欧盟法规
ECHA物质C&L通报上下游产品
4-氯联苯 4'-Biphenyl Chloride 2051-62-9
4-溴代联苯 4-Bromo-1,1'-Biphenyl 92-66-0
4-氨基-4'-溴联苯 4-Amino-4'-Bromobiphenyl 3365-82-04-氯联苯置于溴,溶剂黄146体系中,化学反应生成4'-氯-4-溴联苯
参考文献:40.联苯系列中的取向效应.第十部分.4:4'-二氯-和4:4'-二溴-二苯基和4-氯-4'-溴二苯的定量硝化
标题:40.联苯系列中的取向效应.第十部分.4:4'-二氯-和4:4'-二溴-二苯基和4-氯-4'-溴二苯的定量硝化
摘要:
Doi:10.1039/jr9320000285
专利信息
专利号:US-7479575-B2
优先权日:2003-10-13
标 题:Method for preparing para-phenyl alkynyl benzaldehydes
发明人:SWINNEN DOMINIQUE; POHIN DANIG
权利人:SERONO LAB
摘要:The present invention is related to a new synthesis for preparing para-phenyl alkynyl benzaldehyde of general formula (I). The compounds of formula (I) are useful building blocks, in particular in the synthesis of electrically conducting polymers. R is selected from the group consisting of C 1 -C 12 -alkyl, C 1 -C 12 -alkyl aryl, C 1 -C 12 -alkyl heteroaryl, C 2 -C 12 -alkenyl, C 2 C 12 -alkenyl aryl, C 2 -C 12 -alkenyl heteroaryl, C 2 -C 12 -alkynyl, C 2 -C 12 -alkynyl aryl, C 2 -C 12 -alkynyl heteroaryl, C 3 -C 8 -cycloalkylC 1 -C 12 -alkyl-C 3 -C 8 -cycloalkyl, C 1 -C 12 -alkoxy, aryl, heteroaryl, halides.
专利号:WO-2024185814-A1
优先权日:2023-03-06
标题:Method for producing aryl compound containing tritylsulfanyl group
发明人:OKAZOE TAKASHI; NOZAKI KYOKO; GATZENMEIER Tim; LIU YUE
权利人:AGC INC; UNIV TOKYO
摘要:The present invention provides: a substrate for achieving the highly efficient synthesis of an aryl compound containing a tritylsulfanyl group; a method for producing a compound containing an SF 5 group using the substrate; and others. The present invention is a method for producing an aryl compound containing a tritylsulfanyl group, the method comprising thiotritylating a halogenated aryl compound represented by general formula (1) [wherein A 1 represents an aryl group that may have a substituent or a heteroaryl group that may have a substituent; and X represents a halogen atom] using [(triphenylmethyl)sulfanyl]potassium or [(triphenylmethyl)sulfanyl]sodium to produce an aryl compound containing a tritylsulfanyl group, the aryl compound being represented by general formula (2) [wherein A 1 is the same as A 1 in general formula (1); and Ph represents a phenyl group].