onium salts used as initiators for the synthesis of polycarbonates by copolymerization of carbon dioxide with epoxides are described. Embodiments of the present disclosure describe initiators comprising an insoluble portion including an onium cation attached to an insoluble support; and an anion, wherein the anion is a counter-ion to the onium cation. Embodiments further describe methods of making polycarbonates using the initiator, methods of making initiators, and the like.
专利号:US-12234203-B2 优先权日:2020-03-12 标 题:Process for the synthesis of cannabidiol and intermediates thereof 发明人:ANAND RADHIKA; SHARMA SUMIT; SINGH CHAM PANKAJ; GANNEDI VEERANJANEYULU; KUMAR MUKESH; PRATAP SINGH VARUN; PRAKASH RAHUL VISHAV; ASREY VISHWAKARMA RAM; PAL SINGH PARVINDER 权利人:COUNCIL OF SCIENT AND INDUSTRIAL RESEARCH AN INDIAN REGISTERED BODY INCORPORATED UNDER THE REGN OF T; COUNCIL OF SCIENT AND INDUSTRIAL RESEARCH AN INDIAN REGISTERED BODY INCORPORATED UNDER THE REGN OF S 摘要:The present invention relates to process for the preparation of cannabidiol (A) from the coupling of (D) and (E) through the intermediates (C) and (D) starting from compound (B). The invention further relates to the novel compounds (B), (C), (D) and (E) and reagents used in this process. More specifically, this invention provides the manufacturing of Cannabidiol (A) in milligram to gram or kilogram scale.
专利号:US-11292873-B2 优先权日:2013-11-05 标 题 :Etheramines prepared from a mixture of two or more multifunctional alcohol initiators, and their use as curatives or intermediates for polymer synthesis 发明人:ZHOU HUI; LEWIS DAVID C; KLEIN HOWARD P; RENKEN TERRY L; PATTERSON LEAH 权利人:HUNTSMAN PETROCHEMICAL LLC 摘要:Implementations described herein generally relate to etheramine mixtures formed from a mixture of two or more multifunctional alcohol initiators, processes for the etheramine mixtures production, and its use as a curing agent or as a raw material in the synthesis of polymers. In one implementation, the process comprises mixing a polyol initiator having a melting point greater than a processing temperature and a polyol initiator having a melting point less than the processing temperature to form a polyol initiator mixture having a melting point less than the processing temperature, charging the polyol initiator mixture to an alkoxylation reaction zone, contacting the polyol initiator mixture with an alkylene oxide in the alkoxylation reaction zone to provide a mixture of alkoxylated precursor polyols and charging the mixture of alkoxylated precursor polyols to a reductive amination zone and reductively aminating the mixture of alkoxylated precursor polyols to form the etheramine mixture.
专利号:US-9006347-B2 优先权日:2011-09-08 标 题 :Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent 发明人:WILLIAMS CHARLOTTE K; KEMBER MICHAEL; BUCHARD ANTOINE; JUTZ FABIAN 权利人:IMP INNOVATIONS LTD 摘要:The invention provides a process for the synthesis of a polycarbonate, the process comprising the step of reacting carbon dioxide with at least one epoxide in the presence of a catalyst of formula (I) and a chain transfer agent. The invention also provides a polymerization system for the copolymerization of carbon dioxide and at least one epoxide comprising a catalyst of formula (I) and a chain transfer agent, polycarbonates produced by the inventive process, a block copolymer comprising a polycarbonate produced by the inventive process, and a method of producing the block copolymer. The invention also relates to novel catalysts of formula (III).
摘要:Wohlgemuth, R., Science of Synthesis: Biocatalysis in Organic Synthesis, (2015) 2, 551. 摘要:Bolduc, T. G.; Thomson, B.; Sammis, G. M., Science of Synthesis, (2020) , 394.