📜3-Methyl-Hept-6-En-4-Yn-3-Ol置于乙醇,铂体系中,化学反应生成 3-甲基-3-庚醇 参考文献:Nasarow; Fischer,Izvestiya Akademii Nauk Sssr,Seriya Khimicheskaya,1944,P. 71 标题:Nasarow; Fischer,Izvestiya Akademii Nauk Sssr,Seriya Khimicheskaya,1944,P. 71
专利号:US-6011171-A 优先权日:1996-08-14 标 题 :Process for synthesis of tertiary carboxylic acids and the esters thereof 发明人:XU QIANG; SOUMA YOSHIE 权利人:JIRO HIRAISHI DIRECTOR GENERAL 摘要:The present invention provides a process for synthesizing tertiary carboxylic acids or the esters thereof having one or two more carbon atoms than the raw material has, comprising reacting in a strong acid (e.g., sulfuric acid, sulfuric acid-phosphoric acid, hydrogen fluoride, fluorosulfuric acid, boron trifluoride.water complex and trifluoromethanesulfonic acid) a raw material compound (i.e., olefin, alcohol, diene, diol or saturated hydrocarbon) with carbon monoxide in the presence of a specific metal carbonyl catalyst (i.e., platinum carbonyl catalyst, palladium carbonyl catalyst and gold dicarbonyl catalyst). The metal carbonyl catalyst is formed by reacting in a strong acid at least one specific metal compounds (e.g., platinum compound such as platinum (II, IV) oxide, platinum (II, IV) hydroxide, a platinum powder, etc.; palladium compound such as palladium (II, III, IV) oxide, palladium (II) hydroxide, palladium (II) sulfate, palladium (II) carboxylate, a palladium powder, etc.; and gold compound such as gold (I, III) oxide, gold (I, III) hydroxide, a gold powder, etc.) with carbon monoxide.
专利号:US-4113739-A 优先权日:1974-01-28 标题:Process for preparation of (poly)cyclic polyethers 发明人:TRUCKS ROGER O; STEINER EDWIN C 权利人:DOW CHEMICAL CO 摘要:In the preparation of (poly)cyclic polyethers by a cyclic Williamson synthesis, the improvement of contacting the reactants in a hindered (C 4 -C 14 ) alkanol. For example, bis-chloroethyl ether and the disodium salt of tetraethylene glycol are contacted in t-butanol to produce the cyclic polyether ##STR1## in high yields.
专利号:JP-H11315047-A 优先权日:1998-04-30 标 题:Synthesis of tertiary carboxylic acids using solid acid catalysts.
专利号:JP-H1112220-A 优先权日:1997-06-20 标 题:Synthesis of tertiary carboxylic acids using palladium carbonyl catalyst
专利号:JP-2990275-B1 优先权日:1998-12-24 标 题:Mercury-catalyzed synthesis of tertiary carboxylic acids
专利号:JP-2000191581-A 优先权日:1998-12-24 标题:Mercury-catalyzed synthesis of tertiary carboxylic acids