CAS: 10361-91-8; Ytterbium(Iii) Chloride

该化合物是一种无机化合物,由+3氧化状态中的组成,通常以无水或六氢酸形式提供,而无水体变异则具有高度的湿度. Ytterbium氯化物具有很强的刘易斯酸性,在有机合成中,特别是在Friedel-Crafts 和 aldol反应中,它作为催化剂有用,其光学特性在光纤和激光应用中被利用,它作为阳性.该化合物还被用于研究其光白光学特性,并用作其他基于氧基材料的前体.高纯度等级确保敏感应用中的干扰最小化.由于对湿度的敏感性,需要适当处理.

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欧盟法规

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上下游产品

CAS号54761-04-5 三氟甲磺酸镱 | CAS号114363-84-7 ytterbium(III) ... | CAS号67168-39-2 Yb(PDTA)(1-) | CAS号10025-76-0 氯化铕(III) | CAS号7647-01-0 盐酸

合成工艺路线路线简述

  • 合成目标产物 Ytterbium(Iii) Chloride 主要起始原料 Ytterbium(Iii) Trifluoromethanesulfonate Hydrate
  • (文献来源)合成步骤主要原料 Ytterbium(Iii) Trifluoromethanesulfonate Hydrate
📜Ytterbium(III) Triflate 反应生成氯化镱(III)
参考文献:M/'Ethode De Préparation De Sels Anhydres De Lanthanides Pour La Polarographie En Solvants Non Aqueux Aprotiques
标题:M/'Ethode De Préparation De Sels Anhydres De Lanthanides Pour La Polarographie En Solvants Non Aqueux Aprotiques
摘要:
Doi:10.1016/s0003-2670(01)85482-9

专利信息


专利号:US-11926589-B2
优先权日:2019-07-09
标 题 :Process for the synthesis of non-racemic cyclohexenes
发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND
权利人:BASF CORP; CALIFORNIA INST OF TECHN
摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.

专利号:US-11607677-B2
优先权日:2017-10-30
标 题:Homogeneous and reusable superacid polymer catalyst useful for the synthesis of 5-hydroxymethylfurfural from glucose
发明人:ALBA RUBIO ANA C; COLEMAN MARIA R; KALIDINDI SUBHASH; JOSHI ANUP S; OMODOLOR IBEH S
权利人:UNIV TOLEDO; TJIE UNIV OF TOLEDO
摘要:A superacid polymeric catalyst having both Lewis acidity and Brønsted acidity is described, along with methods of making and methods of using the same.

专利号:WO-9955664-A1
优先权日:1998-04-24
标 题 :Preparation of carbocyclic compounds
发明人:BECKER MARK W; CHAPMAN HARLAN H; KELLY DAPHNE E; KENT KENNETH M; LEW WILLARD; LOUIE MICHAEL S; MCGEE LAWRENCE R; PRISBE ERNEST J; POSTICH MICHAEL J; ROHLOFF JOHN C; SCHULTZE LISA M; YU RICHARD H; ZHANG LIJUN
权利人:GILEAD SCIENCES INC; BECKER MARK W; CHAPMAN HARLAN H; KELLY DAPHNE E; KENT KENNETH M; LEW WILLARD; LOUIE MICHAEL S; MCGEE LAWRENCE R; PRISBE ERNEST J; POSTICH MICHAEL J; ROHLOFF JOHN C; SCHULTZE LISA M; YU RICHARD H; ZHANG LIJUN
摘要:The present invention provides new synthetic methods and compositions. In particular, new methods of preparing intermediates useful in the synthesis of neuraminidase inhibitors and compositions useful as intermediates that are themselves useful in the synthesis of neuraminidase inhibitors are provided.

专利号:US-6518438-B2
优先权日:1996-08-23
标题:Preparation of cyclohexene carboxylate derivatives
发明人:KENT KENNETH M; KIM CHOUNG U; MCGEE LAWRENCE R; MUNGER JOHN D; PRISBE ERNEST J; POSTICH MICHAEL J; ROHLOFF JOHN C; KELLY DAPHNE E; WILLIAMS MATTHEW A; ZHANG LIJUN
权利人:GILEAD SCIENCES INC
摘要:The present invention provides new synthetic methods and compositions. In particular, new methods of preparing intermediates useful in the synthesis of neuraminidase inhibitors and compositions useful as intermediates that are themselves useful in the synthesis of neuraminidase inhibitors are provided.

专利号:US-5886213-A
优先权日:1997-08-22
标题:Preparation of carbocyclic compounds
发明人:KENT KENNETH M; KIM CHOUNG U; MCGEE LAWRENCE R; MUNGER JOHN D; PRISBE ERNEST J; POSTICH MICHAEL J; ROHLOFF JOHN C; KELLY DAPHNE E; WILLIAMS MATTHEW A; ZHANG LIJUN
权利人:GILEAD SCIENCES INC
摘要:The present invention provides new synthetic methods and compositions. In particular, new methods of preparing intermediates useful in the synthesis of neuraminidase inhibitors and compositions useful as intermediates that are themselves useful in the synthesis of neuraminidase inhibitors are provided.

专利号:EP-0920410-B1
优先权日:1996-08-23
标 题 :Preparation of cyclohexene carboxylate derivatives
发明人:KENT KENNETH M; KIM CHOUNG U; MCGEE LAWRENCE R; MUNGER JOHN D; PRISBE ERNEST J; POSTICH MICHAEL J; ROHLOFF JOHN C; KELLY DAPHNE E; WILLIAMS MATTHEW A; ZHANG LIJUN
权利人:GILEAD SCIENCES INC
摘要:The present invention provides new synthetic methods and compositions. In particular, new methods of preparing intermediates such as those having formulas (I)-(IV), such as those having formulas (I)-(IV), useful in the synthesis of neuraminidase inhibitors and compositions useful as intermediates that are themselves useful in the synthesis of neuraminidase inhibitors are provided.

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Caixia Yin, Et Al. Uv-Vis Spectroscopic Study Directly Detecting Inorganic Phosphorus In Urine And Our Reagent Kit. Anal Bioanal Chem. 2006 Feb;384(3):774-9.
[参考文献]: D M Albin, Et Al. The Effect Of Feed Intake On Ileal Rate Of Passage And Apparent Amino Acid Digestibility Determined With Or Without Correction Factors In Pigs. J Anim Sci. 2001 May;79(5):1250-8.
[参考文献]: Daqin Chen, Et Al. Nd(3+)-Sensitized Ho(3+) Single-Band Red Upconversion Luminescence In Core-Shell Nanoarchitecture. J Phys Chem Lett. 2015 Jul 16;6(14):2833-40.
[参考文献]: Haiqing Xiao, Et Al. Distribution Of Ytterbium-169 In Rat Brain After Intravenous Injection. Toxicol Lett. 2005 Feb 15;155(2):247-52.
[参考文献]: J D Pagan, Et Al. Exercise Affects Digestibility And Rate Of Passage Of All-Forage And Mixed Diets In Thoroughbred Horses. J Nutr. 1998 Dec;128(12 Suppl):2704S-2707S.

合成参考文献


摘要:Ye, Z.-S., Science of Synthesis Knowledge Updates, (2021) 2, 355.
摘要:Zefirov, N. S.; Matveeva, E. D.; Shuvalov, M. V., Science of Synthesis: Multicomponent Reactions, (2013) 1, 276.
摘要:te Grotenhuis, C.; Schoonen, L.; Rutjes, F. P. J. T., Science of Synthesis: C-1 Building Blocks in Organic Synthesis, (2013) 2, 237.
参考文献:10.1038/s41594-022-00729-3
摘要:Stsiapanava A, Xu C, Nishio S, Han L, Yamakawa N, Carroni M, Tunyasuvunakool K, Jumper J, de Sanctis D, Wu B, Jovine L. Structure of the decoy module of human glycoprotein 2 and uromodulin and its interaction with bacterial adhesin FimH. Nature Structural & Molecular Biology. 2022 Mar 10;29(3):190–3. doi: 10.1038/s41594-022-00729-3.
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