75-31-0 = 834-12-8 反应条件:1.1 Solvents: Tetrahydrofuran; -10 °C; 30 Min,Rt2.1 Reagents: Sodium Hydroxide Solvents: Toluene,Water; 15 °C; 15 Min,Rt3.1 Solvents: Tetrahydrofuran,Water; 24 H,Reflux 标题:Design,Synthesis,And Biological Activities Of Arylmethylamine Substituted Chlorotriazine And Methylthiotriazine Compounds 作者:Zhao,Hua-Ping; Et Al 参考文献:Journal Of Agricultural And Food Chemistry 日期:2011 卷标:59(21) 页码:11711-11717]
868-84-8 + 1912-24-9 = 834-12-8 反应条件:1.1 Reagents: Potassium Hydroxide,Trioctylmethylammonium Chloride Solvents: Water 标题:A New Application Of S,S-Dialkyl Dithiocarbonates As A Convenient Source For Alkanethiols: Synthesis Of 2,4-Bis(Alkylamino)-6-Alkylthio-S-Triazines 作者:Degani,Iacopo; Et Al 参考文献:Chemistry & Industry (London 日期:1986 卷标:(19) 页码:671-2]
5188-07-8 + 1912-24-9 = 834-12-8 反应条件:1.1 Solvents: Xylene,Water; Ph 9,Rt -> 80 °C; 1 H,80 °C; 6 H,80 °C 标题:Exploitation Of New Process For Ametryn Synthesis 作者:Huang,Ping; Et Al 参考文献:Nongyao 日期:2010 卷标:49(9) 页码:643-644]
1912-24-9 = 834-12-8 反应条件:1.1 Reagents: Potassium Tert-Butoxide,Potassium Thioacetate Catalysts: Triphenylphosphine,Palladium Diacetate Solvents: Dimethyl Sulfoxide; Rt -> 120 °C; 120 °C -> Rt1.2 Reagents: Ammonium Chloride Solvents: Water; Rt 标题:Palladium-Catalyzed Thiomethylation Via A Three-Component Cross-Coupling Strategy 作者:Wang,Ming; Et Al 参考文献:Organic Letters 日期:2018 卷标:20(19) 页码:6193-6197]
5498-17-9 = 834-12-8 反应条件:1.1 Reagents: Lithium Tert-Butoxide,1-Chloro-4-(2,2-Difluoroethenyl)Benzene Solvents: Dimethyl Sulfoxide; 12 H,60 °C1.2 24 H,100 °C 标题:Fluoroolefins-Mediated Deoxygenative Substitution Of Alcohols: Chemo- And Enantiospecific Construction Of C-S,C-N,C-O,And C-Se Bonds 作者:Li,Hengyuan; Et Al 参考文献:Organic Letters 日期:2023 卷标:25(29) 页码:5431-5436]
3703-10-4 = 834-12-8 反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Toluene,Water; 15 °C; 15 Min,Rt2.1 Solvents: Tetrahydrofuran,Water; 24 H,Reflux 标题:Design,Synthesis,And Biological Activities Of Arylmethylamine Substituted Chlorotriazine And Methylthiotriazine Compounds 作者:Zhao,Hua-Ping; Et Al 参考文献:Journal Of Agricultural And Food Chemistry 日期:2011 卷标:59(21) 页码:11711-11717
专利号:WO-2024256370-A1 优先权日:2023-06-13 标 题 :Synthesis of glufosinate using an amidase-based process 发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.
专利号:WO-2024201469-A1 优先权日:2023-03-29 标 题:Process for the preparation of amine intermediates 发明人:YACOVAN AVIHAI; BAR NAHUM ITSIK; KRAKOVICH VLADA; PARNES REGEV; WANG HONGFA; ZHANG QINGLONG; Zi Weiwei 权利人:ADAMA AGAN LTD 摘要:The present disclosure relates a process for the preparation of amines as intermediates for the synthesis of triazines, which are suitable for use as herbicides for controlling weeds.
专利号:US-2025120400-A1 优先权日:2021-12-10 标题:Synthesis of glufosinate using a hydantoinase-based process 发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.
专利号:US-11919928-B2 优先权日:2016-03-16 标题 :Method for producing dihydrotentoxin 发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI 权利人:KUMIAI CHEMICAL INDUSTRY CO 摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.
专利号:WO-2024199476-A1 优先权日:2023-03-31 标 题 :Single-chain antibody and in vitro synthesis system and use thereof 发明人:GUO MIN; YANG LONGJIN; XU LIQIONG; HU JIABAO; ZHU YAJUN; YU XUE 权利人:KANGMA HEATHCODE SHANGHAI BIOTECH CO LTD 摘要:The present invention provides a single-chain antibody and an in vitro synthesis system and use thereof. The antibody has a high expression efficiency, high affinity and high stability, is high-efficiently expressed in one step in an in vitro cell-free synthesis system without secreting and expressing two different protein fragments of a light chain and a heavy chain, respectively, which is not easy to form a homodimer, has a relatively high expression efficiency, can be produced on a large scale, and has a good prospect of commercialization.
专利号:US-2021386068-A1 优先权日:2018-11-07 标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides 发明人:KISTER JEREMY; SATCHIVI NORBERT M 权利人:CORTEVA AGRISCIENCE LLC 摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.
1: Santos T, Cancian G, Neodini DN, Mano DR, Capucho C, Predes FS, Barbieri R, Oliveira CA, Pigoso AA, Dolder H, Severi-Aguiar GD. Toxicological evaluation of ametryn effects in Wistar rats. Exp Toxicol Pathol. 2015 Oct;67(10):525-32. doi: 10.1016/j.etp.2015.08.001. Epub 2015 Aug 24. doi: 10.1039/c4em00352g. doi: 10.1007/s11356-014-4010-5. Epub 2015 Jan 6. doi: 10.1371/journal.pone.0112271. eCollection 2014. 5: Sandoval-Carrasco CA, Ahuatzi-Chacón D, Galíndez-Mayer J, Ruiz-Ordaz N, Juárez-Ramírez C, Martínez-Jerónimo F. Biodegradation of a mixture of the herbicides ametryn, and 2,4-dichlorophenoxyacetic acid (2,4-D) in a compartmentalized biofilm reactor. Bioresour Technol. 2013 Oct;145:33-6. doi: 10.1016/j.biortech.2013.02.068. Epub 2013 Feb 27. Epub 2015 Nov 17. doi: 10.1007/s10661-011-2200-x. Epub 2011 Jun 29. doi: 10.1016/j.biortech.2011.12.018. Epub 2011 Dec 17. doi: 10.1016/j.jhazmat.2010.12.044. Epub 2010 Dec 17. doi: 10.2166/wst.2012.318. doi: 10.1021/jf304742h. Epub 2013 Jan 22. doi: 10.1007/s00244-010-9552-z. Epub 2010 Jun 22. doi: 10.1016/j.biortech.2011.12.017. Epub 2011 Dec 17. doi: 10.1016/j.jhazmat.2008.08.038. Epub 2008 Aug 22. doi: 10.1021/es5055385. Epub 2015 Mar 3. Epub 2002 Jul 25. doi: 10.1016/j.envpol.2012.05.002. Epub 2012 May 30. doi: 10.1016/j.jhazmat.2009.03.147. Epub 2009 Apr 7. doi: 10.1016/j.ecoenv.2017.02.053. Epub 2017 Mar 8.
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