CAS: 375-19-9; Heptafluorobutyrylamidine

该化合物是一种含氟的米介质化合物,其特征是其强大的电子-用拖拉式七氟丁基化合物组,这一结构特征增强了其作为衍生剂的再活动性,特别是在分析化学中,通过气相色谱学或质谱测量检测和量化氨基氨基酸和其他核分裂性解析物.其高氟化能提高了挥发性和检测敏感性,使其在跟踪分析中具有价值.该化合物在衍生条件下的稳定性以及与氟溶剂的兼容性进一步增强了其在专门应用中的效用.需要谨慎处理,因为它有可能对湿度和核分裂物产生反作用.

结构式图片

相似化合物

464-21-1 307-31-3 678-57-9

欧盟法规

ECHA物质C&L通报

上下游产品

CAS号375-00-8 七氟丁腈 | CAS号103573-07-5 Perfluoro(5-aza... | CAS号2992-92-9 Butanimidic aci... | CAS号915-76-4 2,4,6-三(七氟丙基)-1...

合成工艺路线路线简述

    📜全氟(5-氮杂-4-壬烯)置于氨体系中,用31%的收率获得产物七氟丁酰脒
    参考文献:Solvolyis Reactions Of Perfluoro-5-Aza-4-Nonene,C3F7cfnc4F9
    标题:Solvolyis Reactions Of Perfluoro-5-Aza-4-Nonene,C3F7cfnc4F9
    摘要:Hydrolysis Of The Imine Perfluoro-5-Aza-4-Nonene,C3F7-Cf=n-C4F9,In Ether Was Studied By Several Spectroscopic Techniques Including O-17 NMR. The Initial Product Is C3F7-Co-Nh-C4F9 Which Is Converted To (C3F7Co)(2)Nh And Then To C3F7Conh2 And C3F7Co2H. Solvolysis In Liquid Ammonia Afforded The Amidine C3F7-C(=nh)Nh2. Reaction With Hydrazine Produced 3,5-Bis(Heptafluoropropyl)-1,2,4-Triazole Whose Crystal Structure Is Reported. (C) 2003 Elsevier Science B.V. All Rights Reserved.
    DOI:10.1016/s0022-1139(03)00084-8

    海关参考信息

    专利信息


    专利号:US-7247749-B2
    优先权日:2003-01-29
    标 题:Bisaminophenyl-based curatives and amidine-based curatives and cure accelerators for perfluoroelastomeric compositions
    发明人:AUFDERMARSH CARL A; AMIN HARSHAD P; LOGOTHETIS ANESTIS; GUBANOV VICTOR; VOLKOVA MARGARITA; KARMANOVA LIOUDMILA; KOLLAR ALEXANDR; TROICHANSKAIA POLINA; EMELIANOV GENNADY; BERENBLIT VSEVOLOD
    权利人:FED STATE UNITARY ENTPR S V LE
    摘要:Novel monoamidine, monoamidoxime and bisamidine curatives, co-curatives and cure accelerators are provided for use with perfluoroelastomeric compositions as well as novel synthesis methods for making monoamidine- and monoamidoxime-based curatives, co-curatives and cure accelerators. Also provided are diphenyl-based curatives, co-curatives and cure accelerators having sufficiently high molecular weight such that the melting temperature of the curatives, co-curatives and cure accelerators is no greater than about 240° C., and more preferably no greater than about 230° C.

    专利号:US-7521510-B2
    优先权日:2003-01-29
    标 题 :Bisaminophenyl-based curatives and amidine-based curatives and cure accelerators for perfluoroelastomeric compositions
    发明人:AUFDERMARSH CARL A; AMIN HARSHAD P; LOGOTHETIS ANESTIS
    权利人:GREENE TWEED INC
    摘要:Novel monoamidine, monoamidoxime and bisamidine curatives, co-curatives and cure accelerators are provided for use with perfluoroelastomeric compositions as well as novel synthesis methods for making monoamidine- and monoamidoxime-based curatives, co-curatives and cure accelerators. Also provided are diphenyl-based curatives, co-curatives and cure accelerators having sufficiently high molecular weight such that the melting temperature of the curatives, co-curatives and cure accelerators is no greater than about 240° C., and more preferably no greater than about 230° C.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:S25 | OECDPFAS | List of PFAS from the OECD | DOI:10.5281/zenodo.2648775
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