CAS: 527-17-3; 2,3,5,6-Tetramethylcyclohexa-2,5-Diene-1,4-Dione

该化合物是一种对称替代的五角苯衍生物,其特征是四组四甲基混合物,其定位为碳基功能的正方形,该化合物具有显著的稳定性和红氧化活动,作为有机合成的中间体和充电传输综合体中的电子接收器,因此有用.该化合物的硬性,平板结构和电子衰竭的五子核心有助于其在材料科学方面的用途,特别是在发展导电聚合物和光化应用方面.甲基替代成分提高了有机溶剂的溶性,同时保持热稳定性.该化合物还被用于电转移过程的机械学研究,因为其电化学特性十分明确.

结构式图片

相似化合物

935-92-2 527-61-7 137-18-8

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号527-18-4 四甲基氢醌 | CAS号95-93-2 1,2,4,5-四甲苯 | CAS号527-35-5 2,3,5,6-四甲基苯酚 | CAS号82363-84-6 ((2,3,5,6-tetra... | CAS号13199-54-7 1,4-dimethoxy-2... | CAS号148101-03-5 1,2,4,5-tetrame... | CAS号96-54-8 N-甲基吡咯 | CAS号151-10-0 间苯二甲醚 | CAS号110-22-5 过氧化乙酰 | CAS号527-18-4 四甲基氢醌 | CAS号61548-94-5 4-ethoxy-2,3,5,... | CAS号527-35-5 2,3,5,6-四甲基苯酚 | CAS号142347-52-2 1,2,4,5-tetrame... | CAS号484-66-2 2,3,4,5,6-五甲基苯甲醇 | CAS号19587-93-0 4-methoxy-2,3,5... | CAS号930-68-7 环己烯酮 | CAS号70128-24-4 2,3,5,6-tetrame... | CAS号23585-22-0 Benzo[1,2-c:4,5... | CAS号81-20-9 2,6-二甲基硝基苯

合成工艺路线路线简述

  • 9005-53-2 = 527-17-3 + 103-81-1 + 831-00-5 + 22607-11-0 + 74421-05-9 + 2219-78-5 + 219726-60-0 + 94391-24-9 + 60826-26-8 + 7443-70-1 + 51504-54-2 + 72386-20-0 + 79-31-2 + 494-99-5 + 646-07-1 + 4041-09-2 + 1131-62-0 + 432-25-7 + 56687-68-4 + 93-15-2
    反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Molybdenum,Copper Solvents: Methanol,Water; 7 H,220 °C1.2 Reagents: Water
    标题:Cu-Mo Doped Zeolite Zsm-5 Catalyzed Conversion Of Lignin To Alkyl Phenols With High Selectivity
    作者:Singh,Sunit Kumar; Et Al
    参考文献:Catalysis Science & Technology 日期:2015 卷标:5(4) 页码:2117-2124
Trimethyl-(2,3,5,6-Tetramethyl-4-Trimethylsilyloxyphenoxy)Silane置于氧气,二氧化氮体系中,用 二氯甲烷 作为反应溶剂,化学反应生成 杜醌
参考文献:通过氢醌与氮氧化物的催化自氧化方便地制备醌
标题:通过氢醌与氮氧化物的催化自氧化方便地制备醌
摘要:一种有效,廉价的对苯二酚自动氧化的催化方法利用了气态(no X)催化剂,该方法允许简单的后处理步骤,仅通过去除溶剂即可分离出醌.
DOI:10.1016/s0040-4039(00)76211-3

海关参考信息

专利信息


专利号:US-2024336586-A1
优先权日:2021-07-29
标题:Methods for synthesis of racemic, scalemic, and chiral alpha-tocotrienol quinone
发明人:GIANNOUSIS PETER; MOLLARD PAUL; GOUDEDRANCHE SEBASTIEN; KARASAWA TOMOYA
权利人:PTC THERAPEUTICS INC
摘要:The application discloses methods useful for the synthesis of racemic, scalemic, and chiral alpha-tocotrienol quinone, including synthetic intermediates and methods for making said synthetic intermediates.

专利号:EP-2465936-A1
优先权日:2010-12-20
标题 :Enzymatic synthesis of statins and intermediates thereof
权利人:LEK PHARMACEUTICALS
摘要:The present invention discloses a process for preparing an active pharmaceutical ingredient (API) or intermediates thereof, notably particular step in the synthesis of an intermdiate useful for example in the preparation of statins, by using an enzyme capable of catalyzing oxidation or dehydrogenation. The invention further provides an expression system effectively translating said enzyme. In addition, the invention relates to a specific use of such enzyme for preparing API or intermediate thereof, and in particular for preparing statin or interemediate thereof.

专利号:US-6955904-B2
优先权日:2001-11-29
标 题:Gene coding for quinone oxidoreductase of kluyveromyces marxianus and protein expressed therefrom
发明人:HAN YE SUN; KOH HUN YEOUNG; RHIM HYEWHON; CHA JOO HWAN; KIM WOOK HYUN; BACK JUNG HO
权利人:KOREA INST SCI & TECH
摘要:The invention is a gene coding for a quinone oxidoreductase from Kluyveromyces marxianus and a protein having an amino acid sequence expressed therefrom, which can be advantageously used in a reduction reaction of a quinone compound and synthesis of intermediates for a biologically active compound.

专利号:US-2009093521-A1
优先权日:2005-06-14
标 题 :2, 5-Bis-Diamine [1,4] Benzoquinone-Derivatives
发明人:BOLOGNESI MARIA LAURA; BANZI RITA; MINARINI ANNA; MELCHIORRE CARLO
权利人:BOLOGNESI MARIA LAURA; BANZI RITA; MINARINI ANNA; MELCHIORRE CARLO
摘要:Synthesis of 2,5-bis-diamine-[1,4]benzoquinonic derivatives having the general formula (I), products and intermediates of said synthesis; the synthesis involves the use of p-benzoquinones having the general formula (IX) and diamines having the general formula (XI).

专利号:WO-2020185896-A1
优先权日:2019-03-11
标题 :Methods for processing and storing dna encoding formats of information
发明人:LEE HENRY HUNG-YI; HENRY OLIVIER Y F
权利人:HARVARD COLLEGE
摘要:The present disclosure provides methods for selectively tagging a subset of polynucleotide sequences from a plurality of polynucleotides comprising (a) synthesizing a plurality of polynucleotide sequences by flexible-write synthesis on a solid support, (b) selectively releasing a subset of polynucleotide sequences from the plurality of synthesized polynucleotides, and (c) tagging the released subset of polynucleotide sequences.

专利号:US-7674934-B2
优先权日:2004-08-05
标题:Stabilizers for use in NVP synthesis
发明人:HOEFER FRANK; BRAND ALEXANDRA; BOETTCHER ARND; BAUMANN KATRIN; VOGELSANG REGINA
权利人:BASF AG
摘要:A process for preparing N-alkenyl compounds by reacting the corresponding NH compounds with alkynes in the liquid phase in the presence of a catalyst, wherein the reaction is carried out in the presence of at least one stabilizer, and the use of stabilizers for increasing the selectivity in a process for preparing N-alkenyl compounds by reacting the corresponding NH compounds with alkynes in the liquid phase in the presence of a catalyst.
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主要参考文献

[参考文献]: Marilyn P Merker, Et Al. Influence Of Pulmonary Arterial Endothelial Cells On Quinone Redox Status: Effect Of Hyperoxia-Induced Nad(P)H:Quinone Oxidoreductase 1. Am J Physiol Lung Cell Mol Physiol. 2006 Mar;290(3):L607-19.
[参考文献]: Marilyn P Merker, Et Al. Role Of Mitochondrial Electron Transport Complex I In Coenzyme Q1 Reduction By Intact Pulmonary Arterial Endothelial Cells And The Effect Of Hyperoxia. Am J Physiol Lung Cell Mol Physiol. 2007 Sep;293(3):L809-19.
[参考文献]: Michael Weber, Et Al. Method Development In Quantitative Nmr Towards Metrologically Traceable Organic Certified Reference Materials Used As (31)P Qnmr Standards. Anal Bioanal Chem. 2015 Apr;407(11):3115-23.
[参考文献]: Michael Weber, Et Al. Using High-Performance 1H Nmr (Hp-Qnmr) For The Certification Of Organic Reference Materials Under Accreditation Guidelines--Describing The Overall Process With Focus On Homogeneity And Stability Assessment. J Pharm Biomed Anal. 2014 May:93:102-10.
[参考文献]: Roger Giordani, Et Al. Evidence For Two Different Electron Transfer Pathways In The Same Enzyme, Nitrate Reductase A From Escherichia Coli. Eur J Biochem. 2004 Jun;271(12):2400-7.

合成参考文献


摘要:Tobe, Y.; Takeda, T., Science of Synthesis, (2010) 45, 1342.
摘要:Hitomi, Y.; Arakawa, K., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 2, 297.
摘要:Lumb, J.-P.; Esguerra, K. V. N., Science of Synthesis: Catalytic Oxidation in Organic Synthesis, (2017) 1, 610.
摘要:Xu, H.; Dai, H.-X., Science of Synthesis: Special Topics, (2022) 1, 166.
摘要:HANSCH,C ET AL. (1995)
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