CAS: 93379-48-7; (4R,5R)-2,2-Dimethyl-Alpha,Alpha,Alpha',Alpha'-Tetraphenyldioxolane-4,5-Dimethanol

• 英文名称(4R,5R)-2,2-Dimethyl-Alpha,Alpha,Alpha',Alpha'-Tetraphenyldioxolane-4,5-Dimethanol
• 中文名称(-)-4,5-双[羟基(二苯基)甲基]-2,2-二甲基-1,3-二氧戊环
• IUPAC名称((4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol)
• 其它别名(-)-trans-alpha,alpha'-(Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol)
• CAS编号93379-48-7
• MFCD编号:MFCD00064467
• 分子式:C31H30O4
• 分子量:466.57
• 产品CID: 1973080
• 产品分类化学试剂 → 有机试剂 → 膦配体

• 相似结构搜索
• 产品信息参考;
• InChIKey: OWVIRVJQDVCGQX-VSGBNLITSA-N
• RNSJHECWLNVNFE-KYJUHHDHSA-N…
• 计算化学: 氢键受体数4.0氢键供体数2.0可旋转键数6.0

物理性质

• 熔点193-195  °C(文献)
• 沸点633.2±50.0 °C at 760 mmHg
• 闪点336.7±30.1 °C
• 密度1.2±0.1 g/cm3
• PH:-65.5 º (c=1, CHCl3)
• pKa:12.28±0.29(预测)
• PSA:58.92
• LogP:9.6
• 旋光度-65.5º(C=1,CHCL3)
• 折射率1.615
• 蒸汽压0.0±2.0 mmHg at 25°C
• 敏感性遵照规定使用和储存则不会分解。
• 外观形态白色粉末
• 储存条件惰性气氛,室温
• 产品应用该化合物用作藻类非对称水成形,三代代代藻类的氨化导催化非对式水化,将已停止使用的烷基 GRIGNARD试剂添加到甲.

MSDS等安全信息

• 警示词Warning
• 危险描述H302-H315-H319-H335-
• 防范说明P261-P280-P301+P312-P302+P352-P305+P351+P338-
• UN编号NONH for all modes of transport
• 危险品标志Xi,Xn
• 安全声明24/25-36-26
• 危险类别码36/38-36/37/38-20/21/22
• WGK Germany3

上下游产品

合成工艺路线路线简述

• 93379-48-7 = 93379-48-7
  反应条件:1.1 Reagents: Water Solvents: Ethyl Acetate
  标题:New Types Of Soluble Polymer-Supported Bisphosphine Ligands With A Cyclobutane Backbone For Pd-Catalyzed Enantioselective Allylic Substitution Reactions
  作者:Zhao,Dongbo; Sun,Jie; Ding,Kuiling
  参考文献:Chemistry - A European Journal 日期:2004 卷标:10(23) 页码:5952-5963]
  
  59779-75-8 = 93379-48-7
  反应条件:1.1 Solvents: Tetrahydrofuran
  标题:Design Of A New Chiral Host Compound,Trans-4,5-Bis(Hydroxydiphenylmethyl)-2,2-Dimethyl-1,3-Dioxacyclopentane. An Effective Optical Resolution Of Bicyclic Enones Through Host-Guest Complex Formation
  作者:Toda,Fumio; Tanaka,Koichi
  参考文献:Tetrahedron Letters 日期:1988 卷标:29(5) 页码:551-4]
  
  37031-29-1 = 93379-48-7
  反应条件:1.1 Reagents: Magnesium Iodide Solvents: Tetrahydrofuran; Reflux; 1 H,Reflux; Reflux -> Rt1.2 Rt; 20 °C; 1.5 H,20 °C1.3 Reagents: Ammonium Chloride Solvents: Water
  标题:Chiral Phosphonitrile Super Base Catalysts Based On Chiral Diamine Spiro Skeleton Prepared With Chiral O-Dicarboxylic Acid As Raw Material,Their Preparation Methods And Applications In Organic Synthesis Reaction.
  参考文献:China]
  
  37031-29-1 = 93379-48-7
  反应条件:1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Tetrahydrofuran; Rt; 1 H,Reflux; Reflux -> Rt1.2 Solvents: Tetrahydrofuran; < 20 °C; 1.5 H,Reflux
  标题:Design Of Highly Stable Iminophosphoranes As Recyclable Organocatalysts: Application To Asymmetric Chlorinations Of Oxindoles
  作者:Gao,Xing; Han,Jianwei; Wang,Limin
  参考文献:Organic Letters 日期:2015 卷标:17(18) 页码:4596-4599]
  
  59779-75-8 = 93379-48-7
  反应条件:1.1 Reagents: Magnesium Solvents: Tetrahydrofuran1.2 Solvents: Tetrahydrofuran; 1 H,Rt; 6 H,Reflux1.3 Reagents: Ammonium Chloride Solvents: Water
  标题:Enantioselective Catalysis Of The Hetero-Diels-Alder Reaction Between Brassard'S Diene And Aldehydes By Hydrogen-Bonding Activation: A One-Step Synthesis Of (S)-(+)-Dihydrokawain
  作者:Du,Haifeng; Zhao,Dongbo; Ding,Kuiling
  参考文献:Chemistry - A European Journal 日期:2004 卷标:10(23) 页码:5964-5970]
  
  37031-29-1 = 93379-48-7
  反应条件:1.1 Reagents: Magnesium,Iodine Solvents: Tetrahydrofuran; Rt; 2 H,Rt -> 80 °C; 80 °C -> 0 °C1.2 Solvents: Tetrahydrofuran; 0 °C; 12 H,Reflux; Reflux -> 0 °C1.3 Reagents: Ammonium Chloride Solvents: Water
  标题:Palladium-Catalyzed Si-C Bond-Forming Silylation Of Aryl Iodides With Hydrosilanes: An Enhanced Enantioselective Synthesis Of Silicon-Stereogenic Silanes By Desymmetrization
  作者:Chen,Li; Huang,Jiang-Bo; Xu,Zheng; Zheng,Zhan-Jiang; Yang,Ke-Fang; Et Al
  参考文献:Rsc Advances 日期:2016 卷标:6(71) 页码:67113-67117]
  
  93379-48-7 = 93379-48-7
  反应条件:1.1 Reagents: 1H-Phosphole,2,5-Dihydro-3-Methyl-1-(2-Methylpropyl)-,1-Oxide Solvents: Hexane,Ethyl Acetate; 3 H,26 °C
  标题:A Case Study On The Resolution Of The 1-I-Butyl-3-Methyl-3-Phospholene 1-Oxide Via Diastereomeric Complex Formation Using Taddol Derivatives And Via Diastereomeric Coordination Complexes Formed From The Calcium Salts Of O,O'-Diaroyl-(2R,3R)-Tartaric Acids
  作者:Bagi,Peter; Fekete,Andras; Kallay,Mihaly; Hessz,Dora; Kubinyi,Miklos; Et Al
  参考文献:Heteroatom Chemistry 日期:2015 卷标:26(1) 页码:79-90]
  
  59779-75-8 = 93379-48-7
  反应条件:1.1 Reagents: Magnesium Solvents: Tetrahydrofuran; Cooled; 1.5 H,Reflux; Reflux -> Rt1.2 Reagents: Ammonium Chloride Solvents: Water
  标题:Tartaric Acid Framework-Based Chiral Guanidine Catalyst And Preparation Method And Application Thereof
  参考文献:China]
  
  59779-75-8 = 93379-48-7
  反应条件:1.1 Reagents: Magnesium Solvents: Tetrahydrofuran; 1.5 H,Reflux
  标题:Development Of Tartaric Acid Derived Chiral Guanidines And Their Application To Catalytic Enantioselective α-Hydroxylation Of β-Dicarbonyl Compounds
  作者:Zou,Liwei; Wang,Baomin; Mu,Hongfang; Zhang,Huanrui; Song,Yuming; Et Al
  参考文献:Organic Letters 日期:2013 卷标:15(12) 页码:3106-3109]
  
  37031-29-1 = 93379-48-7
  反应条件:1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Tetrahydrofuran1.2 Solvents: Tetrahydrofuran; 8 H1.3 Reagents: Ammonium Chloride Solvents: Water
  标题:Quaternary Phosphonium Salt Compound And Preparation Method Thereof From Tartaric Acid
  参考文献:China]
  
  91967-11-2 = 93379-48-7
  反应条件:1.1 Solvents: Tetrahydrofuran; 10 Min,0 °C; 1 H,Reflux; Reflux -> Rt1.2 Reagents: Ammonium Chloride Solvents: Water
  标题:New Tartrate Based Cyclic Phosphoric Acids As Organocatalysts In Mannich Reactions
  作者:Budragchaa,Tuvshinjargal; Abraham,Michael; Schoefberger,Wolfgang; Roller,Alexander; Widhalm,Michael
  参考文献:Asymmetric Catalysis 日期:2016 卷标:3(1) 页码:1-14]
  
  37031-29-1 = 93379-48-7
  反应条件:1.1 Reagents: Magnesium,Iodine Solvents: Tetrahydrofuran; Reflux; 1 H,Reflux; Overnight,Rt1.2 Solvents: Tetrahydrofuran; 0 °C; 1.5 H,0 °C -> Reflux1.3 Reagents: Ammonium Chloride Solvents: Water
  标题:Chiral Phosphine-Phosphite Ligands In Asymmetric Gold Catalysis: Highly Enantioselective Synthesis Of Furo[3,4-D]-Tetrahydropyridazine Derivatives Through [3+3]-Cycloaddition
  作者:Du,Qingwei; Neudoerfl,Joerg-Martin; Schmalz,Hans-Guenther
  参考文献:Chemistry - A European Journal 日期:2018 卷标:24(10) 页码:2379-2383]
  
  = 93379-48-7
  反应条件:1.1 Reagents: Magnesium Solvents: Tetrahydrofuran1.2 Solvents: Tetrahydrofuran; 30 Min,-20 °C; -20 °C -> Rt; 24 H,Rt1.3 Reagents: Ammonium Chloride Solvents: Water; -20 °C
  标题:Enantioselective Direct Synthesis Of Syn- And Anti-α,β-Dihydroxy γ-Keto Esters Using A Dinuclear Zinc-Azephenol Complex
  作者:Zhang,Zhao-Fei; Yang,Xiao-Chao; Lu,Hui-Jie; Wang,Min-Can
  参考文献:European Journal Of Organic Chemistry 日期:2018 卷标:2018(6) 页码:785-793

海关参考信息

• 2902600000-乙苯
  2905122000-异丙醇
  2905310000-1,2-乙二醇
  2905320000-1,2-丙二醇
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