CAS: 2655-84-7; 3-Bromophenetole

上下游产品

CAS号591-20-8 3-溴苯酚 | CAS号75-03-6 碘乙烷 | CAS号592-55-2 2-溴乙基乙醚 | CAS号74-96-4 溴乙烷 | CAS号585-79-5 间溴硝基苯 | CAS号141-52-6 乙醇钠 | CAS号591-19-5 3-溴苯胺 | CAS号64-67-5 硫酸二乙酯 | CAS号202208-73-9 3-乙氧基-联苯-4-羧酸 | CAS号591-20-8 3-溴苯酚 | CAS号1073339-03-3 3-溴-5-乙氧基苯硼酸频那醇酯 | CAS号54852-73-2 1,1-Biphenyl, 3...

📜3-溴苯硼酸置于三氟化硼乙醚,Sodium Hydride体系中,用 二氯甲烷,甲基叔丁基醚,Mineral Oil 用作溶剂,化学反应 1.75H,反应生成3-溴苯乙醚
参考文献:Base Mediated Synthesis Of Alkyl-Aryl Ethers From The Reaction Of Aliphatic Alcohols And Unsymmetric Diaryliodonium Salts
标题:Base Mediated Synthesis Of Alkyl-Aryl Ethers From The Reaction Of Aliphatic Alcohols And Unsymmetric Diaryliodonium Salts
摘要:The Base Mediated Coupling Of Aliphatic Alcohol Pronudeophiles With Unsymmetric Diaryliodonium Salt Electrophiles Is Described. This Metal-Free Reaction Is Operationally Simple,Proceeds At Mild Temperature,And Displays Broad Substrate Scope To Generate Industrially Important Alkyl-Aryl Ethers In Moderate To Excellent Yield. The Synthetic Utility Of These Reactions Is Demonstrated,And Aspects Of Sustainability Are Highlighted By The Use Of Unsymmetric Aryl(Mesityl)Iodonium Arylating Reagents.
Doi:10.1021/acs.Joc.5B00907

专利信息

专利号:US-7884125-B2
优先权日:2008-04-30
标 题:Straightforward entry to 7-azabicyclo[2.2.1]heptane-1-carbonitriles and subsequent synthesis of epibatidine analogues
发明人：STEVENS CHRISTIAN; HEUGEBAERT THOMAS
权利人:UNIV GENT
摘要:The present invention relates to a group of substituted-7-azabicyclo-[2.2.1]heptyl derivatives with biological activity. The present invention also relates to synthetic methods for producing said substituted-7-azabicyclo-[2.2.1]heptyl derivatives. The present invention also relates to certain intermediates for producing such substituted-7-azabicyclo-[2.2.1]heptyl derivatives, as well as a synthetic method for producing such intermediates. The present invention also relates to pharmaceutical compositions comprising such substituted-7-azabicyclo-[2.2.1]heptyl derivatives, as well as their use as medicaments for the treatment of diseases mediated by a Nicotinic Acetylcholine Receptor or a receptor being a member of the Neurotransmitter-gated Ion Channel Superfamily, such as pain, Alzheimer's disease, Parkinson's disease, schizophrenia, epilepsy and nicotine addiction.

专利号:US-7078568-B2
优先权日:2002-11-12
标 题 :Phosphine compounds, transition metal complexes with the compounds contained as ligands therein, and asymmetric synthesis catalysts containing the complexes
发明人：SHIMIZU HIDEO; SAITO TAKAO; NAGASAKI IZURU
权利人:TAKASAGO PERFUMERY CO LTD
摘要:Phosphine compounds represented by the following formula (1): n nwherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 represent substituents, and asymmetric synthesis catalysts containing transition metal phosphine complexes with the compounds contained as ligands therein.n n The novel phosphine compounds according to the present invention are useful especially as ligands in transition metal complexes. The transition metal phosphine complexes are useful as catalysts for asymmetric synthetic reactions. The novel phosphine compounds useful as ligands can be prepared by a relatively economical preparation process. Further, use of these catalysts can afford hydrogenated products with high optically purity and is also extremely useful from the industrial standpoint.

专利号:US-2009275616-A1
优先权日:2008-04-30
标 题 :Straightforward entry to 7-azabicyclo[2.2.1]heptane-1-carbonitriles and subsequent synthesis of epibatidine analogues

专利号:CN-108101741-A
优先权日:2017-12-05
标题 :A method for the tandem synthesis of chiral alcohols by hydration/asymmetric hydrogenation of alkynes

专利号:RU-2167148-C2
优先权日:1995-12-20
标题 :1-phenyl-2-dimethylaminomethylcyclohexane-1-ol compounds, methods of their synthesis and drug based on thereof