CAS: 10213-09-9; Oxovanadium,Dihydrochloride

该化合物是一种无机化合物,其特点是在+4氧化状态下,以中心为特征,与两种氯化离子相协调,该化合物一般是蓝色或绿色固体,以其血红色性质而著称,这意味着它可以吸收空气中的湿度.二氯化甲醚在水和酒精等极溶剂中可以溶解,并可以参与各种化学反应,包括水解,从而可以形成氟化氧复合体.它经常用于其他化合物的合成中,并作为有机反应中的催化剂.此外,二氯化甲醚展示了有趣的磁性和电子性,使其成为材料科学和协调化学研究的课题.在处理该化合物时,应当采取安全防范措施,因为它可能有毒,并可能对环境造成危害.建议在一个冷干燥的地方进行适当的储存,以保持其稳定性并防止降解.

英文名称Oxovanadium,Dihydrochloride
中文名称二氯氧钒
IUPAC名称oxovanadium;dihydrochloride
其它别名dichlorooxo-Vanadium; dichlorooxovanadium; vanadium chloride oxide; vanadium oxychloride
CAS编号10213-09-9
MFCD编号:MFCD00011458
EINECS号:233-517-7
FDA UNII编号:ET7948FWOY
分子式:Cl2OV+分子量:137.8469
产品CID: 47928
产品分类无机化合物 → 混合金属/非金属化合物 → 过渡金属盐

相似结构搜索
InChIKey: ZKXFNWJICXMNNA-UHFFFAOYSA-L
InChI=1S/2ClH.O.V/h2*1H;;/q;;;+2/p-2
计算化学: 氢键受体数3.0氢键供体数*可旋转键数*

MSDS等安全信息

GHS象形图
GHS符号GHS07 & GHS05;
注释: Exclamation mark & Corrosion
危险类别急性毒性类别4(经口)
皮肤腐蚀类别1B
警示词Danger(危险)
危险描述H302 |吞咽有害.
H314 |造成严重皮肤灼伤和眼损伤.
防范说明P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501-P264-P270-P301+P312-P330-P501
危险等级8
UN编号2923
包装等级III
危险类别码50% Aqueous solution: Causes burns; [BDH Laboratory Supplies MSDS] See Vanadium oxytrichloride and Vanadium tetrachloride.

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号7727-18-6 三氯氧钒 | CAS号7632-51-1 四氯化钒 | CAS号7727-18-6 三氯氧钒 | CAS号13520-87-1 oxovanadium,hyd... | CAS号67332-62-1 ethanol,oxovanadium

合成工艺路线路线简述

📜(C5H5)2V(2+) Chlorid置于氧气体系中,用 Not Given 用作溶剂,化学反应生成二氯氧钒
参考文献:Abakumov,G. A.; Shilov,A. R.; Shulyndin,S. V.,Kinetica I Kataliz,1964,Vol. 5,P. 201-206
标题:Abakumov,G. A.; Shilov,A. R.; Shulyndin,S. V.,Kinetica I Kataliz,1964,Vol. 5,P. 201-206

专利信息

专利号:US-7932311-B2
优先权日:2005-12-23
标题 :Synthesis of particles in dendritic structures
发明人：AYMONIER CYRIL; CANSELL FRANCOIS; MECKING STEFAN; MOISAN SANDY; MARTINEZ VICTOR
权利人:CENTRE NAT RECH SCIENT
摘要:The invention relates to a method of preparing a particle-based composition, comprising: (i) bringing into contact a mixture comprising a dendritic structure and a metal compound precursor in a fluid, under temperature and pressure conditions such that the mixture is not soluble in the fluid; and (ii) chemically converting the metal compound precursor.

专利号:US-4517371-A
优先权日:1981-12-02
标题:Process for the synthesis of carboxylic anhydrides using a vanadium, phosphorus oxygen containing catalyst composition
发明人：YANG TAI-CHENG; RAO KRISHNA K; HUANG I-DER
权利人:EXXON RESEARCH ENGINEERING CO
摘要:A vanadium, phosphorus oxygen containing catalyst composition capable of partially oxidizing hydrocarbons (e.g., n-butane) to form a carboxylic anhydride (e.g., maleic anhydride), a process for preparing this catalyst, and a process for using this catalyst to form such anhydrides is disclosed. The catalyst composition is prepared by an organic heterogenous technique followed by a water treatment step and activation.

专利号:US-2009093597-A1
优先权日:2005-12-23
标题:Synthesis of particles in dendritic structures

专利号:CN-112225250-A
优先权日:2020-10-16
标题:Method for self-reducing hydrothermal synthesis of vanadium dioxide nano-powder

专利号:CN-112225250-B
优先权日:2020-10-16
标题 :Method for self-reducing hydrothermal synthesis of vanadium dioxide nano-powder