CAS: 120591-53-9; 13-Acetyl-7-Oxo-8,11,13-Podocarpatrien-18-Oic Acid

英文名称13-Acetyl-7-Oxo-8,11,13-Podocarpatrien-18-Oic Acid
中文名称(1R,4aS,10aR)-7-乙酰基-1,2,3,4,4a,9,10,10a-八氢-1,4a-二甲基-9-氧代-1-菲羧酸
CAS编号120591-53-9
分子式:C19H22O4分子量:314.38
产品CID: 274826
产品分类有机原料 → 脂质和类脂质分子 → 异戊烯醇脂质

相似结构搜索
InChIKey: UUJPRXAWNIWAPI-BHIYHBOVSA-N
1S/C19H22O4/c1-11(20)12-5-6-14-13(9-12)15(21)10-16-18(14,2)7-4-8-19(16,3)17(22)23/h5-6,9,16H,4,7-8,10H2,1-3H3,(H,22,23)/t16-,18-,19-/m1/s1
计算化学: 氢键受体数4.0氢键供体数1.0可旋转键数2.0

MSDS等安全信息

危险描述H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
防范说明P264+P280+P305+P351+P338+P337+P313
安全声明H303+H313+H333

上下游产品

methyl 13-acetyl-7-oxo-8,11,13-pod°Carpatrien-18-oate dehydroabietic acid acetic anhydride Methyl dehydroabietate ((1R,4aS,10aR)-7-Methoxy-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-°Ctahydro-phenanthren-1-yl)-diphenyl-methanol

合成工艺路线路线简述

📜Methyl 7-Oxodehydroabietate置于氢氧化钾,氧气,Iron(II) Sulfate,过氧化苯甲酰体系中,化学反应生成(1R,4As,10Ar)-7-乙酰基-1,2,3,4,4A,9,10,10A-八氢-1,4A-二甲基-9-氧代-1-菲羧酸
参考文献:The Preparation And Reactions Of Methyl 9-Oxo-14-Hydroperoxydehydroabietate
标题:The Preparation And Reactions Of Methyl 9-Oxo-14-Hydroperoxydehydroabietate
摘要:
Doi:10.1021/ja01632A026