CAS: 5372-81-6; Dimethyl Aminoterephthalate

上下游产品

CAS号5292-45-5 2-硝基对苯二甲酸二甲酯 | CAS号120-61-6 对苯二甲酸二甲酯 | CAS号67-56-1 甲醇 | CAS号10312-55-7 2-氨基对苯二甲酸 | CAS号60728-41-8 2-氨基对苯二甲酸1-甲酯 | CAS号808123-08-2 acetylamino-ter... | CAS号74-88-4 碘甲烷 | CAS号409127-32-8 2,6-二氯-4-氰基苯甲酸甲酯 | CAS号32888-88-3 2-氨基-5-氯-1,4-苯二甲酸 | CAS号313535-84-1 4-氧代-3,4-二氢喹唑啉-... | CAS号1829-22-7 2-碘对苯二甲酸 | CAS号6342-72-9 2-羟基对苯二甲酸二甲酯 | CAS号610-29-7 2-硝基对苯二甲酸 | CAS号77423-14-4 4-羧基靛红酸酐 | CAS号636-94-2 2-羟基对苯二甲酸 | CAS号32888-87-2 DIMETHYL 2-AMIN...

2-硝基对苯二甲酸二甲酯置于氢气体系中,130.0 °C,100.0 Kpa 条件下,反应 6.0H,以99%的收率获得产物2-氨基对苯二甲酸二甲酯
参考文献:铝-有机骨架连接的单点镍(II)-氢化物,用于多相化学选择性催化
标题:铝-有机骨架连接的单点镍(II)-氢化物,用于多相化学选择性催化
摘要:化学选择性的和非均质的富含地球的金属催化剂的开发对于环境友好的化学合成至关重要.我们报告了一种高效,化学选择性和可重复使用的单中心氢化镍(II)氢化物催化剂,该催化剂基于坚固且多孔的铝金属有机骨架(mofs)(dut-5),用于将硝基和腈化合物加氢成相应的胺并进行氢解温和条件下制备芳基醚.镍-氢化物催化剂的制备是通过的氢氧化铝次级结构单元的金属化的al具有(μ的式dut-5的(事业部)2-Oh)(bpdc)(bpdc = 4,4'-联苯双酯)与nibr 2然后与naet 3反应bh.dut-5-Nih具有广泛的底物范围,在1 Bar H 2下氢化芳族和脂肪族硝基和腈化合物时,具有出色的官能团耐受性至少可以回收再利用10次.通过改变腈氢化的反应条件,还选择性地提供了对称或不对称的仲胺.实验和计算研究表明,在营业额限制步骤中,镍与镍的可逆腈配位是可逆的,然后将1,2-的配位腈插入氢化镍中.此
DOI:10.1021/acscatal.0C04379

专利信息

专利号:US-8772301-B2
优先权日:2009-12-18
标题 :Compounds for treating disorders mediated by metabotropic glutamate receptor 5, and methods of use thereof
发明人：HARDY LARRY WENDELL; HEFFERNAN MICHELE L R; WU FRANK XINHE; SPEAR KERRY L; SARASWAT LAKSHMI D
权利人:HARDY LARRY WENDELL; HEFFERNAN MICHELE L R; WU FRANK XINHE; SPEAR KERRY L; SARASWAT LAKSHMI D; SUNOVION PHARMACEUTICALS INC
摘要:Provided herein are compounds and methods of synthesis thereof. The compounds set forth herein are useful for the treatment, prevention, and/or management of various disorders, such as neurological disorders, neurodegenerative disorders, neuropsychiatric disorders, disorders of cognition, learning or memory, gastrointestinal disorders, lower urinary tract disorder, and cancer. Compounds set forth herein modulate the activity of metabotropic glutamate receptor 5 (mGluR5) in the central nervous system or the periphery. Pharmaceutical formulations containing the compounds and their methods of use are also provided herein.

专利号:US-4136033-A
优先权日:1969-11-07
标 题:6-hydroxypyridone-2 compounds having a cationic group in the 3-position
发明人：STEINEMANN WILLY
权利人:SANDOZ LTD
摘要:Compounds of the formula ##STR1## wherein K.sup.⊕ is a cationic group, preferably heterocyclic, n R is hydrogen or an organic radical, preferably alkyl, phenyl or acyl, n R 1 is hydrogen, hydrocarbyl, substituted hydrocarbyl, heterocyclyl, substituted heterocyclyl, amino or substituted amino, and n A.sup.⊖ is an anion, n Are useful as intermediates in the synthesis of azo dyes of the formula ##STR2## wherein D is an aromatic carbocyclic or heterocyclic diazo component radical, and n K.sup.⊕, r, r 1 and A.sup.⊖ are as defined above.

专利号:US-5616778-A
优先权日:1989-12-22
标题 :Modified form of bis-1,4-[2'-(2',5'-dimethoxycarbonylphenylazo)-3'-oxobutyramido]benzene and process for its synthesis
发明人：GOLDMANN JUERGEN; KAUL BANSI L
权利人:SANDOZ LTD
摘要:The compound of the formula ##STR1## having the following CIELAB values: L*=82.55 n a*=11.53 n b*=90.49 n C*=91.22 and n H*=82.74.

专利号:CN-106632092-A
优先权日:2016-12-22
标 题:A kind of 1,3-dimethyl-7-substituted quinazoline-2,4-diketone compound and its synthesis method and application