CAS: 89615-73-6; (2R)-2-Acetamido-3-(4-Nitrophenyl)Propanoic Acid

该化合物是一种氨酸衍生物,其特点是有乙酰基质组和硝基苯替代物.该化合物的特点是一个手淫中心,它有助于其立体化学,特别是(R)配置.它是一种白色至白色的,在水和乙醇等极溶剂中溶解的,由于酸性和基本功能组的存在而溶解的脱白固体.硝基苯组增强了其电子特性,有可能使其在各种化学应用中有用,包括作为药物中的建筑块或作为生物化学实验中的探测器.该化合物的酸性可归因于氨基酸功能组,而乙基酰基组则可以参与氢的结合,影响其再活性和与生物系统的互动.

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    上下游产品

    N-acetyl-4-nitro-DL-phenylalanineN-acetyl-4-nitro-DL-phenylalanine trans-cinnamic acidα-acetylamino-4-nitro-trans-cinnamic acid 2-acetylamino-2-(4-nitrobenzyl)malonic acid diethyl ester 2-(N-acetylamino)-2-benzylpropanedioic diethyl ester (R)-4-nitro-phenylalanine Ac-p-NO2-D-Phe-Mel-OEt N-acetyl-4-nitro-D-phenylalanine ethyl esterN-acetyl-4-nitro-D-phenylalanine ethyl ester 4-nitro-D-phenylalanine ethyl ester; hydr°Chloride

    合成工艺路线路线简述

    • 93341-45-8 = 89615-73-6
      反应条件:1.1 Reagents: Hydrogen Catalysts: Rhodium(1+),[(1,2,5,6-η)-1,5-Cyclooctadiene][rel-(1R,5R,6R)-Spiro[4.4]Nonane-1,... Solvents: Methanol; 10 Min,1 Atm,25 °C
      标题:(1R,5R,6R)-Spiro[4.4]Nonane-1,6-Diyl Diphenylphosphinous Acid Ester
      作者:Kwok,Wai Him; Hu,Wen Hao; Chan,Albert S. C.; Barreiro,Elena M.; Hii,King Kuok; Et Al
      参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2014 卷标:1 页码:1-3]

      93341-45-8 = 89615-73-6
      反应条件:1.1 Reagents: Hydrogen Catalysts: Rhodium(1+),[(1,2,5,6-η)-1,5-Cyclooctadiene][spiro[4.4]Nonane-1,6-Diyl Bis(Diph... Solvents: Methanol,Tetrahydrofuran
      标题:Novel Spirobicyclic Phosphinite Ligands And Their Application In Homogeneous Catalytic Hydrogenation Reactions
      作者:Chan,Albert S. C.; Hu,Wenhao; Pai,Cheng-Chao; Lau,Chak-Po; Jiang,Yaozhong; Et Al
      参考文献:Journal Of The American Chemical Society 日期:1997 卷标:119(40) 页码:9570-9571]

      93341-45-8 = 89615-73-6
      反应条件:1.1 Reagents: Hydrogen Catalysts: Rhodium(1+),[(1,2,5,6-η)-1,5-Cyclooctadiene][rel-(1R,5R,6R)-Spiro[4.4]Nonane-1,... Solvents: Methanol; 10 Min,1 Atm,25 °C
      标题:(1R,5R,6R)-Spiro[4.4]Nonane-1,6-Diyl Diphenylphosphinous Acid Ester (R-Spirop)
      作者:Kwok,Wai Him; Hu,Wen Hao; Chan,Albert S. C.
      参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

      93341-45-8 = 89615-73-6
      反应条件:1.1 Reagents: Hydrogen Catalysts: N,N′-[(1R)-5,5′,6,6′,7,7′,8,8′-Octahydro[1,1′-Binaphthalene]-2,2′-Diyl]Bis[p,P-D... Solvents: Ethanol
      标题:A Comparison Of The Asymmetric Hydrogenation Catalyzed By Rhodium Complexes Containing Chiral Ligands With A Binaphthyl Unit And Those With A 5,5',6,6',7,7',8,8'-Octahydro-Binaphthyl Unit
      作者:Zhang,Fu-Yao; Kwok,Wai Him; Chan,Albert S. C.
      参考文献:Tetrahedron: Asymmetry 日期:2001 卷标:12(16) 页码:2337-2342
    📜2-Acetamido-3-(4-Nitrophenyl)Propionic Acid 反应生成 (R)-2-乙酰胺基-4-硝基苯丙氨酸
    参考文献:Bergel Et Al.,Journal Of The Chemical Society,1955,P. 1229
    标题:Bergel Et Al.,Journal Of The Chemical Society,1955,P. 1229

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    参考DOI号:10.1016/j.tetasy.2012.08.017
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