CAS: 3898-08-6; 1,1-Diphenylthiourea

该化合物是一种有机化合物,其特征是硫尿亚结构,其中两个苯基组附在氮原子上,看起来像是白色到浅黄色晶状固体,以水中的溶性相对较低闻名,但在乙醇和丙酮等有机溶剂中具有较高的溶性.该化合物具有C13H12N2S分子分子配方和反映其成分的分子重量.N,N-Dimentythiourea主要用于各种用途,包括作为有机合成的试剂,特别是用于制作某些药品和农用化学品.它也是橡胶生产中的稳定剂,在某些化学反应中也可以起到催化剂作用.它具有典型的硫尿的复合特性,例如形成氢链和参加核细胞反应的能力.在处理该物质时,应当采取安全防范措施,因为如果浸入或吸入,可能会对健康造成危害,而且应当使用适当的防护设备.

结构式图片

上下游产品

propan-1-ol 1-(2-chloro-phenyl)-3-phenyl-thiourea 2,4-dimethyl-1,2,4-thiadiazolidine-3-thione-5-one aniline N,N',N''-triphenylguanidine aniline N,N'-dibenzoyl-N,N'-diphenyl-thioureaN,N'-dibenzoyl-N,N'-diphenyl-thiourea 2-phenylimino-3-phenyl-4-isopropyl-2,3-dihydrothiazole

合成工艺路线路线简述

    📜在 盐酸体系中,用 丙酮 作为反应溶剂,化学反应 0.25H,以50.7 G的收率获得产物1,1-二苯基硫脲
    参考文献:新型空穴传输材料 N,N'-Perarylated Phenylene-1,4-Diamines 和联苯胺的一些杂环类似物的合成与表征
    标题:新型空穴传输材料 N,N'-Perarylated Phenylene-1,4-Diamines 和联苯胺的一些杂环类似物的合成与表征
    摘要:从 N,N-二芳基取代的硫脲 20 和硫代乙酰胺 21 开始,获得了一系列类似于 N,N'-过芳基化亚苯基-1,4-二胺和联苯胺的杂环.通过 Dsc 测量研究,这些化合物代表了一类新的空穴传输材料,具有高热稳定性和形成稳定无定形状态的高趋势.此外,通过循环伏安法测量,一些新化合物很容易被可逆氧化,表明形成持久的自由基离子.此类化合物通常在其杂环部分完全被芳基取代,已成功用作 Oled 中的空穴传输材料.
    DOI:10.1055/s-2002-32531

    海关参考信息

    专利信息


    专利号:US-2023257553-A1
    优先权日:2022-02-15
    标 题 :Synthesis of silane compounds
    发明人:PINNOW MATTHEW J; CHANDRASEKARAN YOGESH; HWANG LESLEY; PAPPAS CHRISTOPHER M; SHARMA NIDHI
    权利人:MOMENTIVE PERFORMANCE MAT INC
    摘要:The present disclosures are directed to a silane coupling agent, two silane functional polymers, a method of making a silane coupling agent, the use of a silane coupling agent for making a silane functional polymer, a method of making a silane functional polymer by removing a protecting group, and a composition comprising one or more silane functional polymers.

    专利号:US-2012184724-A1
    优先权日:2009-09-22
    标 题 :Protected monomers and methods of deprotection for rna synthesis
    发明人:SIERZCHALA AGNIESZKA B; SMART BRIAN PHILLIP; DELLINGER DOUGLAS J; DELLINGER GERALDINE; MYERSON JOEL; TIMAR ZOLTAN
    权利人:SIERZCHALA AGNIESZKA B; SMART BRIAN PHILLIP; DELLINGER DOUGLAS J; DELLINGER GERALDINE; MYERSON JOEL; TIMAR ZOLTAN; AGILENT TECHNOLOGIES INC
    摘要:A nucleoside monomer that is protected by a thionocarbamate protecting group and contains one or more 2 H, 13 C, or 15 N isotopes in the ribose and/or base part is provided, as well as a method for making a polynucleotide that uses the same. Also provided is a polynucleotide synthesis method that employs a diamine to deprotect a protected polynucleotide.

    专利号:US-2008004415-A1
    优先权日:2004-05-03
    标题 :Non-linear optically active molecules, their synthesis, and use
    发明人:MCGINNISS VINCENT D; RISSER STEVEN M; DROTLEFF ELIZABETH; JIANG EDWARD; SPAHR KEVIN B
    权利人:OPTIMER PHOTONICS INC
    摘要:In one aspect, the present invention provides a hyperpolarizable organic chromophore. The chromophore is a nonlinear optically active compound that includes a Ï€-donor conjugated to a Ï€-acceptor through a Ï€-electron conjugated bridge. In other aspects of the invention, donor structures and acceptor structures are provided. In another aspect of the invention, a chromophore-containing polymer is provided. In one embodiment, the chromophore is physically incorporated into the polymer to provide a composite. In another embodiment, the chromophore is covalently bonded to the polymer, either as a side chain polymer or through crosslinking into the polymer. In other aspects, the present invention also provides a method for making the chromophore, a method for making the chromophore-containing polymer, and methods for using the chromophore and chromophore-containing polymer.

    专利号:US-5270213-A
    优先权日:1991-06-21
    标题:Protein sequencing
    发明人:FARNSWORTH VINCENT
    权利人:PORTON INSTR INC
    摘要:A method for the generation of phenylthiocarbamyl (PTC) amino acids from phenylthiohydantoin (PTH) or anilinothiozolinone (ATZ) amino acids. The method involves a base-catalyzed ring opening of the PTH or ATZ in the presence of a reducing agent. The method affords an alternative to the established aqueous acid conversion reaction of the Edman degradation in which ATZ and PTC amino acids are converted to the PTH amino acid. A further method is described for the generation of reactive ATZ amino acids from PTH amino acids. These methods facilitate the analysis of protein at low molar amounts by allowing the synthesis of amino acid derivatives which can be analyzed in quantities which are much lower than those required for conventional PTH amino acid analysis.

    专利号:US-2012059163-A1
    优先权日:2005-04-28
    标题 :Non-linear opticaly active molecules, their synthesis, and use
    发明人:MCGINNISS VINCENT D; RISSER STEVEN M; DROTLEFF ELIZABETH; JIANG EDWARD; SPAHR KEVIN B
    权利人:MCGINNISS VINCENT D; RISSER STEVEN M; DROTLEFF ELIZABETH; JIANG EDWARD; SPAHR KEVIN B; OPTIMER PHOTONICS INC
    摘要:In one aspect, the present invention provides a hyperpolarizable organic chromophore. The chromophore is a nonlinear optically active compound that includes a Ï€-donor conjugated to a Ï€-acceptor through a Ï€-electron conjugated bridge. In other aspects of the invention, donor structures and acceptor structures are provided. In another aspect of the invention, a chromophore-containing polymer is provided. In one embodiment, the chromophore is physically incorporated into the polymer to provide a composite. In another embodiment, the chromophore is covalently bonded to the polymer, either as a side chain polymer or through crosslinking into the polymer. In other aspects, the present invention also provides a method for making the chromophore, a method for making the chromophore-containing polymer, and methods for using the chromophore and chromophore-containing polymer.

    专利号:JP-2025505262-A
    优先权日:2022-02-15
    标 题:Synthesis of silane compounds

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1016/j.saa.2003.09.007|10.1016/s1386-1425(03)00412-8
    摘要:Datta K, Mukherjee AK. Study of a reaction between 2,3-dichloro-1,4-naphthoquinone and N,N′-diphenyl thiourea involving an EDA adduct as intermediate. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2004 Jun;60(7):1641–7. doi: 10.1016/j.saa.2003.09.007.
    参考文献:10.1002/dvdy.20921
    摘要:Tingaud‐Sequeira A, Forgue J, André M, Babin PJ. Epidermal transient down‐regulation of retinolbinding protein 4 and mirror expression of apolipoprotein Eb and estrogen receptor 2a during zebrafish fin and scale development. Developmental Dynamics. 2006 Oct 12;235(11):3071–9. doi: 10.1002/dvdy.20921.
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